Chiral Allylic Amine Synthesis Enabled by the Enantioselective CpXRh(III)-Catalyzed Carboaminations of 1,3-Dienes
Published 2021 View Full Article
- Home
- Publications
- Publication Search
- Publication Details
Title
Chiral Allylic Amine Synthesis Enabled by the Enantioselective CpXRh(III)-Catalyzed Carboaminations of 1,3-Dienes
Authors
Keywords
-
Journal
ACS Catalysis
Volume 11, Issue 4, Pages 2279-2287
Publisher
American Chemical Society (ACS)
Online
2021-02-06
DOI
10.1021/acscatal.0c04777
References
Ask authors/readers for more resources
Related references
Note: Only part of the references are listed.- Rhodium(III)-Catalyzed Asymmetric Access to Spirocycles through C−H Activation and Axial-to-Central Chirality Transfer
- (2020) Lingheng Kong et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Diverse Approaches for Enantioselective C–H Functionalization Reactions Using Group 9 CpxMIII Catalysts
- (2020) Tatsuhiko Yoshino et al. CHEMISTRY-A EUROPEAN JOURNAL
- Enantioselective CpxRhIII–Catalyzed Carboaminations of Acrylates
- (2020) Nicolai Cramer et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium(III)‐Catalyzed Atroposelective Synthesis of Biaryls by C−H Activation and Intermolecular Coupling with Sterically Hindered Alkynes
- (2020) Fen Wang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Divergent Synthesis of Tunable Cyclopentadienyl Ligands and Their Application in Rh-Catalyzed Enantioselective Synthesis of Isoindolinone
- (2020) Wen-Jun Cui et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Chiral cyclopentadienyl ligands: design, syntheses and applications in asymmetric catalysis
- (2020) Nicolai Cramer et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Designing a Planar Chiral Rhodium Indenyl Catalyst for Regio- and Enantioselective Allylic C–H Amidation
- (2020) Caitlin M. B. Farr et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Achiral CpxIr(III)/Chiral Carboxylic Acid Catalyzed Enantioselective C–H Amidation of Ferrocenes under Mild Conditions
- (2020) Lei Liu et al. ACS Catalysis
- Cobalt(III)‐Catalyzed Enantioselective Intermolecular Carboaminations via C‒H Functionalizations
- (2020) Nicolai Cramer et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Synthesis of Nitrile Bearing Acyclic Quaternary Centers via Co(III)‐Catalyzed Sequential C–H Bond Addition to Dienes and N‐Cyanosuccinimide
- (2020) Sun Dongbang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium(III)‐Catalyzed Asymmetric [4+1] and [5+1] Annulation of Arenes and 1,3‐Enynes: A Distinct Mechanism of Allyl Formation and Allyl Functionalization
- (2020) Jiaqiong Sun et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Chiral Bicyclo[2.2.2]octane‐Fused CpRh Complexes: Synthesis and Potential Use in Asymmetric C−H Activation
- (2020) Guozhu Li et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Catalytic Enantioselective Functionalizations of C–H Bonds by Chiral Iridium Complexes
- (2020) Łukasz Woźniak et al. CHEMICAL REVIEWS
- An Enantioselective CpxRh(III)-Catalyzed C-H Functionalization / Ring-Opening Route to Chiral Cyclopentenylamines
- (2019) Nicolai Cramer et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Ir-Catalyzed Intermolecular Branch-Selective Allylic C–H Amidation of Unactivated Terminal Olefins
- (2019) Honghui Lei et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective Synthesis of C-N Axially Chiral N-Aryloxindoles by Asymmetric Rhodium-Catalyzed Dual C-H Activation
- (2019) Honghe Li et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Intermolecular, Branch-Selective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C-H Amidation
- (2019) Tobias Knecht et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Efficient Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Exploiting CpX RhIII -Catalyzed C−H Functionalization
- (2019) Marcus Brauns et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Synthesis of Homoallylic Alcohols with Acyclic Quaternary Centers through CoIII -Catalyzed Three-Component C−H Bond Addition to Internally Substituted Dienes and Carbonyls
- (2019) Sun Dongbang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rh(III)-Catalyzed Asymmetric Synthesis of Axially Chiral Biindolyls by Merging C–H Activation and Nucleophilic Cyclization
- (2019) Miaomiao Tian et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Stereoselective β–F Elimination Enabled Redox-Neutral [4 + 1] Annulation via Rh(III)-Catalyzed C–H Activation: Access to Z-Monofluoroalkenyl Dihydrobenzo[d]isoxazole Framework
- (2019) Hui Gao et al. ORGANIC LETTERS
- RhI, IrIII ,and CoIII Complexes with Atropchiral Biaryl Cyclopentadienyl Ligands: Syntheses, Structures, and Catalytic Activities
- (2019) Coralie Duchemin et al. ORGANOMETALLICS
- α-Branched amines by catalytic 1,1-addition of C–H bonds and aminating agents to terminal alkenes
- (2019) Soham Maity et al. Nature Catalysis
- Rhodium-Catalyzed Enantioselective Oxidative [3+2] Annulation of Arenes and Azabicyclic Olefins through Twofold C−H Activation
- (2019) Ruijie Mi et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Intermolecular 1,4-Carboamination of Conjugated Dienes Enabled by Cp*RhIII -Catalyzed C−H Activation
- (2019) Tobias Pinkert et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Asymmetric Alkenyl C−H Functionalization by Cpx RhIII forms 2H -Pyrrol-2-ones through [4+1]-Annulation of Acryl Amides and Allenes
- (2019) Shou-Guo Wang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium(III)-Catalyzed Enantio- and Diastereoselective C−H Cyclopropylation of N-Phenoxylsulfonamides: Combined Experimental and Computational Studies
- (2019) Guangfan Zheng et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Nickel(0)-Catalyzed Hydroalkenylation of Imines with Styrene and Its Derivatives
- (2018) Li-Jun Xiao et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Synthesis of Bifunctional Allylic Compounds using Cyclopropenes as Functionalized Allyl Equivalents
- (2018) Sergio Mata et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A Planar-Chiral Rhodium(III) Catalyst with a Sterically Demanding Cyclopentadienyl Ligand and Its Application in the Enantioselective Synthesis of Dihydroisoquinolones
- (2018) Evgeniya A. Trifonova et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A Readily Accessible Class of Chiral Cp Ligands and their Application in RuII -Catalyzed Enantioselective Syntheses of Dihydrobenzoindoles
- (2018) Shou-Guo Wang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium-Catalyzed Enantioselective Alkenylation of Cyclic Ketimines: Synthesis of Multifunctional Chiral α,α-Disubstituted Allylic Amine Derivatives
- (2018) Yi Li et al. ORGANIC LETTERS
- 2H-Chromene-3-carboxylic Acid Synthesis via Solvent-Controlled and Rhodium(III)-Catalyzed Redox-Neutral C–H Activation/[3 + 3] Annulation Cascade
- (2018) Zhi Zhou et al. ORGANIC LETTERS
- Tailored trisubstituted chiral CpxRhIII catalysts for kinetic resolutions of phosphinic amides
- (2018) Y. Sun et al. Chemical Science
- Rh(III)-Catalyzed and Solvent-Controlled Chemoselective Synthesis of Chalcone and Benzofuran Frameworks via Synergistic Dual Directing Groups Enabled Regioselective C–H Functionalization: A Combined Experimental and Computational Study
- (2018) Wei Yi et al. ACS Catalysis
- Enantioselective Formal C(sp3 )−H Bond Activation in the Synthesis of Bioactive Spiropyrazolone Derivatives
- (2018) Houhua Li et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rhodium(III)-Catalyzed Enantioselective Coupling of Indoles and 7-Azabenzonorbornadienes by C−H Activation/Desymmetrization
- (2018) Xifa Yang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams
- (2017) John H. Conway et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Synthesis of Chiral α,β-Unsaturated γ-Amino Esters via Pd-Catalyzed Asymmetric Allylic Amination
- (2017) Chao Xia et al. ORGANIC LETTERS
- Unnatural Amino Acid Synthesis Enabled by the Regioselective Cobalt(III)-Catalyzed Intermolecular Carboamination of Alkenes
- (2016) Andreas Lerchen et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds
- (2016) Joshua R. Hummel et al. CHEMICAL REVIEWS
- Why is the Ir(III)-Mediated Amido Transfer Much Faster Than the Rh(III)-Mediated Reaction? A Combined Experimental and Computational Study
- (2016) Yoonsu Park et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands
- (2016) Christopher G. Newton et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes
- (2016) Jun Zheng et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Facile Generation and Isolation of π-Allyl Complexes from Aliphatic Alkenes and an Electron-Deficient Rh(III) Complex: Key Intermediates of Allylic C–H Functionalization
