Mechanistic Understanding of Arylation vs Alkylation of Aliphatic Csp3–H Bonds by Decatungstate–Nickel Catalysis

Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)–H Cross-Coupling

(2021) Stavros K. Kariofillis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Photochemical C–H Activation Enables Nickel-Catalyzed Olefin Dicarbofunctionalization

(2021) Mark W. Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Defluorinative sp3 C–H Alkylation of Secondary Amides

(2021) Wen-Jun Yue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid and Direct Photocatalytic C(sp 3 )−H Acylation and Arylation in Flow

(2021) Daniele Mazzarella et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Monovalent Nickel-Mediated Radical Formation: A Concerted Halogen-Atom Dissociation Pathway Determined by Electroanalytical Studies

(2021) Qiao Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Application of Pulse Radiolysis to the Study of Ni(I) Intermediates in Ni-Catalyzed Cross-Coupling Reactions

(2021) Nicholas A. Till et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Alkylation of Aldehydes by Merging TBADT Hydrogen Atom Transfer with Nickel Catalysis

(2021) Vetrivelan Murugesan et al.   ORGANIC LETTERS

On the Nature of C(sp3)–C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides

(2020) Mingbin Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation

(2020) Patrick J. Sarver et al.   Nature Chemistry

Stereoinduction in Metallaphotoredox Catalysis

(2020) Alexander Lipp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C(sp3)–H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow

(2020) Gabriele Laudadio et al.   SCIENCE

Mechanistic Insight into the Photoredox-Nickel-HAT Triple Catalyzed Arylation and Alkylation of α-Amino Csp3–H Bonds

(2020) Bholanath Maity et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iterative Arylation of Amino Acids and Aliphatic Amines via δ-C(sp3 )−H Activation: Experimental and Computational Exploration

(2019) Srimanta Guin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Dual Role of Benzophenone in Visible-Light/Nickel Photoredox-Catalyzed C−H Arylations: Hydrogen-Atom Transfer and Energy Transfer

(2019) Abhishek Dewanji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Oxidative R1-H/R2-H Cross-Coupling with Hydrogen Evolution via Photo-/Electrochemistry

(2019) Huamin Wang et al.   CHEMICAL REVIEWS

A multicomponent synthesis of stereodefined olefins via nickel catalysis and single electron/triplet energy transfer

(2019) Chen Zhu et al.   Nature Catalysis

Regioselective Alkylative Cross-Coupling of Remote Unactivated C(sp3)–H Bonds

(2019) Scott M. Thullen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Cross-Coupling of Allylic C(sp3 )−H Bonds with Aryl- and Vinylbromides by Combined Nickel and Visible-Light Catalysis

(2018) Long Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective C(sp3 )−H Aerobic Oxidation Enabled by Decatungstate Photocatalysis in Flow

(2018) Gabriele Laudadio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative R1-H/R2-H Cross-Coupling with Hydrogen Evolution

(2018) Shan Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

sp3 C–H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts

(2018) Yangyang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct arylation of strong aliphatic C–H bonds

(2018) Ian B. Perry et al.   NATURE

Photocatalytic Activation of Less Reactive Bonds and Their Functionalization via Hydrogen-Evolution Cross-Couplings

(2018) Bin Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Recent Advances in Alkyl Carbon-Carbon Bond Formation by Nickel/Photoredox Cross-Coupling

(2018) Gary Molander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Strong C(sp3)-H Arylation by Synergistic Decatungstate Photo-HAT and Nickel Catalysis

(2018) Dong-Mei Yan et al.   Chem

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer

(2017) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

(2017) Chip Le et al.   NATURE

Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

(2017) Junwon Choi et al.   SCIENCE

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Merging Visible Light Photoredox Catalysis with Metal Catalyzed C–H Activations: On the Role of Oxygen and Superoxide Ions as Oxidants

(2016) David C. Fabry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp3–sp2 Cross-Coupling

(2016) John C. Tellis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Decatungstate Anion for Photocatalyzed “Window Ledge” Reactions

(2016) Davide Ravelli et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Acylation of C(sp3 )−H Bonds Enabled by Nickel and Photoredox Catalysis

(2016) Candice L. Joe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

Recent Advances in C–H Functionalization

(2016) Huw M. L. Davies et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoredox Catalysis in Organic Chemistry

(2016) Megan H. Shaw et al.   JOURNAL OF ORGANIC CHEMISTRY

Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations

(2016) Drew R. Heitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

(2016) Benjamin J. Shields et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides

(2016) Craig P. Johnston et al.   NATURE

Recent advances in dual transition metal–visible light photoredox catalysis

(2016) Balázs L. Tóth et al.   TETRAHEDRON LETTERS

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Switching on elusive organometallic mechanisms with photoredox catalysis

(2015) Jack A. Terrett et al.   NATURE

O-H hydrogen bonding promotes H-atom transfer from   C-H bonds for C-alkylation of alcohols

(2015) J. L. Jeffrey et al.   SCIENCE

Computational study of the mechanism and selectivity of ruthenium-catalyzed hydroamidations of terminal alkynes

(2015) Bholanath Maity et al.   Chemical Science

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Merging photoredox with nickel catalysis: Coupling of  -carboxyl sp3-carbons with aryl halides

(2014) Z. Zuo et al.   SCIENCE

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Secondary Alkyl Halides in Transition-Metal-Catalyzed Cross-Coupling Reactions

(2009) Alena Rudolph et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decatungstate as an efficient photocatalyst in organic chemistry

(2009) Manolis D. Tzirakis et al.   CHEMICAL SOCIETY REVIEWS

A Combined Charge and Energy Decomposition Scheme for Bond Analysis

(2009) Mariusz P. Mitoraj et al.   Journal of Chemical Theory and Computation

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B