Primary trifluoroborate-iminiums enable facile access to chiral α-aminoboronic acids via Ru-catalyzed asymmetric hydrogenation and simple hydrolysis of the trifluoroborate moiety

Catalytic Approach to Diverse α‐Aminoboronic Acid Derivatives by Iridium‐Catalyzed Hydrogenation of Trifluoroborate‐Iminiums

(2021) Andrej Šterman et al.   ADVANCED SYNTHESIS & CATALYSIS

Borata‐alkene species as nucleophilic reservoir

(2021) Elena Fernández et al.   ADVANCED SYNTHESIS & CATALYSIS

Photoinduced Borylation for the Synthesis of Organoboron Compounds

(2021) Ya-Ming Tian et al.   CHEMICAL REVIEWS

Saturated boronic acids, boronates, and trifluoroborates: an update on their synthetic and medicinal chemistry

(2021) Dmitriy M. Volochnyuk et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Chiral α-Amino Tertiary Boronates via the Catalytic Enantioselective Nucleophilic Borylation of Dialkyl Ketimines

(2021) Koji Kubota et al.   ACS Catalysis

First-Row d-Block Element-Catalyzed Carbon–Boron Bond Formation and Related Processes

(2021) Shubhankar Kumar Bose et al.   CHEMICAL REVIEWS

Organoboron molecules and polymers for organic solar cell applications

(2021) Junhui Miao et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective catalytic 1,2-boronate rearrangements

(2021) Hayden A. Sharma et al.   SCIENCE

Applications of triarylborane materials in cell imaging and sensing of bio-relevant molecules such as DNA, RNA, and proteins

(2021) Sarina M. Berger et al.   Materials Horizons

Asymmetric Hydrogenation of α-Boryl Enamides Enabled by Nonbonding Interactions

(2020) Dongyang Fan et al.   ACS Catalysis

Arylboronic Acids and their Myriad of Applications Beyond Organic Synthesis

(2020) Noemi de Jesus Hiller et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Stereodivergent Asymmetric Synthesis of α,β-Disubstituted β-Aminoalkylboronic Acid Derivatives via Group-Selective Protodeboronation Enabling Access to the Elusive Anti Isomer

(2020) Xiangyu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Progress on Catalytic Addition Reaction to N-Unsubstituted Imines

(2020) Kazuhiro Morisaki et al.   ACS Catalysis

Synthesis and Applications of β Aminoalkylboronic Acid Derivatives

(2020) Xiangyu Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Acylboron Compounds

(2020) Dino Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and discovery of boronic acid drugs

(2020) Jessica Plescia et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Recent Advances in the Synthesis of Acylboranes and Their Widening Applicability

(2020) Andrej Šterman et al.   ACS Omega

α‐Selective Ring‐Opening Reactions of Bicyclo[1.1.0]butyl Boronic Ester with Nucleophiles

(2020) Varinder Kumar Aggarwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photochemical Radical C‐H Halogenation of Benzyl N‐methyliminodiacetyl (MIDA) boronates as Versatile Platform for α‐Functionalized Alkyl Boronates Synthesis

(2020) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Neues zur Synthese von Aminoboronsäuren

(2020) Franziska Thomas et al.   NACHRICHTEN AUS DER CHEMIE

Fluorinated Aryl Boronates as Building Blocks in Organic Synthesis

(2020) Yudha Budiman et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthetic Chemistry with Lewis Acidity‐Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross‐Couplings

(2020) Shintaro Kamio et al.   ADVANCED SYNTHESIS & CATALYSIS

Dynamic Ion Speciation during the Hydrolysis of Aryltrifluoroborates**

(2020) Isaac Omari et al.   CHEMISTRY-A EUROPEAN JOURNAL

Evading antimicrobial resistance using boron-containing therapeutics

(2020) Komal G Sangu et al.   Future Medicinal Chemistry

Structurally Constrained Boron-, Nitrogen-, Silicon-, and Phosphorus-Centered Polycyclic π-Conjugated Systems

(2019) Masato Hirai et al.   CHEMICAL REVIEWS

Virtues of Volatility: A Facile Transesterification Approach to Boronic Acids

(2019) Stefan P. A. Hinkes et al.   ORGANIC LETTERS

Proteasome Inhibitor Drugs

(2019) Lloyd D. Fricker   Annual Review of Pharmacology and Toxicology

Boron: Its role in energy related research and applications

(2019) Zhenguo Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ru‐Catalyzed Selective C(sp 3 )−H Monoborylation of Amides and Esters

(2019) Wubing Yao et al.   ChemSusChem

Boron in drug design: Recent advances in the development of new therapeutic agents

(2019) Guilherme Felipe Santos Fernandes et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Rhodium-Catalyzed Regiodivergent and Enantioselective Hydroboration of Enamides

