Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

Palladium catalyzed asymmetric Suzuki–Miyaura coupling reactions to axially chiral biaryl compounds: Chiral ligands and recent advances

(2015) Dao Zhang et al.   COORDINATION CHEMISTRY REVIEWS

Fluxionally Chiral DMAP Catalysts: Kinetic Resolution of Axially Chiral Biaryl Compounds

(2014) Gaoyuan Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of Atropisomeric Biaryls: A Cation-Directed Nucleophilic Aromatic Substitution Reaction

(2014) Roly J. Armstrong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Kinetic Resolution of Axially Chiral BINAM Derivatives Catalyzed by a Brønsted Acid

(2014) Dao-Juan Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Atroposelective Aldol Condensation: Synthesis of Axially Chiral Biaryls by Arene Formation

(2014) Achim Link et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes

(2014) Jun Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Kinetic Resolution of 1,1′-Biaryl-2,2′-Diols and Amino Alcohols through NHC-Catalyzed Atroposelective Acylation

(2014) Shenci Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Axially Chiral Biaryls through Sulfoxide-Directed Asymmetric Mild CH Activation and Dynamic Kinetic Resolution

(2014) Chinmoy Kumar Hazra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enzymatic Desymmetrising Redox Reactions for the Asymmetric Synthesis of Biaryl Atropisomers

(2014) Samantha Staniland et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Concise Atroposelective Formal Synthesis of (-)-Steganone

(2014) Boubacar Yalcouye et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in Stereoselective [2+2+2] Cycloadditions

(2014) Muriel Amatore et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioposition-Selective Copper-Catalyzed Azide–Alkyne Cycloaddition for Construction of Chiral Biaryl Derivatives

(2014) Takao Osako et al.   ORGANIC LETTERS

Pd(II)-Catalyzed Intermolecular Direct C–H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution

(2014) De-Wei Gao et al.   ACS Catalysis

Enantioselective Oxidative Coupling of 2-Naphthol Derivatives by Copper-(R)-1,1′-Binaphthyl-2,2′-diamine-TEMPO Catalyst

(2013) Santosh Kumar Alamsetti et al.   ADVANCED SYNTHESIS & CATALYSIS

Atropodiastereoselective CH Olefination of Biphenylp-Tolyl Sulfoxides with Acrylates

(2013) Thomas Wesch et al.   ADVANCED SYNTHESIS & CATALYSIS

Kinetic Resolution of Axially Chiral 2-Amino-1,1′-Biaryls by Phase-Transfer-Catalyzed N-Allylation

(2013) Seiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Benzidine Rearrangement

(2013) Chandra Kanta De et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions

(2013) Guangqing Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Cross-Coupling Strategy for the Asymmetric Synthesis of Axially Chiral Heterobiaryls

(2013) Abel Ros et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of QUINAP via Dynamic Kinetic Resolution

(2013) Vikram Bhat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Multisubstituted Biaryl Skeleton by Chiral Phosphoric Acid Catalyzed Desymmetrization/Kinetic Resolution Sequence

(2013) Keiji Mori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Aryl–Aryl Bond Formation: An Atroposelective [3,3]-Rearrangement Approach to BINAM Derivatives

(2013) Gong-Qiang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Bromine–Lithium Exchange: Application toward the Synthesis of Natural Product

(2013) Julien Graff et al.   ORGANIC LETTERS

Enantioselective Synthesis of Axially Chiral Multifunctionalized Biaryls via Asymmetric Suzuki–Miyaura Coupling

(2013) Yougui Zhou et al.   ORGANIC LETTERS

Aromatic C–H coupling with hindered arylboronic acids by Pd/Fe dual catalysts

(2013) Kazuya Yamaguchi et al.   Chemical Science

Transition-Metal-Free Atropo-Selective Synthesis of Biaryl Compounds Based on Arynes

(2012) Frédéric R. Leroux et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphino Hydrazones as Suitable Ligands in the Asymmetric Suzuki–Miyaura Cross-Coupling

(2012) Abel Ros et al.   JOURNAL OF ORGANIC CHEMISTRY

1,2-Di(phenylethynyl)ethenes with axially chiral, 2,2′-bridged 1,1′-binaphthyl substituents: potent cholesteric liquid-crystal inducers

(2012) Yi-Lin Wu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Construction of the biaryl-part of vancomycin aglycon via atropo-diastereoselective Suzuki–Miyaura coupling

(2012) Timo Leermann et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of 6,6′-Binaphthopyran-2-one Natural Products: Pigmentosin A, Talaroderxines A and B

(2012) Charles I. Grove et al.   ORGANIC LETTERS

Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki–Miyaura Coupling Reactions

(2012) Wenjun Tang et al.   ORGANIC LETTERS

Highly Efficient Synthesis of a Class of Novel Chiral-Bridged Atropisomeric Monophosphine Ligands via Simple Desymmetrization and Their Applications in Asymmetric Suzuki–Miyaura Coupling Reaction

(2012) Shouliang Wang et al.   ORGANIC LETTERS

Total Synthesis of (±)-Decinine via an Oxidative Biaryl Coupling with Defined Axial Chirality

(2012) Zhen-Hua Shan et al.   ORGANIC LETTERS

Enantioselective Total Synthesis of (S)-Bisoranjidiol, an Axially Chiral Bisanthraquinone

(2012) Erin E. Podlesny et al.   ORGANIC LETTERS

Hindered biaryls by C–H coupling: bisoxazoline-Pd catalysis leading to enantioselective C–H coupling

(2012) Kazuya Yamaguchi et al.   Chemical Science

Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki-Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines

(2011) Takeshi Yamamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Chiral and Modifiable Hexahydroxydiphenoyl Compounds

(2011) Noriaki Asakura et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Bromine-Lithium Exchange: A New Tool to Build Axial Chirality

(2010) Quentin Perron et al.   ADVANCED SYNTHESIS & CATALYSIS

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Intramolecular Suzuki-Miyaura Reaction for the Total Synthesis of Signal Peptidase Inhibitors, Arylomycins A2 and B2

(2010) Jeremy Dufour et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent advances in asymmetric oxidative coupling of 2-naphthol and its derivatives

(2010) Hui Wang   CHIRALITY

Total Synthesis of (+)-Korupensamine B via an Atropselective Intermolecular Biaryl Coupling

(2010) Shenlin Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki−Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations

(2010) Xiaoqiang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioenriched Synthesis ofC1-Symmetric BINOLs: Iron-Catalyzed Cross-Coupling of 2-Naphthols and Some Mechanistic Insight

(2010) Hiromichi Egami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Biphenols from 1,4-Diketones by Traceless Central-to-Axial Chirality Exchange

(2010) Fenghai Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Diene as the Ligand for the Synthesis of Axially Chiral Compounds via Palladium-Catalyzed Suzuki−Miyaura Coupling Reaction

(2010) Shu-Sheng Zhang et al.   ORGANIC LETTERS

Highly Effective and Diastereoselective Synthesis of Axially Chiral Bis-sulfoxide Ligands via Oxidative Aryl Coupling

(2010) Qing-An Chen et al.   ORGANIC LETTERS

Dynamic Kinetic Resolution of Biaryl Atropisomers via Peptide-Catalyzed Asymmetric Bromination

(2010) J. L. Gustafson et al.   SCIENCE

Asymmetric Suzuki-Miyaura Coupling in Water with a Chiral Palladium Catalyst Supported on an Amphiphilic Resin

(2009) Yasuhiro Uozumi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dynamic kinetic resolution in the asymmetric synthesis of atropisomeric biaryl[4] and [5]helicene quinones

(2009) Alfonso Latorre et al.   CHEMICAL COMMUNICATIONS

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

Controlling Axial Conformation in 2-Arylpyridines and 1-Arylisoquinolines: Application to the Asymmetric Synthesis of QUINAP by Dynamic Thermodynamic Resolution

(2009) Jonathan Clayden et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Asymmetric Aerobic Oxidation: Oxidative Coupling of 2-Naphthols

(2009) Hiromichi Egami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Axial Chirality Control During Suzuki−Miyaura Cross-Coupling Reactions: Thetert-Butylsulfinyl Group as an Efficient Chiral Auxiliary

(2009) Françoise Colobert et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Enantioselective [2+2+2] Cycloadditions for the Synthesis of Axially Chiral Biaryls

(2008) Ken Tanaka   Chemistry-An Asian Journal

C2-Symmetric Bis-Hydrazones as Ligands in the Asymmetric Suzuki−Miyaura Cross-Coupling

(2008) Antonio Bermejo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyticatropo-Enantioselective Reduction of Biaryl Lactones to Axially Chiral Biaryl Compounds

(2008) Tomoko Ashizawa et al.   ORGANIC LETTERS