Recent Advances in the Catalytic Functionalization of “Electrophilic” Indoles

Indolylvinyl Ketones: Building Blocks for the Synthesis of Natural Products and Bioactive Compounds

(2019) Olga Serdyuk et al.   SYNTHESIS-STUTTGART

CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence

(2019) Yuxuan Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical Dearomative 2,3-Difunctionalization of Indoles

(2019) Ju Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphine-Catalyzed Enantioselective Dearomative [3+2]-Cycloaddition of 3-Nitroindoles and 2-Nitrobenzofurans

(2019) Huamin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dearomatization of 3-Nitroindoles by a Phosphine-Catalyzed Enantioselective [3+2] Annulation Reaction

(2019) Kaizhi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-Catalyzed Stereoselective Dearomatization of 3-NO2-Indoles with Allenoates

(2019) Alessandro Cerveri et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Asymmetric Dearomatization of 3-Nitroindoles and 3-Nitrobenzothiophenes via Thiol-Triggered Diastereo- and Enantioselective Double Michael Addition Reaction

(2019) Xin-Meng Chen et al.   ORGANIC LETTERS

Phosphine-catalyzed dearomative [3+2] annulation of 3-nitroindoles and allenoates

(2019) Kui Liu et al.   TETRAHEDRON LETTERS

Dearomatization of 3‐Nitroindoles with Highly γ‐Functionalized Allenoates in Formal (3+2) Cycloadditions

(2019) Léo Birbaum et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereodivergent Synthesis of Tetrahydrofuroindoles through Pd-Catalyzed Asymmetric Dearomative Formal [3+2] Cycloaddition

(2018) Qiang Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed C–H functionalization of heteroarenes using indoleBX hypervalent iodine reagents

(2018) Erwann Grenet et al.   Beilstein Journal of Organic Chemistry

Recent advances in spirocyclization of indole derivatives

(2018) Jitender Bariwal et al.   CHEMICAL SOCIETY REVIEWS

Diastereo- and Enantioselective Palladium-Catalyzed Dearomative [3+2] Cycloaddition of 3-Nitroindoles

(2018) Jia-Jia Suo et al.   Chemistry-An Asian Journal

Catalytic Asymmetric Dearomative [3 + 2] Cycloaddition of Electron-Deficient Indoles with All-Carbon 1,3-Dipoles

(2018) Meng Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Asymmetric Dearomative Cycloaddition for Construction of Optically Active Pyrroloindoline and Cyclopentaindoline Derivatives: Access to 3a-Aminopyrroloindolines

(2018) Jun-Qi Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Dearomative Diallylation of N-Acylindoles Mediated by FeCl3

(2018) Ju Wu et al.   ORGANIC LETTERS

Iridium- and Rhodium-Catalyzed Directed C–H Heteroarylation of Benzaldehydes with Benziodoxolone Hypervalent Iodine Reagents

(2018) Erwann Grenet et al.   ORGANIC LETTERS

Metal-Catalyzed Synthesis of Substituted Indoles

(2018) So Won Youn et al.   Asian Journal of Organic Chemistry

Recent Develoments of Transition-Metal Catalyzed Dearomative Cycloadditions using Indoles as Dipolarophiles for the Construction of Indolines

(2018) Guanghao Huang et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidative coupling strategies for the synthesis of indole alkaloids

(2018) Karre Nagaraju et al.   CHEMICAL SOCIETY REVIEWS

Tryptophol and derivatives: natural occurrence and applications to the synthesis of bioactive compounds

(2018) Alessandro Palmieri et al.   NATURAL PRODUCT REPORTS

Recent Advances in the Synthesis of Unsymmetrical Bisindolylmethane Derivatives

(2018) Marino Petrini et al.   SYNTHESIS-STUTTGART

Recent Progress in the Transition Metal Catalyzed Synthesis of Indoles

(2018) Raffaella Mancuso et al.   Catalysts

Bench-Stable Electrophilic Indole and Pyrrole Reagents: Serendipitous Discovery and Use in C-H Functionalization

(2017) Paola Caramenti et al.   HELVETICA CHIMICA ACTA

Pd-Catalyzed Dearomative [3 + 2] Cycloaddition of 3-Nitroindoles with 2-Vinylcyclopropane-1,1-dicarboxylates

(2017) Yi Sing Gee et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent progress in transition-metal-catalyzed enantioselective indole functionalizations

(2017) Jing-Biao Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium(0)-Catalyzed Dearomative [3 + 2] Cycloaddition of 3-Nitroindoles with Vinylcyclopropanes: An Entry to Stereodefined 2,3-Fused Cyclopentannulated Indoline Derivatives

(2017) Maxime Laugeois et al.   ORGANIC LETTERS

Multiple Hydrogen-Bonding Bifunctional Thiourea-Catalyzed Asymmetric Dearomative [4 + 2] Annulation of 3-Nitroindoles: Highly Enantioselective Access to Hydrocarbazole Skeletons

(2017) Deng-Feng Yue et al.   ORGANIC LETTERS

The Diastereoselective Synthesis of Pyrroloindolines by Pd-Catalyzed Dearomative Cycloaddition of 1-Tosyl-2-vinylaziridine to 3-Nitroindoles

(2017) Daniel J. Rivinoja et al.   ACS Catalysis

Advances in Synthetic Applications of Hypervalent Iodine Compounds

(2016) Akira Yoshimura et al.   CHEMICAL REVIEWS

Copper(I)-Catalyzed Asymmetric Dearomatization of Indole Acetamides with 3-Indolylphenyliodonium Salts

(2016) Chuan Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of Heteroaromatic (Aryl)iodonium Imides as I−N Bond-Containing Hypervalent Iodine

(2016) Kazuma Ishida et al.   Chemistry-An Asian Journal

Addition of 4-(cyclohex-1-en-1-yl)morpholine on 3-nitroindole: an unprecedented dearomatizing process

(2016) Manuel Andreini et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stabilized pyrrolyl iodonium salts and metal-free oxidative cross-coupling

(2016) Koji Morimoto et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Lewis Acid and Fluoroalcohol Mediated Nucleophilic Addition to the C2 Position of Indoles

(2016) Naoki Morimoto et al.   ORGANIC LETTERS

Enantioselective dearomative [3 + 2] cycloadditions of indoles with azomethine ylides derived from alanine imino esters

(2016) Anthony L. Gerten et al.   Organic Chemistry Frontiers

Enantioselective Formal [4+2] Cycloadditions to 3-Nitroindoles by Trienamine Catalysis: Synthesis of Chiral Dihydrocarbazoles

(2015) Yang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thiourea-catalyzed dearomatizing [4+2] cycloadditions of 3-nitroindole

(2015) Manuel Andreini et al.   CATALYSIS COMMUNICATIONS

Zn-Catalyzed Diastereo- and Enantioselective Cascade Reaction of 3-Isothiocyanato Oxindoles and 3-Nitroindoles: Stereocontrolled Syntheses of Polycyclic Spirooxindoles

(2015) Jian-Qiang Zhao et al.   ORGANIC LETTERS

Direct Oxidative Coupling ofN-Acetyl Indoles and Phenols for the Synthesis of Benzofuroindolines Related to Phalarine

(2014) Terry Tomakinian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PyBidine/Copper Catalyst: Asymmetricexo′-Selective [3+2] Cycloaddition using Imino Ester and Electrophilic Indole

(2014) Atsuko Awata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular C–H Amination of (Hetero)arenes via Transient Unsymmetrical λ3-Iodanes

(2014) Igors Sokolovs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Dearomative Trimethylenemethane Cycloaddition Reactions

(2014) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilicity: the “dark-side” of indole chemistry

(2013) Marco Bandini   ORGANIC & BIOMOLECULAR CHEMISTRY

Indigo and Tyrian Purple - From Ancient Natural Dyes to Modern Organic Semiconductors

(2012) Eric Daniel Głowacki et al.   ISRAEL JOURNAL OF CHEMISTRY

Indirect C–H Azidation of Heterocycles via Copper-Catalyzed Regioselective Fragmentation of Unsymmetrical λ3-Iodanes

(2012) Dmitrijs Lubriks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophilic Addition of Grignard Reagents to 3–Acylindoles: Stereoselective Synthesis of Highly Substituted Indoline Scaffolds

(2012) Lu Wang et al.   ORGANIC LETTERS

Recent advances in indole syntheses: New routes for a classic target

(2011) Rubén Vicente   ORGANIC & BIOMOLECULAR CHEMISTRY

Nucleophilic Substitution of Hydrogen in Nitroarenes: A New Chapter of Aromatic Chemistry

(2011) Mieczysław Mąkosza   SYNTHESIS-STUTTGART

Nucleophilic substitution of hydrogen in electron-deficient arenes, a general process of great practical value

(2010) Mieczysław Mąkosza   CHEMICAL SOCIETY REVIEWS

Organocatalytic strategies for the asymmetric functionalization of indoles

(2010) Giuseppe Bartoli et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acid catalyzed Friedel–Crafts alkylation reactions

(2009) Shu-Li You et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Asymmetric Friedel−Crafts Alkylation ReactionsCopper Showed the Way

(2008) Thomas B. Poulsen et al.   CHEMICAL REVIEWS