Silylboranes as Powerful Tools in Organic Synthesis: Stereo- and Regioselective Reactions with 1,n-Enynes

Catalytic Asymmetric Conjugate Protosilylation and Protoborylation of 2-Trifluoromethyl Enynes for Synthesis of Functionalized Allenes

(2020) Chao Yang et al.   ORGANIC LETTERS

Catalytic Generation of Rhodium Silylenoid for Alkene–Alkyne–Silylene [2 + 2 + 1] Cycloaddition

(2019) Toshimichi Ohmura et al.   ORGANIC LETTERS

Cobalt-Catalyzed Enantioselective Hydroboration/Cyclization of 1,7-Enynes: Asymmetric Synthesis of Chiral Quinolinones Containing Quaternary Stereogenic Centers

(2019) Caizhi Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom-Economical Ni-Catalyzed Diborylative Cyclization of Enynes: Preparation of Unsymmetrical Diboronates

(2019) Natalia Cabrera-Lobera et al.   ORGANIC LETTERS

Ligand-Dependent-Controlled Copper-Catalyzed Regio- and Stereoselective Silaboration of Alkynes

(2019) Meng Zhao et al.   ORGANIC LETTERS

Geometric E →Z Isomerisation of Alkenyl Silanes by Selective Energy Transfer Catalysis: Stereodivergent Synthesis of Triarylethylenes via a Formal anti -Metallometallation

(2019) Svenja I. Faßbender et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Base-Catalyzed 1,1-Silaboration of Terminal Alkynes

(2019) Yiting Gu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances and Perspectives in Transition Metal‐Catalyzed 1,4‐Functionalizations of Unactivated 1,3‐Enynes for the Synthesis of Allenes

(2019) Liang Fu et al.   CHINESE JOURNAL OF CHEMISTRY

Palladium-catalyzed silaborative carbocyclizations of 1,6-diynes

(2018) Qian Zhang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed borylative cyclization of 1,n-enynyl phosphates leading to five- to eight-membered cyclic 1,4-dienyl boronates

(2017) Fang Zhang et al.   TETRAHEDRON LETTERS

Transition metal-catalyzed couplings of alkynes to 1,3-enynes: modern methods and synthetic applications

(2016) Barry M. Trost et al.   CHEMICAL SOCIETY REVIEWS

Borylative Cyclization Reactions

(2016) Elena Buñuel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Intermolecular Three-Component Arylsilylation of Alkynes under Palladium/Copper Cooperative Catalysis

(2016) Ryo Shintani et al.   JOURNAL OF ORGANIC CHEMISTRY

Site-Selective and Stereoselective trans-Hydroboration of 1,3-Enynes Catalyzed by 1,4-Azaborine-Based Phosphine–Pd Complex

(2016) Senmiao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and stereoselective synthesis of conjugated trienes from silaborated 1,3-enynes

(2016) Ende Li et al.   NEW JOURNAL OF CHEMISTRY

Silaborative Carbocyclizations of 1,7-Enynes. Diastereoselective Preparation of Chromane Derivatives

(2016) You-Cai Xiao et al.   ORGANIC LETTERS

Ru(0)-Catalyzed Direct Coupling of Internal Alkynes with Conjugated Dienes: An Efficient Access to Conjugated Trienes

(2016) Sayori Kiyota et al.   ORGANOMETALLICS

Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes

(2015) H. Yoshida et al.   CHEMICAL COMMUNICATIONS

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Catalytic bismetallative multicomponent coupling reactions: scope, applications, and mechanisms

(2014) Hee Yeon Cho et al.   CHEMICAL SOCIETY REVIEWS

Construction of Homoallylic Alcohols from Terminal Alkynes and Aldehydes with Installation of syn-Stereochemistry

(2014) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanogold-Catalyzed cis-Silaboration of Alkynes with Abnormal Regioselectivity

(2014) Charis Gryparis et al.   ORGANIC LETTERS

Preparation of allylboronates by Pd-catalysed borylative cyclisation of dienynes

(2013) Ruth López-Durán et al.   CHEMICAL COMMUNICATIONS

Regio- and Stereoselective Hydrosilylation of 1,3-Enynes Catalyzed by Palladium

(2013) Hui Zhou et al.   ORGANIC LETTERS

Pd-catalyzed borylative cyclisation of 1,7-enynes

(2012) Virtudes Pardo-Rodríguez et al.   CHEMICAL COMMUNICATIONS

Tunable Cross Coupling of Silanols: Selective Synthesis of Heavily Substituted Allenes and Butadienes

(2012) Hui Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

(2011) Yusuke Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Cyclization of Functionalized 1,n-Diynes Mediated by [X−Y] Reagents [X−Y = R3Si−SnR′3or (R2N)2B−SnR′3]: Synthesis and Properties of Atropisomeric 1,3-Dienes

(2010) Ramakrishna Reddy Singidi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Silaborations of 1,3-Enynes − Substrate Controlled Allene/1,3-Diene Selectivity

(2008) Christina Moberg   ORGANIC LETTERS

Pd-Catalyzed Borylative Polycyclization of Enediynes to Allylboronates

(2008) Juan Marco-Martínez et al.   ORGANIC LETTERS