Construction of Axially Chiral Arylborons via Atroposelective Miyaura Borylation

Recent Advances in Catalytic Asymmetric Construction of Atropisomers

(2021) Jun Kee Cheng et al.   CHEMICAL REVIEWS

Stereochemistry and Recent Applications of Axially Chiral Organic Molecules.

(2020) Michele Mancinelli et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Axially Chiral Biaryl Monophosphine Oxides Enabled by Palladium/WJ-Phos-Catalyzed Asymmetric Suzuki–Miyaura Cross-coupling

(2020) Wangqin Ji et al.   ACS Catalysis

Enantioselective Cross-Coupling for Axially Chiral Tetra-ortho-Substituted Biaryls and Asymmetric Synthesis of Gossypol

(2020) He Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific 1,2‐Migrations of Boronate Complexes Induced by Electrophiles

(2020) Hui Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium‐Catalyzed Enantioselective C(sp 3 )‐H Borylation of Cyclobutanes

(2020) Xiang Chen et al.   CHINESE JOURNAL OF CHEMISTRY

Well‐Designed Chiral Ligands for Enantioselective Ir‐Catalyzed C(sp 2 )−H Borylation

(2020) Yin–Xia Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Iridium-Catalyzed Enantioselective α-C(sp3)–H Borylation of Azacycles

(2020) Lili Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium‐Catalyzed Regio‐ and Enantioselective Borylation of Unbiased Methylene C(sp3)‐H Bonds at the Position Beta to a Nitrogen Center

(2020) Rongrong Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium‐Catalyzed Enantioselective Unbiased Methylene C(sp 3 )–H Borylation of Acyclic Amides

(2020) Yuhuan Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Improvement in the Palladium-Catalyzed Miyaura Borylation Reaction by Optimization of the Base: Scope and Mechanistic Study

(2020) Santiago Barroso et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds

(2019) Ronald L. Reyes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Axial Chirality at the Boron–Carbon Bond: Synthesis, Stereodynamic Analysis, and Atropisomeric Resolution of 6-Aryl-5,6-dihydrodibenzo[c,e][1,2]azaborinines

(2019) Andrea Mazzanti et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Enantioselective C(sp3)–H Borylation of Cyclopropanes

(2019) Yongjia Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of α-Aminoboronates via Rhodium-Catalyzed Enantioselective C(sp3)–H Borylation

(2019) Ronald L. Reyes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Axially Chiral Compounds via Asymmetric Organocatalysis

(2018) Yong-Bin Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Atropisomerism in medicinal chemistry: challenges and opportunities

(2018) Sean T Toenjes et al.   Future Medicinal Chemistry

Enantioselective Synthesis of Biaryl Atropisomers via Pd/Norbornene-Catalyzed Three-Component Cross-Couplings

(2018) Linlin Ding et al.   ACS Catalysis

Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis

(2018) Jianhui Chen et al.   Organic Chemistry Frontiers

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

(2018) Jennifer V. Obligacion et al.   Nature Reviews Chemistry

Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis

(2018) Jianhui Chen et al.   CHINESE JOURNAL OF CHEMISTRY

Pd(II)-Catalyzed Enantioselective C(sp3)–H Borylation

(2017) Jian He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic synthesis of axially chiral atropisomers

(2017) P. Renzi   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed B(dan)-Installing Carboboration of Alkenes

(2017) Ikuo Kageyuki et al.   ORGANIC LETTERS

Axially Chiral P,N-Ligands: Some Recent Twists and Turns

(2017) Balaji V. Rokade et al.   ACS Catalysis

Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)

(2017) Hiroto Yoshida et al.   Organic Chemistry Frontiers

Recent Developments in Organoboron Chemistry: Old Dogs, New Tricks

(2017) James W.B. Fyfe et al.   Chem

Development of Cu-Catalyzed Asymmetric Addition of Boron to Olefin

(2016) Yuanyuan Liu et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Axial Chirality about Boron–Carbon Bond: Atropisomeric Azaborines

