C–H Alkylation of Aldehydes by Merging TBADT Hydrogen Atom Transfer with Nickel Catalysis

Nickel-Mediated Enantiospecific Silylation via Benzylic C–OMe Bond Cleavage

(2021) Venkadesh Balakrishnan et al.   ORGANIC LETTERS

Photoinduced Nickel-Catalyzed Deaminative Cross-Electrophile Coupling for C(sp2)–C(sp3) and C(sp3)–C(sp3) Bond Formation

(2021) Tao Yang et al.   ACS Catalysis

Bidentate Directing Groups: An Efficient Tool in C–H Bond Functionalization Chemistry for the Expedient Construction of C–C Bonds

(2020) Supriya Rej et al.   CHEMICAL REVIEWS

Dehydrogenative Coupling of Benzylic and Aldehydic C–H Bonds

(2020) Tairin Kawasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coupling Reaction between Aldehydes and Non-Activated Hydrocarbons via the Reductive Radical-Polar Crossover Pathway

(2020) Kenzo Yahata et al.   ORGANIC LETTERS

Nickel‐Catalyzed Synthesis of Dialkyl Ketones from the Coupling of N‐Alkyl Pyridinium Salts with Activated Carboxylic Acids

(2020) Jiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Cross-Coupling of Alkyl Carboxylic Acid Derivatives with Pyridinium Salts via C–N Bond Cleavage

(2020) Feba Thomas Pulikottil et al.   ORGANIC LETTERS

Acylation of Aryl Halides and α-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis

(2020) Pei Fan et al.   ORGANIC LETTERS

Direct C–H Arylation of Aldehydes by Merging Photocatalyzed Hydrogen Atom Transfer with Palladium Catalysis

(2020) Lu Wang et al.   ACS Catalysis

Temporary or removable directing groups enable activation of unstrained C–C bonds

(2020) Ying Xia et al.   Nature Reviews Chemistry

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

(2020) Supriya Rej et al.   COORDINATION CHEMISTRY REVIEWS

Deaminative Reductive Cross-Electrophile Couplings of Alkylpyridinium Salts and Aryl Bromides

(2019) Jennie Liao et al.   ORGANIC LETTERS

Harnessing Alkylpyridinium Salts as Electrophiles in Deaminative Alkyl–Alkyl Cross-Couplings

(2019) Shane Plunkett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Free Deaminative Functionalizations of Primary Amines by Photoinduced Single-Electron Transfer

(2019) Jingjing Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid Assessment of the Reaction-Condition-Based Sensitivity of Chemical Transformations

(2019) Lena Pitzer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst

(2019) Vyacheslav I. Supranovich et al.   ORGANIC LETTERS

Deaminative Reductive Arylation Enabled by Nickel/Photoredox Dual Catalysis

(2019) Jun Yi et al.   ORGANIC LETTERS

Nickel-catalyzed cross-coupling reaction of carbamates with silylmagnesium reagents

(2019) Vetrivelan Murugesan et al.   JOURNAL OF CATALYSIS

Deaminative Arylation of Amino Acid-derived Pyridinium Salts

(2019) Megan E. Hoerrner et al.   ORGANIC LETTERS

Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins

(2019) Shang-Zheng Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-specific allylic C–H bond functionalization with a copper-bound N-centred radical

(2019) Jiayuan Li et al.   NATURE

Site-selectivity in TBADT-photocatalyzed C(sp3)–H Functionalization of Saturated Alcohols and Alkanes

(2018) Takahide Fukuyama et al.   CHEMISTRY LETTERS

Transforming Benzylic Amines into Diarylmethanes: Cross-Couplings of Benzylic Pyridinium Salts via C–N Bond Activation

(2018) Jennie Liao et al.   ORGANIC LETTERS

Palladium-Catalyzed Synthesis of Diaryl Ketones from Aldehydes and (Hetero)Aryl Halides via C–H Bond Activation

(2018) Takayuki Wakaki et al.   ACS Catalysis

Transient Directing Groups for Transformative C–H Activation by Synergistic Metal Catalysis

(2018) Parthasarathy Gandeepan et al.   Chem

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Photoinduced Deaminative Borylation of Alkylamines

(2018) Jingjing Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct arylation of strong aliphatic C–H bonds

(2018) Ian B. Perry et al.   NATURE

Deaminative Borylation of Aliphatic Amines Enabled by Visible Light Excitation of an Electron Donor-Acceptor Complex

(2018) Frederik Sandfort et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Mediated Deaminative Three-Component Dicarbofunctionalization of Styrenes with Benzylic Radicals

(2018) Felix J. R. Klauck et al.   ACS Catalysis

Direct Aldehyde C–H Arylation and Alkylation via the Combination of Nickel, Hydrogen Atom Transfer, and Photoredox Catalysis

(2017) Xiaheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C–N Bond Activation

(2017) Corey H. Basch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

(2017) Chip Le et al.   NATURE

Photocatalyzed Site-Selective C(sp3)–H Functionalization of Alkylpyridines at Non-Benzylic Positions

(2017) Takahide Fukuyama et al.   ORGANIC LETTERS

Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope

(2017) Davide Ravelli et al.   ACS Catalysis

Direct Acylation of C(sp3 )−H Bonds Enabled by Nickel and Photoredox Catalysis

(2016) Candice L. Joe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Environmentally Benign Acylation

(2016) Basuli Suchand et al.   JOURNAL OF ORGANIC CHEMISTRY

Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations

(2016) Drew R. Heitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

(2016) Benjamin J. Shields et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-selective and stereoselective functionalization of unactivated C–H bonds

(2016) Kuangbiao Liao et al.   NATURE

Unraveling the Key Features of the Reactive State of Decatungstate Anion in Hydrogen Atom Transfer (HAT) Photocatalysis

(2016) Vincent De Waele et al.   ACS Catalysis

Nickel-Catalyzed Borylation of Benzylic Ammonium Salts: Stereospecific Synthesis of Enantioenriched Benzylic Boronates

(2015) Corey H. Basch et al.   ORGANIC LETTERS

N-Heterocyclic Carbene Dichotomy in Pd-Catalyzed Acylation of Aryl Chlorides via C–H Bond Functionalization

(2012) Areli Flores-Gaspar et al.   ORGANIC LETTERS

Acyl Radical Reactions in Fullerene Chemistry: Direct Acylation of [60]Fullerene through an Efficient Decatungstate-Photomediated Approach

(2009) Manolis D. Tzirakis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Intramolecular Acylation of Aryl Bromides via C−H Functionalization: A Highly Efficient Synthesis of Benzocyclobutenones

(2009) Paula Álvarez-Bercedo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Acylation of Aryl Bromides with Aldehydes by Palladium Catalysis

(2008) Jiwu Ruan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY