Organic Photoredox-Catalyzed Silyl Radical Generation from Silylboronate

Three-Component Ni-Catalyzed Silylacylation of Alkenes

(2021) Dongshun Ni et al.   ACS Catalysis

Carbene-Catalyzed Alkylation of Carboxylic Esters via Direct Photoexcitation of Acyl Azolium Intermediates

(2021) Shi-Chao Ren et al.   ACS Catalysis

Light‐Driven Carbene Catalysis for the Synthesis of Aliphatic and α‐Amino Ketones

(2021) Anna V. Bay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper‐Photocatalyzed Hydrosilylation of Alkynes and Alkenes under Continuous Flow

(2021) Mingbing Zhong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Regioselective Sila-Acylation and Silaformylation of 1,3-Dienes Using Esters

(2021) Kazutaka Kanayama et al.   JOURNAL OF ORGANIC CHEMISTRY

Generation of Functionalized Alkyl Radicals via the Direct Photoexcitation of 2,2′-(Pyridine-2,6-diyl)diphenol-Based Borates

(2021) Yusuke Miyamoto et al.   ORGANIC LETTERS

HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters

(2021) Martin Oestreich et al.   SYNTHESIS-STUTTGART

Catalyst-free carbosilylation of alkenes using silyl boronates and organic fluorides via selective C-F bond activation

(2021) Jun Zhou et al.   Nature Communications

Aryl radical-mediated N-heterocyclic carbene catalysis

(2021) Yuki Matsuki et al.   Nature Communications

Recent advances in the chemistry and applications of N-heterocyclic carbenes

(2021) Peter Bellotti et al.   Nature Reviews Chemistry

Critical Assessment of the Reducing Ability of Breslow‐type Derivatives and Implications for Carbene‐Catalyzed Radical Reactions**

(2021) Ludivine Delfau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

p-Silylation of Arenes via Organic Photoredox Catalysis: Use of p-Silylated Arenes for Exclusive o-Silylation, o-Acylation, and o-Alkylation Reactions

(2021) Ganesh Pandey et al.   ORGANIC LETTERS

Light-Driven N-Heterocyclic Carbene Catalysis Using Alkylborates

(2021) Yukiya Sato et al.   ACS Catalysis

Direct Photoexcitation of Borate Enabling Minisci Reaction

(2021) Marin Kemmochi et al.   Asian Journal of Organic Chemistry

Combined Photoredox and Carbene Catalysis for the Synthesis of Ketones from Carboxylic Acids

(2020) Karl Scheidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sila- and Germacarboxylic Acids: Precursors for the Corresponding Silyl and Germyl Radicals

(2020) Ning-Xin Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of Alkyl Radical through Direct Excitation of Boracene-Based Alkylborate

(2020) Yukiya Sato et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative NHC and Photoredox Catalysis for the Synthesis of β‐Trifluoromethylated Alkyl Aryl Ketones

(2020) Qing-Yuan Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General Synthesis of Trialkyl- and Dialkylarylsilylboranes: Versatile Silicon Nucleophiles in Organic Synthesis

(2020) Ryosuke Shishido et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Based Catalysis Enabling Cross-Coupling Reactions

(2020) Hirohisa Ohmiya   ACS Catalysis

An Electroreductive Approach to Radical Silylation via the Activation of Strong Si–Cl Bond

(2020) Lingxiang Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes

(2019) Takuya Ishii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Persistent Radical Effect in Organic Synthesis

(2019) Dirk Leifert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes

(2019) Takuya Ishii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Neutral-Eosin-Y-Photocatalyzed Silane Chlorination Using Dichloromethane

(2019) Xuanzi Fan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silaboration of [1.1.1]Propellane: A Storable Feedstock for Bicyclo[1.1.1]pentane Derivatives

(2019) Masaki Kondo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thirty Years of (TMS)3SiH: A Milestone in Radical-Based Synthetic Chemistry

(2018) Chryssostomos Chatgilialoglu et al.   CHEMICAL REVIEWS

Copper-Catalyzed Radical Relay for Asymmetric Radical Transformations

(2018) Fei Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Fifty Years of Hydrosilylation in Polymer Science: A Review of Current Trends of Low-Cost Transition-Metal and Metal-Free Catalysts, Non-Thermally Triggered Hydrosilylation Reactions, and Industrial Applications

(2017) Robin Hofmann et al.   Polymers

Silicon based radicals, radical ions, diradicals and diradicaloids

(2016) Kartik Chandra Mondal et al.   CHEMICAL SOCIETY REVIEWS

Decatungstate-Photocatalyzed Si−H/C−H Activation in Silyl Hydrides: Hydrosilylation of Electron-Poor Alkenes

(2015) Hisham Qrareya et al.   ChemCatChem

Synthesis of silafluorenes and silaindenes via silyl radicals from arylhydrosilanes: intramolecular cyclization and intermolecular annulation with alkynes

(2015) Liang Xu et al.   Organic Chemistry Frontiers

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes

(2008) Timothy A. Boebel et al.   ORGANOMETALLICS