(2016) Andrea Mazzanti et al.   ORGANIC LETTERS

Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron

(2015) H. Yoshida et al.   CHEMICAL COMMUNICATIONS

Direct introduction of a naphthalene-1,8-diamino boryl [B(dan)] group by a Pd-catalysed selective boryl transfer reaction

(2015) Liang Xu et al.   CHEMICAL COMMUNICATIONS

Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations

(2015) Elango Kumarasamy et al.   CHEMICAL REVIEWS

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Recent Progress on Cu-Catalyzed Asymmetric Conjugate Borylation toα,β-Unsaturated Compounds

(2015) Qiang Liu et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Ligand-Controlled Regiodivergent Cu-Catalyzed Aminoboration of Unactivated Terminal Alkenes

(2015) Ryosuke Sakae et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A twist of nature – the significance of atropisomers in biological systems

(2015) Jamie E. Smyth et al.   NATURAL PRODUCT REPORTS

Organocatalytic Strategies for the Synthesis of Axially Chiral Compounds

(2015) Giorgio Bencivenni   SYNLETT

Configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions: an alternative approach to asymmetric synthesis

(2015) Chao-Yuan Wang et al.   Chemical Science

Regio- and Chemoselective Diboration of Allenes with Unsymmetrical Diboron: Formation of Vinyl and Allyl Boronic Acid Derivatives

(2015) Xi Guo et al.   ACS Catalysis

Stereospecific Couplings of Secondary and Tertiary Boronic Esters

(2014) Daniele Leonori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons

(2014) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

A Clear-Cut Example of Selective BpinBdan Activation and Precise Bdan Transfer on Boron Conjugate Addition

(2014) Jessica Cid et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of Hibarimicinone, a v-Src Tyrosine Kinase Inhibitor Possessing the Pseudo-Dimer Structure of Tetracycline

(2013) Kuniaki Tatsuta et al.   CHEMICAL RECORD

Biological Stereoselectivity of Atropisomeric Natural Products and Drugs

(2013) Arie Zask et al.   CHIRALITY

Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions

(2013) Guangqing Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic methodologies for the β-boration of conjugated electron deficient alkenes

(2012) Adam D. J. Calow et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Fluorescent Sensors: A Tale of BINOL

(2011) Lin Pu   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective formal hydration of α,β-unsaturated acceptors: asymmetric conjugate addition of silicon and boron nucleophiles

(2011) Eduard Hartmann et al.   CHEMICAL COMMUNICATIONS

Revealing Atropisomer Axial Chirality in Drug Discovery

(2011) Steven R. LaPlante et al.   ChemMedChem

Assessing Atropisomer Axial Chirality in Drug Discovery and Development

(2011) Steven R. LaPlante et al.   JOURNAL OF MEDICINAL CHEMISTRY

Enantioselective Conjugate Borylation

(2010) Julia A. Schiffner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

(2010) Noriyuki Iwadate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki−Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations

(2010) Xiaoqiang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of the Palladium-Catalyzed Borylation of Aryl Halides with Pinacolborane

(2010) King Chung Lam et al.   ORGANOMETALLICS

Asymmetric Suzuki-Miyaura Coupling in Water with a Chiral Palladium Catalyst Supported on an Amphiphilic Resin

(2009) Yasuhiro Uozumi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Challenge of Atropisomerism in Drug Discovery

(2009) Jonathan Clayden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions

(2008) Masahiro Terada   CHEMICAL COMMUNICATIONS

C2-Symmetric Bis-Hydrazones as Ligands in the Asymmetric Suzuki−Miyaura Cross-Coupling

(2008) Antonio Bermejo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Knipholone and related 4-phenylanthraquinones: structurally, pharmacologically, and biosynthetically remarkable natural products

(2008) Gerhard Bringmann et al.   NATURAL PRODUCT REPORTS