Configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions: an alternative approach to asymmetric synthesis

Copper-Catalyzed Asymmetric Three-Component Borylstannation: Enantioselective Formation of CSn Bond

(2015) Tao Jia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reaction Optimization, Scalability, and Mechanistic Insight on the Catalytic Enantioselective Desymmetrization of 1,1-Diborylalkanes via Suzuki-Miyaura Cross-Coupling

(2015) Ho-Yan Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereodivergent Synthesis of Arylcyclopropylamines by Sequential CH Borylation and Suzuki-Miyaura Coupling

(2014) Shin Miyamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific Couplings of Secondary and Tertiary Boronic Esters

(2014) Daniele Leonori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

(2014) Chunrui Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enantiomerically Enriched Triarylmethanes by Enantiospecific Suzuki–Miyaura Cross-Coupling Reactions

(2014) Smitha C. Matthew et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Pd-Catalyzed Cross-Coupling Reactions of Secondary Alkylboron Nucleophiles and Aryl Chlorides

(2014) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Enantioselective Copper(I)-Catalyzed Hydroboration of Borylalkenes: Asymmetric Synthesis of 1,1-Diborylalkanes

(2013) Xinhui Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Configurational Stability of Chiral Heteroatom-Substituted [D1]Methylpalladium Complexes as Intermediates of Stille and Suzuki-Miyaura Cross-Coupling Reactions

(2013) Petra Malova Krizkova et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Preparation and Reactions of Enantiomerically Pure α-Functionalized Grignard Reagents

(2013) Peter J. Rayner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and aryl halides

(2013) Ling Li et al.   Nature Chemistry

Asymmetric transition metal-catalyzed cross-coupling reactions for the construction of tertiary stereocenters

(2013) Elizabeth C. Swift et al.   TETRAHEDRON

Stereospecific Cross-Coupling of Secondary Organotrifluoroborates: Potassium 1-(Benzyloxy)alkyltrifluoroborates

(2012) Gary A. Molander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design and preparation of new palladium precatalysts for C–C and C–N cross-coupling reactions

(2012) Nicholas C. Bruno et al.   Chemical Science

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base

(2011) Christian Amatore et al.   CHEMISTRY-A EUROPEAN JOURNAL

Distinguishing Between Pathways for Transmetalation in Suzuki−Miyaura Reactions

(2011) Brad P. Carrow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ate Complexes of Secondary Boronic Esters as Chiral Organometallic-Type Nucleophiles for Asymmetric Synthesis

(2011) Robin Larouche-Gauthier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters

(2011) Tomotsugu Awano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pinene-Derived Iminodiacetic Acid (PIDA): A Powerful Ligand for Stereoselective Synthesis and Iterative Cross-Coupling of C(sp3) Boronate Building Blocks

(2011) Junqi Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed, Stereoselective, Cyclizative Alkenylboration of Carbon−Carbon Double Bonds through Activation of a Boron−Chlorine Bond

(2011) Masaki Daini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Stereocontrolled Synthesis of α-Amino-α′-alkoxy Ketones by a Copper-Catalyzed Cross-Coupling of Peptidic Thiol Esters and α-Alkoxyalkylstannanes

(2011) Hao Li et al.   ORGANIC LETTERS

Highly Enantioselective Catalytic Dynamic Resolution ofN-Boc-2-lithiopiperidine: Synthesis of (R)-(+)-N-Boc-Pipecolic Acid, (S)-(−)-Coniine, (S)-(+)-Pelletierine, (+)-β-Conhydrine, and (S)-(−)-Ropivacaine and Formal Synthesis of (−)-Lasubine II and (+)-Cermizine C

(2010) Timothy K. Beng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Suzuki−Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Cross-Coupling of Secondary Alkyl β-Trifluoroboratoamides

(2010) Deidre L. Sandrock et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature

(2010) Kohei Endo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids

(2010) Tom Kinzel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly diastereoselective Csp3–Csp2 Negishi cross-coupling with 1,2-, 1,3- and 1,4-substituted cycloalkylzinc compounds

(2010) Tobias Thaler et al.   Nature Chemistry

Pd-catalyzed Cross-Coupling of α-(Acyloxy)-tri-n-butylstannanes with Alkenyl, Aryl, and Heteroaryl Electrophiles

(2010) Mohan Goli et al.   ORGANIC LETTERS

Application of Catalytic Dynamic Resolution ofN-Boc-2-lithiopiperidine to the Asymmetric Synthesis of 2-Aryl and 2-Vinyl Piperidines

(2010) Timothy K. Beng et al.   ORGANIC LETTERS

Secondary Alkyl Halides in Transition-Metal-Catalyzed Cross-Coupling Reactions

(2009) Alena Rudolph et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed N-Arylation of Secondary Acyclic Amides: Catalyst Development, Scope, and Computational Study

(2009) Jacqueline D. Hicks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross Coupling Reactions of Chiral Secondary Organoboronic Esters With Retention of Configuration

(2009) Daisuke Imao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Improved method for the conversion of pinacolboronic esters into trifluoroborate salts: facile synthesis of chiral secondary and tertiary trifluoroborates

(2009) Viktor Bagutski et al.   TETRAHEDRON

A New Class of Easily Activated Palladium Precatalysts for Facile C−N Cross-Coupling Reactions and the Low Temperature Oxidative Addition of Aryl Chlorides

(2008) Mark R. Biscoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols

(2008) Jake L. Stymiest et al.   NATURE

Cu(I)-catalyzed stereospecific coupling reactions of enantioenriched α-stannylated benzyl carbamates and their application

(2008) Heiko Lange et al.   TETRAHEDRON