4.5 Article

Well-Designed Chiral Ligands for Enantioselective Ir-Catalyzed C(sp2)-H Borylation†

Journal

CHINESE JOURNAL OF CHEMISTRY
Volume 38, Issue 12, Pages 1762-1766

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.202000288

Keywords

Enantioselectivity; Iridium; Arenes; C(sp(2))− H borylation; Site‐ selective; Non‐ covalent interaction

Funding

  1. National Natural Science Foundation of China [91856104, 21871145, 21672107]
  2. Tianjin Applied Basic Research Project [19JCZDJC37900]
  3. Cutting-Edge Technology Research Plan [19JCZDJC37900]
  4. Fundamental Research Funds for the Central Universities [63191601]

Ask authors/readers for more resources

Due to the lack of proper chiral ligands, enantioselective C(sp(2))-H borylation has been a challenging goal for a long time. Recently, three different types of well-designed chiral ligands were developed, not only addressing this challenge, but also providing a good inspiration for the future development of other asymmetric reactions.

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