(2019) Xiao-Yan Bai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of α-Aminoboronates via Rhodium-Catalyzed Enantioselective C(sp3)–H Borylation

(2019) Ronald L. Reyes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Borono–Strecker Reaction: Synthesis of α-Aminoboronates via a Multicomponent Reaction of Carbonyl Compounds, Amines, and B2pin2

(2019) Wenbo Ming et al.   ORGANIC LETTERS

Cascade CuH-catalysed conversion of alkynes into enantioenriched 1,1-disubstituted products

(2019) De-Wei Gao et al.   Nature Catalysis

Facile synthesis of α-aminoboronic acids from amines and potassium acyltrifluoroborates (KATs) via trifluoroborate-iminiums (TIMs)

(2018) Tomoya Shiro et al.   Chemical Science

A solid-phase approach for the synthesis of α-aminoboronic acid peptides

(2018) Blake E. Daniels et al.   RSC Advances

Copper-boryl mediated organic synthesis

(2018) David Hemming et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Synthesis of α-Amidoboronates Catalyzed by Planar-Chiral NHC-Cu(I) Complexes

(2018) C. Benjamin Schwamb et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ixazomib for the treatment of multiple myeloma

(2018) Paul G. Richardson et al.   EXPERT OPINION ON PHARMACOTHERAPY

Catalytic Homogeneous Asymmetric Hydrogenation: Successes and Opportunities

(2018) Chris S. G. Seo et al.   ORGANOMETALLICS

Charge-Transfer Emitting Triarylborane π-Electron Systems

(2017) Sheng-Yong Li et al.   INORGANIC CHEMISTRY

The versatility of boron in biological target engagement

(2017) Diego B. Diaz et al.   Nature Chemistry

Proteasome inhibitors in cancer therapy

(2017) Elisabet E. Manasanch et al.   Nature Reviews Clinical Oncology

Acylboranes: synthetic strategies and applications

(2017) Florian Korbinian Scharnagl et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent developments in and perspectives on three-coordinate boron materials: a bright future

(2017) Lei Ji et al.   Chemical Science

Doping Polycyclic Aromatics with Boron for Superior Performance in Materials Science and Catalysis

(2017) Esther von Grotthuss et al.   Asian Journal of Organic Chemistry

Recent Developments in Organoboron Chemistry: Old Dogs, New Tricks

(2017) James W.B. Fyfe et al.   Chem

Synthesis and Reactivity of 1,1-Diborylalkanes towards C-C Bond Formation and Related Mechanisms

(2017) Núria Miralles et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Aminoboronic Acid Derivatives from Amines and Amphoteric Boryl Carbonyl Compounds

(2016) Diego B. Diaz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Development of Phosphine-Free "Tethered" Ruthenium(II) Catalysts for the Asymmetric Reduction of Ketones and Imines

(2016) Hans G. Nedden et al.   CHEMICAL RECORD

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

(2016) Emily C. Neeve et al.   CHEMICAL REVIEWS

Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds: Synthetic Routes, Properties, and Applications

(2016) Marcin Stępień et al.   CHEMICAL REVIEWS

Synthesis of α-aminoboronic acids

(2016) Patricia Andrés et al.   CHEMICAL SOCIETY REVIEWS

Solid Phase Synthesis of C-Terminal Boronic Acid Peptides

(2016) Mira A. M. Behnam et al.   ORGANIC LETTERS

Imino Transfer Hydrogenation Reductions

(2016) Martin Wills   Topics in Current Chemistry

Proteasome inhibitors

(2015) Beverly A. Teicher et al.   BIOCHEMICAL PHARMACOLOGY

Recent Developments in the Chemistry and Biological Applications of Benzoxaboroles

(2015) Agnieszka Adamczyk-Woźniak et al.   CHEMICAL REVIEWS

A General Method for Interconversion of Boronic Acid Protecting Groups: Trifluoroborates as Common Intermediates

(2015) Quentin I. Churches et al.   JOURNAL OF ORGANIC CHEMISTRY

Air- and Moisture-Stable Amphoteric Molecules: Enabling Reagents in Synthesis

(2014) Zhi He et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Asymmetric Hydrogenation of Unprotected NH Imines Assisted by a Thiourea

(2014) Qingyang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functional group directed C–H borylation

(2014) A. Ros et al.   CHEMICAL SOCIETY REVIEWS

Asymmetric Synthesis of Protected α-Amino Boronic Acid Derivatives with an Air- and Moisture-Stable Cu(II) Catalyst

(2014) Andrew W. Buesking et al.   JOURNAL OF ORGANIC CHEMISTRY

α-Boryl Isocyanides Enable Facile Preparation of Bioactive Boropeptides

(2013) Adam Zajdlik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Four-coordinate organoboron compounds for organic light-emitting diodes (OLEDs)

