PyBidine/Copper Catalyst: Asymmetricexo′-Selective [3+2] Cycloaddition using Imino Ester and Electrophilic Indole

An Enantioselective Inverse-Electron-Demand Imino Diels-Alder Reaction

(2014) Vincent Eschenbrenner-Lux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Cascade Michael Addition/Cyclization Reactions of 3-Nitro-2H-Chromenes with 3-Isothiocyanato Oxindoles: Efficient Synthesis of Functionalized Polycyclic Spirooxindoles

(2014) Fen Tan et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Imidazoline-Aminophenol (IAP) Nickel Catalyst: Structure and Catalytic Activity in the Enantioselective 1,4-Addition of 3′-Indolyl-3-Oxindoles to Nitroethylene

(2014) Atsuko Awata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic C6 Functionalization of 2,3-Disubstituted Indoles by Scandium Triflate

(2014) Hua Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Diversity-Oriented Asymmetric Catalysis (DOAC): Stereochemically Divergent Synthesis of Thiochromanes Using an Imidazoline–Aminophenol–Nickel-Catalyzed Michael/Henry Reaction

(2014) Takayoshi Arai et al.   ORGANIC LETTERS

Catalytic Enantioselective Synthesis of Functionalized Tropanes Reveals Novel Inhibitors of Hedgehog Signaling

(2013) Rishikesh Narayan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric construction of fluorinated imidazolidines via Cu(i)-catalyzed exo′-selective 1,3-dipolar cycloaddition of azomethine ylides with fluorinated imines

(2013) Qing-Hua Li et al.   CHEMICAL COMMUNICATIONS

Towards the Core Structure ofStrychnosAlkaloids Using Samarium Diiodide-Induced Reactions of Indole Derivatives

(2013) Christine Beemelmanns et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aromatic CC Bonds as Dipolarophiles: Facile Reactions of Uncomplexed Electron-Deficient Benzene Derivatives and Other Aromatic Rings with a Non-Stabilized Azomethine Ylide

(2013) Sunyoung Lee et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Developments in the Catalytic, Asymmetric Construction of Pyrroloindolines Bearing All-Carbon Quaternary Stereocenters

(2013) Lindsay M. Repka et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereodivergent Synthesis of Chiral Fullerenes by [3 + 2] Cycloadditions to C60

(2013) Enrique E. Maroto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilicity: the “dark-side” of indole chemistry

(2013) Marco Bandini   ORGANIC & BIOMOLECULAR CHEMISTRY

Phosphoramidite–Cu(OTf)2 Complexes as Chiral Catalysts for 1,3-Dipolar Cycloaddition of Iminoesters and Nitroalkenes

(2013) Luis M. Castelló et al.   ORGANIC LETTERS

Highly Enantioselective Catalytic [6+3] Cycloadditions of Azomethine Ylides

(2012) Marco Potowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Dearomatization Reactions

(2012) Chun-Xiang Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

syn-Selective Asymmetric Mannich Reaction of Sulfonyl Imines with Iminoesters Catalyzed by the N,N,N-Tridentate Bis(imidazolidine)pyridine (PyBidine)-Cu(OTf)2 Complex

(2012) Takayoshi Arai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric exo′-Selective [3+2] Cycloaddition for Constructing Stereochemically Diversified Spiro[pyrrolidin-3,3′-oxindole]s

(2012) Atsuko Awata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver/ThioClickFerrophos-Catalyzed Enantioselective Conjugate Addition and Cycloaddition of Glycine Imino Ester with Nitroalkenes

(2012) Kazumi Imae et al.   ORGANIC LETTERS

Densely substituted unnatural l- and d-prolines as catalysts for highly enantioselective stereodivergent (3 + 2) cycloadditions and aldol reactions

(2012) Egoitz Conde et al.   Chemical Science

Exploiting the Electrophilic Properties of Indole Intermediates: New Options in Designing Asymmetric Reactions

(2011) Charles C. J. Loh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dearomatization Strategies in the Synthesis of Complex Natural Products

(2011) Stéphane P. Roche et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Novel dipolarophiles and dipoles in the metal-catalyzed enantioselective 1,3-dipolar cycloaddition of azomethine ylides

(2011) Javier Adrio et al.   CHEMICAL COMMUNICATIONS

Update 1 of:C2-Symmetric Chiral Bis(oxazoline) Ligands in Asymmetric Catalysis

(2011) Giovanni Desimoni et al.   CHEMICAL REVIEWS

Structure, Bioactivity and Synthesis of Natural Products with Hexahydropyrrolo[2,3-b]indole

(2011) Pau Ruiz-Sanchis et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereodivergency in Catalytic Asymmetric Conjugate Addition Reactions of Glycine (Ket)imines

(2011) Hun Young Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereocontrolled (3+2) cycloadditions between azomethine ylides and dipolarophiles: a fruitful interplay between theory and experiment

(2011) Abel de Cózar et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Catalytic Asymmetric exo′-Selective [3+2] Cycloaddition of Iminoesters with Nitroalkenes

(2010) Takayoshi Arai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile Dearomatization of Nitrobenzene Derivatives and Other Nitroarenes with N-Benzyl Azomethine Ylide

(2010) Sunyoung Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic strategies for the asymmetric functionalization of indoles

(2010) Giuseppe Bartoli et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of hydrogenated 2,7-dimethylpyrrolo[3,4-b]indoles – analogs of dimebon

(2010) A. V. Ivachtchenko et al.   Chemistry of Heterocyclic Compounds

Cornerstone Works for Catalytic 1,3-Dipolar Cycloaddition Reactions

(2010) Shuji Kanemasa   HETEROCYCLES

Chiral Bis(imidazolidine)pyridine−Cu(OTf)2: Catalytic Asymmetric Endo-Selective [3 + 2] Cycloaddition of Imino Esters with Nitroalkenes

(2010) Takayoshi Arai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly enantioselective synthesis and cellular evaluation of spirooxindoles inspired by natural products

(2010) Andrey P. Antonchick et al.   Nature Chemistry

Recent Advances in the Synthesis of 2-Imidazolines and Their Applications in Homogeneous Catalysis

(2009) Han Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acid catalyzed Friedel–Crafts alkylation reactions

(2009) Shu-Li You et al.   CHEMICAL SOCIETY REVIEWS

An efficient approach to chiral fullerene derivatives by catalytic enantioselective 1,3-dipolar cycloadditions

(2009) Salvatore Filippone et al.   Nature Chemistry

A convenient synthesis of ortho–ortho disubstituted biphenyls containing an eight-membered lactam ring using radical chemistry

(2009) C.H. Wang et al.   TETRAHEDRON LETTERS

Catalytic Asymmetric Friedel−Crafts Alkylation ReactionsCopper Showed the Way

(2008) Thomas B. Poulsen et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions

(2008) Levi M. Stanley et al.   CHEMICAL REVIEWS

Benzofurans as Efficient Dienophiles in Normal Electron Demand [4 + 2] Cycloadditions

(2008) Nathalie Chopin et al.   JOURNAL OF ORGANIC CHEMISTRY