Diastereotopic Group-Selective Intramolecular Aldol Reactions Initiated by Enantioselective Conjugate Silylation: Diastereodivergence Controlled by the Silicon Nucleophile

Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates

(2020) Weichao Xue et al.   ACS Central Science

Enantioselective Synthesis of α-Chiral Propargylic Silanes by Copper-Catalyzed 1,4-Selective Addition of Silicon Nucleophiles to Enyne-Type α,β,γ,δ-Unsaturated Acceptors

(2020) Wenbin Mao et al.   ORGANIC LETTERS

Copper-Catalyzed Borylative Difunctionalization of π-Systems

(2020) Andrew Whyte et al.   ACS Catalysis

Copper-Catalyzed Regio- and Enantioselective Addition of Silicon Grignard Reagents to Alkenes Activated by Azaaryl Groups

(2019) Wenbin Mao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Diastereoselective Synthesis of Functionalized Carbocycles by Cu-Catalyzed Borylative Cyclization of Alkynes with Ketones

(2019) Joseph M. Zanghi et al.   ORGANIC LETTERS

Copper-Catalyzed Carbon–Silicon Bond Formation

(2019) Jake R. Wilkinson et al.   ACS Catalysis

Copper-Catalyzed Functionalization of 1,3-Dienes: Hydrofunctionalization, Borofunctionalization, and Difunctionalization

(2019) Gregory J. P. Perry et al.   ACS Catalysis

Rhodium-Catalyzed Asymmetric Conjugate Alkynylation/Aldol Cyclization Cascade for the Formation of α-Propargyl-β-hydroxyketones

(2018) Ken-Loon Choo et al.   ORGANIC LETTERS

Copper-catalyzed asymmetric silylative cyclization of cyclohexadienone-containing 1,6-enynes

(2018) Cheng-Yu He et al.   TETRAHEDRON

Enantioselective Total Synthesis of Cannogenol-3-O-α-l-rhamnoside via Sequential Cu(II)-Catalyzed Michael Addition/Intramolecular Aldol Cyclization Reactions

(2017) Bijay Bhattarai et al.   ORGANIC LETTERS

Efficient Access to Bicyclo[4.3.0]nonanes: Copper-Catalyzed Asymmetric Silylative Cyclization of Cyclohexadienone-Tethered Allenes

(2015) Zhi-Tao He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed Silylative Allylation of Ketones and Aldehydes Employing Allenes and Silylboranes

(2015) Yosuke Tani et al.   CHEMISTRY LETTERS

Asymmetric Catalysis with Silicon-Based Cuprates: Enantio- and Regioselective Allylic Substitution of Linear Precursors

(2015) Alexander Hensel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cu(I)-NHC-Catalyzed Silylation of Allenes: Diastereoselective Three-Component Coupling with Aldehydes

(2014) James Rae et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Convergent Total Synthesis of 19-Hydroxysarmentogenin

(2013) Ken Mukai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Addition of Nucleophilic Silicon to Aldehydes

(2013) Virginie Cirriez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper(I)-Catalyzed Borylative Aldol Cyclizations of Enone Diones

(2012) Alan R. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Stereocontrolled Domino Reactions

(2012) Hélène Pellissier   CHEMICAL REVIEWS

Desymmetrizing reductive aldol cyclizations of enethioate derivatives of 1,3-diones catalyzed by a chiral copper hydride

(2012) Jun Ou et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles

(2011) Eduard Hartmann et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems

(2011) Christian Kleeberg et al.   CHEMISTRY-A EUROPEAN JOURNAL

An easy route toward enantio-enriched polycyclic derivatives via an asymmetric domino conjugate reduction–aldol cyclization catalyzed by a chiral Cu(I) complex

(2011) Julia Deschamp et al.   TETRAHEDRON

Reductive aldol cyclizations of unsaturated thioester derivatives of 1,3-cyclopentanedione catalyzed by chiral copper hydrides

(2011) Jun Ou et al.   TETRAHEDRON

Copper-Catalysed Domino Silylative Aldol Reaction Leading to Stereocontrolled Chiral Quaternary Carbons

(2010) Alexandre Welle et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!

(2009) Andreas Weickgenannt et al.   CHEMISTRY-A EUROPEAN JOURNAL

B-Alkylcatecholborane-Mediated Tandem Radical Conjugated Addition−Aldol Cyclization

(2009) Alice Beauseigneur et al.   ORGANIC LETTERS

Efficient Construction of Polycyclic Derivatives via a Highly Selective CuI-Catalyzed Domino Reductive-Aldol Cyclization

(2009) Julia Deschamp et al.   ORGANIC LETTERS

CuH-Catalyzed Enantioselective Intramolecular Reductive Aldol Reactions Generating Three New Contiguous Asymmetric Stereocenters

(2008) Bruce H. Lipshutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY