Rh(iii)-catalyzed and alcohol-involved carbenoid C–H insertion into N-phenoxyacetamides using α-diazomalonates

Rh(iii)-catalyzed C–H activation/cyclization of benzamides and diazo compounds to form isocoumarins and α-pyrones

(2015) Xing Guang Li et al.   CHEMICAL COMMUNICATIONS

One-pot cascade synthesis of N-methoxyisoquinolinediones via Rh(iii)-catalyzed carbenoid insertion C–H activation/cyclization

(2015) Jingjing Shi et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

(2015) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Asymmetric Allylic Dearomatization Reactions

(2014) Chun-Xiang Zhuo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Regioselective Synthesis of IndolesviaRhodium-Catalyzed CH Activation Directed by anIn-SituGenerated Redox-Neutral Group

(2014) Krishnamoorthy Muralirajan et al.   ADVANCED SYNTHESIS & CATALYSIS

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

The CH Activation/1,3-Diyne Strategy: Highly Selective Direct Synthesis of Diverse Bisheterocycles by RhIIICatalysis

(2014) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles

(2014) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Transannulation of Cyclopropenes withN-Phenoxyacetamides through CH Activation

(2014) Hang Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Isoindolones by Chiral Cyclopentadienyl-Rhodium(III)-Catalyzed CH Functionalizations

(2014) Baihua Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed CC and CO Coupling of QuinolineN-Oxides with Alkynes: Combination of CH Activation with O-Atom Transfer

(2014) Xueyun Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed direct coupling of biaryl pyridine derivatives with internal alkynes

(2014) Jun Zheng et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed C2-selective carbenoid functionalization and subsequent C7-alkenylation of indoles

(2014) Jingjing Shi et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed C–H activation/[4+3] annulation of N-phenoxyacetamides and α,β-unsaturated aldehydes: an efficient route to 1,2-oxazepines at room temperature

(2014) Pingping Duan et al.   CHEMICAL COMMUNICATIONS

Rh(iii)-catalyzed synthesis of 1-aminoindole derivatives from 2-acetyl-1-arylhydrazines and diazo compounds in water

(2014) Yujie Liang et al.   CHEMICAL COMMUNICATIONS

Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds

(2014) Feng Chen et al.   CHEMICAL REVIEWS

Sesquiterpenoids fromChloranthus henryiand Their Anti-neuroinflammatory Activities

(2014) Li-Jun Wang et al.   CHEMISTRY & BIODIVERSITY

Rhodium(III)- and Iridium(III)-Catalyzed C7 Alkylation of Indolines with Diazo Compounds

(2014) Wen Ai  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed CH Activation and Indole Synthesis With Hydrazone as an Auto-Formed and Auto-Cleavable Directing Group

(2014) Liyao Zheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Intramolecular Redox-Neutral Annulation of Tethered Alkynes: Formal Total Synthesis of (±)-Goniomitine

(2014) Bing Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh(III)-Catalyzed C–H Activation/Cyclization of Indoles and Pyrroles: Divergent Synthesis of Heterocycles

(2014) Yan Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Indolo[2,1-a]isoquinolines via a Triazene-Directed C–H Annulation Cascade

(2014) Huan Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Traceless Coupling of Quinoline N-Oxides with Internal Diarylalkynes

(2014) Upendra Sharma et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators

(2014) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Overcoming the limitations of directed C–H functionalizations of heterocycles

(2014) Yue-Jin Liu et al.   NATURE

Rhodium(iii)-catalyzed formal oxidative [4 + 1] cycloaddition of benzohydroxamic acids and α-diazoesters. A facile synthesis of functionalized benzolactams

(2014) Hon-Wah Lam et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh(III)-Catalyzed Intramolecular Redox-Neutral or Oxidative Cyclization of Alkynes: Short, Efficient Synthesis of 3,4-Fused Indole Skeletons

(2014) Bing Zhou et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–C Bond Formation of Quinoline N-Oxides at the C-8 Position under Mild Conditions

(2014) Jisu Jeong et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Redox-Neutral C–H Activation via N–N Cleavage: Synthesis of N-Substituted Indoles

(2014) Zhenxing Zhang et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Ortho-Alkenylation through C–H Bond Cleavage Directed by Sulfoxide Groups

(2014) Kazunori Nobushige et al.   ORGANIC LETTERS

Isoquinoline skeleton synthesis via chelation-assisted C−H activation

(2014) Ruoyu He et al.   TETRAHEDRON LETTERS

Rhodium(III)-catalyzed synthesis of indoles from 1-alkylidene-2-arylhydrazines and alkynes via C–H and N–N bond cleavages

(2014) Takanori Matsuda et al.   TETRAHEDRON LETTERS

Rh(iii)-catalyzed C–H functionalization/aromatization cascade with 1,3-dienes: a redox-neutral and regioselective access to isoquinolines

(2014) Dongbing Zhao et al.   Chemical Science

Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

(2014) Min Zhang et al.   Organic Chemistry Frontiers

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Isoquinoline Derivatives through Rhodium(III)- Catalyzed Reactions of Benzylamines with Non-Terminal Alkynes

(2013) Dong-Su Kim et al.   ADVANCED SYNTHESIS & CATALYSIS

Indole Synthesis by Rhodium(III)-Catalyzed Hydrazine-Directed CH Activation: Redox-Neutral and Traceless by NN Bond Cleavage

(2013) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Redox-Neutral Coupling ofN-Phenoxyacetamides and Alkynes with Tunable Selectivity

(2013) Guixia Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General and Efficient Synthesis of Indoles through Triazene-Directed C-H Annulation

(2013) Chengming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-CatalyzedorthoAlkenylation ofN-Phenoxyacetamides withN-Tosylhydrazones or Diazoesters through CH Activation

(2013) Fangdong Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Oxide as a Traceless Oxidizing Directing Group: Mild Rhodium(III)-Catalyzed CH Olefination for the Synthesis ofortho-Alkenylated Tertiary Anilines

(2013) Xiaolei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H nitrogenation and oxygenation by ruthenium catalysis

(2013) Vedhagiri S. Thirunavukkarasu et al.   CHEMICAL COMMUNICATIONS

Rhodium(III)-Catalyzed Azacycle-Directed Intermolecular Insertion of Arene C–H Bonds into α-Diazocarbonyl Compounds

(2013) Xinzhang Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

Cross-Coupling Reactions Involving Metal Carbene: From C═C/C–C Bond Formation to C–H Bond Functionalization

(2013) Zhenxing Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed Indole Synthesis Using N–N Bond as an Internal Oxidant

(2013) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Synthesis of Unsymmetrical Acridines and Phenazines by a Rh(III)-Catalyzed Amination/Cyclization/Aromatization Cascade

(2013) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds

(2013) Zhuangzhi Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Directed C–H Cyanation of Arenes with N-Cyano-N-phenyl-p-toluenesulfonamide

(2013) Tian-Jun Gong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation

(2013) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Traceless Directing Strategy: Efficient Synthesis of N-Alkyl Indoles via Redox-Neutral C–H Activation

(2013) Chengming Wang et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–H Olefination for the Synthesis of ortho-Alkenyl Phenols Using an Oxidizing Directing Group

(2013) Yangyang Shen et al.   ORGANIC LETTERS

Rh(iii)-catalyzed C–H activation/[4 + 3] cycloaddition of benzamides and vinylcarbenoids: facile synthesis of azepinones

(2013) Sunliang Cui et al.   Chemical Science

Catalytic Cascade Reactions Involving Metal Carbene Migratory Insertion

(2013) Ying Xia et al.   ACS Catalysis

Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

(2012) Qing Xiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium(III)-Catalyzed Oxidative CH Functionalization of Azomethine Ylides

(2012) Wencui Zhen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed CH Activation and Intermolecular Annulation with Allenes

(2012) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Amide-Directed Tandem CC/CN Bond Formation through CH Activation

(2012) Chen Zhu et al.   Chemistry-An Asian Journal

Cationic Ruthenium Catalysts for Alkyne Annulations with Oximes by C–H/N–O Functionalizations

(2012) Christoph Kornhaaß et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild Rh(III)-Catalyzed C–H Activation and Annulation with Alkyne MIDA Boronates: Short, Efficient Synthesis of Heterocyclic Boronic Acid Derivatives

(2012) Honggen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalyzed regioselective amidation of indoles with sulfonyl azides via C–H bond activation

(2012) Jingjing Shi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative CC and CN Coupling between Oximines and Alkynes

(2011) Xingping Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidizing Directing Groups Enable Efficient and Innovative CH Activation Reactions

(2011) Frederic W. Patureau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tosylhydrazones: New Uses for Classic Reagents in Palladium-Catalyzed Cross-Coupling and Metal-Free Reactions

(2011) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pyridine synthesis from oximes and alkynesviarhodium(iii) catalysis: Cp* and Cptprovide complementary selectivity

(2011) Todd K. Hyster et al.   CHEMICAL COMMUNICATIONS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

N-Tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions

(2011) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

Recent Developments in Pd-Catalyzed Reactions of Diazo Compounds

(2011) Yan Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Substituted diaryldiazomethanes and diazofluorenes: structure, reactivity and stability

(2011) Philip J. Davis et al.   TETRAHEDRON LETTERS

The Vinyl Moiety as a Handle for Regiocontrol in the Preparation of Unsymmetrical 2,3-Aliphatic-Substituted Indoles and Pyrroles

(2010) Malcolm P. Huestis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Terpenoids from the Aerial Parts ofParasenecio deltophylla

(2010) Guo-Du Huang et al.   JOURNAL OF NATURAL PRODUCTS

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes

(2010) Derek J. Schipper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation

(2010) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Alkenylation of Quinoline-N-oxides via C−H Activation under External-Oxidant-Free Conditions

(2009) Junliang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes

(2009) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modulation of Carbene Spin State Population through Precursor Photophysics

(2009) William S. Jenks et al.   ORGANIC LETTERS

On the Most Powerful Chemical Traps for Bis(methoxycarbonyl)carbene (=2-Methoxy-1-(methoxycarbonyl)-2-oxoethylidene)

(2008) Vladimir V. Shevchenko et al.   HELVETICA CHIMICA ACTA

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Recent studies on the reactions of α-diazocarbonyl compounds

(2008) Zhenhua Zhang et al.   TETRAHEDRON