- (2016) Yu Shibata et al. ORGANOMETALLICS
- Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations
- (2015) Baihua Ye et al. ACCOUNTS OF CHEMICAL RESEARCH
- Comparative Catalytic Activity of Group 9 [Cp*MIII] Complexes: Cobalt-Catalyzed CH Amidation of Arenes with Dioxazolones as Amidating Reagents
- (2015) Juhyeon Park et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rh(iii)-catalyzed and alcohol-involved carbenoid C–H insertion into N-phenoxyacetamides using α-diazomalonates
- (2015) Jie Zhou et al. CHEMICAL COMMUNICATIONS
- Mechanistic Studies on the Rh(III)-Mediated Amido Transfer Process Leading to Robust C–H Amination with a New Type of Amidating Reagent
- (2015) Yoonsu Park et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Rhodium-catalysed syn-carboamination of alkenes via a transient directing group
- (2015) Tiffany Piou et al. NATURE
- Mild and Efficient Ir(III)-Catalyzed Direct C–H Alkynylation of N-Phenoxyacetamides with Terminal Alkyne
- (2015) Jie Zhou et al. ACS Catalysis
- Asymmetric Synthesis of Isoindolones by Chiral Cyclopentadienyl-Rhodium(III)-Catalyzed CH Functionalizations
- (2014) Baihua Ye et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Rh(III)-Catalyzed Cyclopropanation Initiated by C–H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N-Enoxyphthalimides and Alkenes
- (2014) Tiffany Piou et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Acid-Catalyzed In Situ Generation of Less Accessible or UnprecedentedN-Boc Imines fromN-Boc Aminals
- (2013) Taichi Kano et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Organocatalytic Asymmetric Synthesis of Propargylamines with Two Adjacent Stereocenters: Mannich-Type Reactions of In Situ Generated C-Alkynyl Imines with β-Keto Esters
- (2013) Taichi Kano et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Recent Advances in Organocatalytic Asymmetric Morita–Baylis–Hillman/aza-Morita–Baylis–Hillman Reactions
- (2013) Yin Wei et al. CHEMICAL REVIEWS
- A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides
- (2013) Baihua Ye et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Rhodium(III)-Catalyzed C–H Olefination for the Synthesis of ortho-Alkenyl Phenols Using an Oxidizing Directing Group
- (2013) Yangyang Shen et al. ORGANIC LETTERS
- Rhodium(iii)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines
- (2012) Thomas Cochet et al. CHEMICAL COMMUNICATIONS
- Rh-Catalyzed CC Cleavage of Benzyl/Allylic Alcohols to Produce Benzyl/Allylic Amines or other Alcohols by Nucleophilic Addition of Intermediate Rhodacycles to Aldehydes and Imines
- (2012) Xi-Sha Zhang et al. CHEMISTRY-A EUROPEAN JOURNAL
- Olefinic C–H Bond Addition to Aryl Aldehyde and Its N-Sulfonylimine via Rh Catalysis
- (2012) Yang Li et al. ORGANIC LETTERS
- Allylic Amines as Key Building Blocks in the Synthesis of (E)-Alkene Peptide Isosteres
- (2012) Erin M. Skoda et al. ORGANIC PROCESS RESEARCH & DEVELOPMENT
- Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation
- (2012) T. K. Hyster et al. SCIENCE
- Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization
- (2012) B. Ye et al. SCIENCE
- Asymmetric Strecker Reactions
- (2011) Jun Wang et al. CHEMICAL REVIEWS
- Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions
- (2011) Jimmie D. Weaver et al. CHEMICAL REVIEWS
- Catalytic C–H amination: the stereoselectivity issue
- (2011) Florence Collet et al. CHEMICAL SOCIETY REVIEWS
- Recent advances in transition metal-catalyzed sp3C–H amination adjacent to double bonds and carbonyl groups
- (2011) Thomas A. Ramirez et al. CHEMICAL SOCIETY REVIEWS
- Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution
- (2010) John F. Hartwig et al. ACCOUNTS OF CHEMICAL RESEARCH
- Enantioselective Nickel-Catalyzed Reductive Coupling of Alkynes and Imines
- (2010) Chang-Yue Zhou et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Synthesis of Aziridines by Palladium-Catalyzed Reactions of Allylamines with Aryl and Alkenyl Halides: Evidence of asyn-Carboamination Pathway
- (2009) Sayuri Hayashi et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Discover Peeref hubs
Discuss science. Find collaborators. Network.
Join a conversationPublish scientific posters with Peeref
Peeref publishes scientific posters from all research disciplines. Our Diamond Open Access policy means free access to content and no publication fees for authors.
Learn More