(2013) Di Li et al.   CHEMICAL SOCIETY REVIEWS

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Effect of the Substitution Pattern on the Intramolecular Charge-Transfer Emissions in Organoboron-Based Biphenyls, Diphenylacetylenes, and Stilbenes

(2013) Yi-Qiao Yan et al.   Chemistry-An Asian Journal

Boronic Esters in Asymmetric Synthesis

(2013) Donald S. Matteson   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective One-pot Aminoborylation of Aldehydes: A Strategy for Construction of Nonracemic α-Amino Boronates

(2013) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Acid Activation Strategy in Transition-Metal Catalyzed Asymmetric Hydrogenation of N-Unprotected Imines, Enamines, and N-Heteroaromatic Compounds

(2012) Zhengkun Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron Containing Compounds as Protease Inhibitors

(2012) Reem Smoum et al.   CHEMICAL REVIEWS

Trivalent boron nucleophile as a new tool in organic synthesis: reactivity and asymmetric induction

(2012) Jessica Cid et al.   CHEMICAL SOCIETY REVIEWS

A first in human phase I study of the proteasome inhibitor CEP-18770 in patients with advanced solid tumours and multiple myeloma

(2012) Elisa Gallerani et al.   EUROPEAN JOURNAL OF CANCER

Rh-Catalyzed Borylation of N-Adjacent C(sp3)–H Bonds with a Silica-Supported Triarylphosphine Ligand

(2012) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boroalkyl Group Migration Provides a Versatile Entry into α-Aminoboronic Acid Derivatives

(2012) Zhi He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organotrifluoroborate Hydrolysis: Boronic Acid Release Mechanism and an Acid–Base Paradox in Cross-Coupling

(2012) Alastair J. J. Lennox et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Chemoselective and Enantioselective Hydrogenation of (1-Chloro-1-Alkenyl) Boronic Esters

(2011) Ivana Gazić Smilović et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron-containing inhibitors of synthetases

(2011) Stephen J. Baker et al.   CHEMICAL SOCIETY REVIEWS

Hexamethyldisiloxane-based nanoprobes for1H MRI oximetry

(2011) Praveen K. Gulaka et al.   NMR IN BIOMEDICINE

Iron trichloride promoted hydrolysis of potassium organotrifluoroborates

(2011) David W. Blevins et al.   TETRAHEDRON LETTERS

Evaluation of the Proteasome Inhibitor MLN9708 in Preclinical Models of Human Cancer

(2010) E. Kupperman et al.   CANCER RESEARCH

Highlights of Transition Metal-Catalyzed Asymmetric Hydrogenation of Imines

(2010) Nicolas Fleury-Brégeot et al.   ChemCatChem

Natural and Synthetic Small Boron-Containing Molecules as Potential Inhibitors of Bacterial and Fungal Quorum Sensing

(2010) Valery M. Dembitsky et al.   CHEMICAL REVIEWS

Transition Metal-Catalyzed Enantioselective Hydrogenation of Enamines and Imines

(2010) Jian-Hua Xie et al.   CHEMICAL REVIEWS

Boron based anion receptors as sensors

(2010) Ewan Galbraith et al.   CHEMICAL SOCIETY REVIEWS

Iridium−Monodentate Phosphoramidite-Catalyzed Asymmetric Hydrogenation of Substituted Benzophenone N−H Imines

(2010) Guohua Hou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis σ-Bond Dihydrogen and Borane Ruthenium Complexes: Bonding Nature, Catalytic Applications, and Reversible Hydrogen Release

(2009) Gilles Alcaraz et al.   ACCOUNTS OF CHEMICAL RESEARCH

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Therapeutic potential of boron-containing compounds

(2009) Stephen J Baker et al.   Future Medicinal Chemistry

Mosher Amides: Determining the Absolute Stereochemistry of Optically-Active Amines

(2009) Damian A. Allen et al.   JOURNAL OF CHEMICAL EDUCATION

Efficient Hydrolysis of Organotrifluoroborates via Silica Gel and Water

(2009) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY

Observations on the Deprotection of Pinanediol and Pinacol Boronate Esters via Fluorinated Intermediates

(2009) Steven R. Inglis et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Hydrogenation of N−H Imines

(2009) Guohua Hou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Thermal and microwave hydrolysis of organotrifluoroborates mediated by alumina

(2009) George W. Kabalka et al.   TETRAHEDRON LETTERS

Asymmetric Copper-Catalyzed Synthesis of α-Amino Boronate Esters fromN-tert-Butanesulfinyl Aldimines

(2008) Melissa A. Beenen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassium Organotrifluoroborates:  New Perspectives in Organic Synthesis

(2007) Sylvain Darses et al.   CHEMICAL REVIEWS