Synthesis and Reactivity of 1,1-Diborylalkanes towards C-C Bond Formation and Related Mechanisms

Benzyltriboronates: Building Blocks for Diastereoselective Carbon–Carbon Bond Formation

(2017) W. Neil Palmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Tandem Bis-Electrophile Couplings of Diborylmethane

(2017) Stephanie A. Murray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated SN2′ Allyl–Alkyl and Allyl–Boryl Couplings of Vinyl Cyclic Carbonates

(2017) Núria Miralles et al.   ORGANIC LETTERS

Selective uni- and bidirectional homologation of diborylmethane

(2017) Daniel J. Blair et al.   Chemical Science

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

(2017) Lei Li et al.   Nature Communications

Catalytic SN 2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis

(2016) Ying Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Diastereoselective 1,2-Additions to α-Ketoesters with Diborylmethane and Substituted 1,1-Diborylalkanes

(2016) Stephanie A. Murray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed cross-coupling reactions of epoxides with gem-diborylmethane: access to γ-hydroxyl boronic esters

(2016) Ahmed Ebrahim-Alkhalil et al.   CHEMICAL COMMUNICATIONS

Opportunegem-Silylborylation of Carbonyl Compounds: A Modular and Stereocontrolled Entry to Tetrasubstituted Olefins

(2016) Enrico La Cascia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp3)–H Bonds

(2016) W. Neil Palmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Strategic Trimethylsilyldiazomethane Insertion into pinB–SR Followed by Selective Alkylations

(2016) Marc G. Civit et al.   ORGANIC LETTERS

Copper-Catalyzed SN2′-Selective Allylic Substitution Reaction of gem-Diborylalkanes

(2016) Zhen-Qi Zhang et al.   ORGANIC LETTERS

Copper-Catalyzed Diastereoselective Addition of Diborylmethane to N-tert-Butanesulfinyl Aldimines: Synthesis of β-Aminoboronates

(2016) Jinyoung Park et al.   ORGANIC LETTERS

Silver-Assisted, Iridium-Catalyzed Allylation of Bis[(pinacolato)boryl]methane Allows the Synthesis of Enantioenriched Homoallylic Organoboronic Esters

(2016) Miao Zhan et al.   ACS Catalysis

Pd-catalyzed cross-coupling of 1,1-diborylalkanes with aryl triflates

(2016) Long-Can Cui et al.   RSC Advances

Synthesis of 1,1-diboronate esters by cobalt-catalyzed sequential hydroboration of terminal alkynes

(2016) Ziqing Zuo et al.   Organic Chemistry Frontiers

Silver(I)-Catalyzed Diastereoselective Synthesis ofanti-1,2-Hydroxyboronates

(2015) Matthew V. Joannou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes

(2015) Junghoon Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron-selective reactions as powerful tools for modular synthesis of diverse complex molecules

(2015) Liang Xu et al.   CHEMICAL SOCIETY REVIEWS

Enantio- and Diastereoselective Synthesis of 1,2-Hydroxyboronates through Cu-Catalyzed Additions of Alkylboronates to Aldehydes

(2015) Matthew V. Joannou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unsymmetrical 1,1-diborated multisubstituted sp3-carbons formed via a metal-free concerted-asynchronous mechanism

(2015) Ana B. Cuenca et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Vinyl Boronates from Aldehydes by a Practical Boron–Wittig Reaction

(2015) John R. Coombs et al.   ORGANIC LETTERS

Palladium(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with Vinyl Bromides and 1,1-Dibromoalkenes

(2014) Huan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cover Picture: Stereo- and Regioselective Phyllobilane Oxidation in Leaf Homogenates of the Peace Lily (Spathiphyllum wallisii): Hypothetical Endogenous Path to Yellow Chlorophyll Catabolites (Chem. Eur. J. 1/2015)

(2014) Clemens Vergeiner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Synthesis of 1,1-Diborylalkanes through Regioselective Dihydroboration of Terminal Alkynes

(2014) Sumin Lee et al.   Chemistry-An Asian Journal

Nonracemic Allylic Boronates through Enantiotopic-Group-Selective Cross-Coupling of Geminal Bis(boronates) and Vinyl Halides

(2014) Bowman Potter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

(2014) Chunrui Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Access to Elusive α-Boryl Carbanions and Their Alkylation: An Umpolung Construction for Organic Synthesis

(2014) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiomerically Enriched Tris(boronates): Readily Accessible Conjunctive Reagents for Asymmetric Synthesis

(2014) John R. Coombs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed/Promoted Cross-coupling of gem-Diborylalkanes with Nonactivated Primary Alkyl Halides: An Alternative Route to Alkylboronic Esters

(2014) Zhen-Qi Zhang et al.   ORGANIC LETTERS

One-Pot Cross-Coupling of Diborylmethane for the Synthesis of Dithienyl­methane Derivatives

(2014) Kohei Endo et al.   SYNLETT

On the scope of the Pt-catalyzed Srebnik diborylation of diazoalkanes. An efficient approach to chiral tertiary boronic esters and alcohols via B-stabilized carbanions

(2014) Andrew J. Wommack et al.   TETRAHEDRON LETTERS

Regio- and Enantioselective Copper(I)-Catalyzed Hydroboration of Borylalkenes: Asymmetric Synthesis of 1,1-Diborylalkanes

(2013) Xinhui Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formal Carbon Insertion of N-Tosylhydrazone into B–B and B–Si Bonds: gem-Diborylation and gem-Silylborylation of sp3 Carbon

(2013) Huan Li et al.   ORGANIC LETTERS

Asymmetric addition of chiral boron-ate complexes to cyclic iminium ions

(2013) Maziar Mohiti et al.   Chemical Science

Iridium-catalyzed diborylation of benzylic C–H bonds directed by a hydrosilyl group: synthesis of 1,1-benzyldiboronate esters

(2013) Seung Hwan Cho et al.   Chemical Science

Transition-Metal-Free Synthesis of Pinacol Alkylboronates from Tosylhydrazones

(2012) Huan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature

(2012) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper(I)-Catalyzed Boryl Substitution of Unactivated Alkyl Halides

(2012) Hajime Ito et al.   ORGANIC LETTERS

Stereoselective Synthesis of Allylsilanes Bearing Tetrasubstituted Olefin via 2,2-Diborylethylsilane

(2011) Kohei Endo et al.   CHEMISTRY LETTERS

Ate Complexes of Secondary Boronic Esters as Chiral Organometallic-Type Nucleophiles for Asymmetric Synthesis

(2011) Robin Larouche-Gauthier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of Benzylboronates

(2011) Kohei Endo et al.   ORGANIC LETTERS

Formation and Synthetic Applications of Metalated Organoboranes

(2010) Tomasz Klis et al.   CURRENT ORGANIC CHEMISTRY

Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates

(2010) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereospecific Suzuki−Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Cross-Coupling of Secondary Alkyl β-Trifluoroboratoamides

(2010) Deidre L. Sandrock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature

(2010) Kohei Endo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 1,1-Organodiboronates via Rh(I)Cl-Catalyzed Sequential Regioselective Hydroboration of 1-Alkynes

(2009) Kohei Endo et al.   SYNLETT

Diastereoselective Addition of Zincated Hydrazones to Alkenylboronates and Stereospecific Trapping of Boron/Zinc Bimetallic Intermediates by Carbon Electrophiles

(2008) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY