Diastereo- and Enantioselective Palladium-Catalyzed Dearomative [3+2] Cycloaddition of 3-Nitroindoles

A catalyst-free 1,3-dipolar cycloaddition of C,N-cyclic azomethine imines and 3-nitroindoles: an easy access to five-ring-fused tetrahydroisoquinolines

(2017) Xihong Liu et al.   GREEN CHEMISTRY

Pd-Catalyzed Dearomative [3 + 2] Cycloaddition of 3-Nitroindoles with 2-Vinylcyclopropane-1,1-dicarboxylates

(2017) Yi Sing Gee et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Diastereo- and Enantioselective Palladium-Catalyzed [3 + 2] Cycloaddition of Vinyl Epoxides and α,β-Unsaturated Ketones

(2017) Jia-Jia Suo et al.   ORGANIC LETTERS

Palladium(0)-Catalyzed Dearomative [3 + 2] Cycloaddition of 3-Nitroindoles with Vinylcyclopropanes: An Entry to Stereodefined 2,3-Fused Cyclopentannulated Indoline Derivatives

(2017) Maxime Laugeois et al.   ORGANIC LETTERS

Multiple Hydrogen-Bonding Bifunctional Thiourea-Catalyzed Asymmetric Dearomative [4 + 2] Annulation of 3-Nitroindoles: Highly Enantioselective Access to Hydrocarbazole Skeletons

(2017) Deng-Feng Yue et al.   ORGANIC LETTERS

The Diastereoselective Synthesis of Pyrroloindolines by Pd-Catalyzed Dearomative Cycloaddition of 1-Tosyl-2-vinylaziridine to 3-Nitroindoles

(2017) Daniel J. Rivinoja et al.   ACS Catalysis

Palladium-Catalyzed Highly Stereoselective Dearomative [3 + 2] Cycloaddition of Nitrobenzofurans

(2017) Qiang Cheng et al.   Chem

Catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives

(2016) Wen-Ting Wu et al.   CHEMICAL SOCIETY REVIEWS

Highly Stereoselective [3+2] Cycloadditions of Chiral Palladium-ContainingN1-1,3-Dipoles: A Divergent Approach to Enantioenriched Spirooxindoles

(2016) Tian-Ren Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synergistic Catalysis for the Asymmetric [3+2] Cycloaddition of Vinyl Aziridines with α,β-Unsaturated Aldehydes

(2016) Line Naesborg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective dearomative [3 + 2] cycloadditions of indoles with azomethine ylides derived from alanine imino esters

(2016) Anthony L. Gerten et al.   Organic Chemistry Frontiers

Catalytic Asymmetric Dearomatization by Transition-Metal Catalysis: A Method for Transformations of Aromatic Compounds

(2016) Chao Zheng et al.   Chem

Enantioselective Formal [4+2] Cycloadditions to 3-Nitroindoles by Trienamine Catalysis: Synthesis of Chiral Dihydrocarbazoles

(2015) Yang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Dearomatization of Indoles through a Michael/Friedel-Crafts-Type Cascade To Construct Polycyclic Spiroindolines

(2015) Xiaohu Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)-Catalyzed Dearomative Rautenstrauch Rearrangement: Enantioselective Access to Cyclopenta[b]indoles

(2015) Weiwei Zi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Arylative Dearomatization of Indoles via Pd-Catalyzed Intramolecular Reductive Heck Reactions

(2015) Chong Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zn-Catalyzed Diastereo- and Enantioselective Cascade Reaction of 3-Isothiocyanato Oxindoles and 3-Nitroindoles: Stereocontrolled Syntheses of Polycyclic Spirooxindoles

(2015) Jian-Qiang Zhao et al.   ORGANIC LETTERS

Asymmetric Michael/Cyclization Cascade Reaction of 3-Isothiocyanato Oxindoles and 3-Nitroindoles with Amino-Thiocarbamate Catalysts: Enantioselective Synthesis of Polycyclic Spirooxindoles

(2015) Jian-Qiang Zhao et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Asymmetric Allylic Dearomatization Reactions

(2014) Chun-Xiang Zhuo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and α,β-Unsaturated Ketones

(2014) Chao-Fan Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Synthesis of [2,3]-Fused Indoline Heterocycles through Inverse-Electron-Demand Aza-Diels-Alder Reaction of Indoles with Azoalkenes

(2014) Min-Chao Tong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PyBidine/Copper Catalyst: Asymmetricexo′-Selective [3+2] Cycloaddition using Imino Ester and Electrophilic Indole

(2014) Atsuko Awata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Dearomative Trimethylenemethane Cycloaddition Reactions

(2014) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Erythrinane Skeleton via Pd(0)-Catalyzed Intramolecular Dearomatization of para-Aminophenols

(2014) Ren-Qi Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic CC Bonds as Dipolarophiles: Facile Reactions of Uncomplexed Electron-Deficient Benzene Derivatives and Other Aromatic Rings with a Non-Stabilized Azomethine Ylide

(2013) Sunyoung Lee et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-enabled multiple absolute stereocontrol in metal-catalysed cycloaddition for construction of contiguous all-carbon quaternary stereocentres

(2013) Kohsuke Ohmatsu et al.   Nature Chemistry

Concise Synthesis of (+)-allo-Kainic Acid via MgI2-Mediated Tandem Aziridine Ring Opening–Formal [3 + 2] Cycloaddition

(2013) Giada Arena et al.   ORGANIC LETTERS

Application of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids

(2013) Stephen P. Lathrop et al.   Chemical Science

Recent advances in the synthesis of naturally occurring pyrrolidines, pyrrolizidines and indolizidine alkaloids using proline as a unique chiral synthon

(2013) Chinmay Bhat et al.   RSC Advances

Catalytic Asymmetric Dearomatization Reactions

(2012) Chun-Xiang Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Construction of Aryl Pyrroloindolines via an Arylation–Cyclization Cascade

(2012) Shaolin Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Diastereo- and Enantioselective [3+2]-Cycloaddition Reaction of Vinyl Epoxide with Nitroalkenes

(2012) Xue-Long Hou et al.   SYNLETT

Palladium-Mediated Annulation of Vinyl Aziridines with Michael Acceptors: Stereocontrolled Synthesis of Substituted Pyrrolidines and Its Application in a Formal Synthesis of (−)-α-Kainic Acid

(2011) Martin A. Lowe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure, Bioactivity and Synthesis of Natural Products with Hexahydropyrrolo[2,3-b]indole

(2011) Pau Ruiz-Sanchis et al.   CHEMISTRY-A EUROPEAN JOURNAL

A New Dimeric Alkaloid from the Leaf of Psychotria calocarpa

(2010) Hua Zhou et al.   HELVETICA CHIMICA ACTA

Unprotected Vinyl Aziridines: Facile Synthesis and Cascade Transformations

(2009) Sivaraj Baktharaman et al.   ORGANIC LETTERS

Tributylphosphine-Catalyzed Cycloaddition of Aziridines with Carbon Disulfide and Isothiocyanate

(2008) Jing-Yu Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of highly substituted pyrrolidines via palladium-catalyzed cyclization of 5-vinyloxazolidinones and activated alkenes

(2008) Julian G. Knight et al.   TETRAHEDRON