Recent Advances in First-Row Transition Metal/Chiral Phosphoric Acid Combined Catalysis

Recent developments in enantioselective iron-catalyzed transformations

(2019) Hélène Pellissier   COORDINATION CHEMISTRY REVIEWS

Cu/chiral phosphoric acid-catalyzed radical-initiated asymmetric aminosilylation of alkene with hydrosilane

(2019) Yang Zeng et al.   Science China-Chemistry

Palladium(II)-Catalyzed Enantioselective Arylation of Unbiased Methylene C(sp3 )−H Bonds Enabled by a 2-Pyridinylisopropyl Auxiliary and Chiral Phosphoric Acids

(2018) Sheng-Yi Yan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ferrocene as a Privileged Framework for Chiral Organocatalysts

(2018) Jun-Chao Zhu et al.   ChemCatChem

Chiral phosphoric acid catalysis: from numbers to insights

(2018) Rajat Maji et al.   CHEMICAL SOCIETY REVIEWS

Asymmetric Transfer and Pressure Hydrogenation with Earth-Abundant Transition Metal Catalysts

(2018) Zhenfeng Zhang et al.   CHINESE JOURNAL OF CHEMISTRY

Chiral Magnesium Bisphosphate-Catalyzed Asymmetric Double C(sp3)–H Bond Functionalization Based on Sequential Hydride Shift/Cyclization Process

(2018) Keiji Mori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Decarboxylative Alkylation of β-Keto Acids to ortho-Quinone Methides as Reactive Intermediates: Asymmetric Synthesis of 2,4-Diaryl-1-benzopyrans

(2018) Hyun Jung Jeong et al.   ORGANIC LETTERS

Amino- and azidotrifluoromethylation of alkenes

(2018) Yu Tian et al.   TETRAHEDRON LETTERS

Copper-Catalyzed Radical Relay for Asymmetric Radical Transformations

(2018) Fei Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Intramolecular Nicholas Reaction Catalyzed by Chiral Phosphoric Acid: Enantioconvergent Synthesis of Seven-Membered Cyclic Ethers from Racemic Diols

(2018) Yusuke Ota et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Stereoselective SN 1-Type Reactions Promoted by Chiral Phosphoric Acids as Brønsted Acid Catalysts

(2018) Andrea Gualandi et al.   Asian Journal of Organic Chemistry

First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands

(2018) Lukas Alig et al.   CHEMICAL REVIEWS

Cu/Chiral Phosphoric Acid-Catalyzed Asymmetric Three-Component Radical-Initiated 1,2-Dicarbofunctionalization of Alkenes

(2018) Jin-Shun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective α-C-H functionalization of amides with indoles triggered by radical trifluoromethylation of alkenes: Highly selective formation of C CF 3 and C C bonds

(2017) Taotao Li et al.   JOURNAL OF FLUORINE CHEMISTRY

Boosting Chemical Stability, Catalytic Activity, and Enantioselectivity of Metal–Organic Frameworks for Batch and Flow Reactions

(2017) Xu Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Atroposelective Synthesis of Arylpyrroles by Catalytic Asymmetric Paal–Knorr Reaction

(2017) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Phosphate Catalyzed Asymmetric Cross-Dehydrogenative Coupling of 2-Naphthols with β-Ketoesters

(2017) Sachin Narute et al.   ORGANIC LETTERS

Relay Catalysis: Manganese(III) Phosphate Catalyzed Asymmetric Addition of β-Dicarbonyls to ortho-Quinone Methides Generated by Catalytic Aerobic Oxidation

(2017) Konrad Gebauer et al.   ORGANIC LETTERS

Transition metal–catalyzed alkyl-alkyl bond formation: Another dimension in cross-coupling chemistry

(2017) Junwon Choi et al.   SCIENCE

Enantioselective Nazarov cyclization of indole enones cooperatively catalyzed by Lewis acids and chiral Brønsted acids

(2017) Guo-Peng Wang et al.   Chemical Science

Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines

(2017) Jin-Shun Lin et al.   Nature Communications

Catalytic Asymmetric Radical Diamination of Alkenes

(2017) Fu-Li Wang et al.   Chem

Radical cascade reactions triggered by single electron transfer

(2017) Mateusz P. Plesniak et al.   Nature Reviews Chemistry

Silyl-Substituted Planar Chiral Phosphoric Acids with Ferrocene-bridged Paracyclophane Frameworks: Synthesis, Characterization, and Uses in Enantioselective aza-Friedel-Crafts Reactions

(2016) Jérémy Stemper et al.   ADVANCED SYNTHESIS & CATALYSIS

Which Metals are Green for Catalysis? Comparison of the Toxicities of Ni, Cu, Fe, Pd, Pt, Rh, and Au Salts

(2016) Ksenia S. Egorova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Rhodium/Phosphoric Acid Catalysis for the Enantioselective Addition of Oxonium Ylides to ortho -Quinone Methides

(2016) Santosh Kumar Alamsetti et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes

(2016) Robert H. Morris   CHEMICAL REVIEWS

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Enantioconvergent Nucleophilic Substitution Reaction of Racemic Alkyne–Dicobalt Complex (Nicholas Reaction) Catalyzed by Chiral Brønsted Acid

(2016) Masahiro Terada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Oxidative Homocoupling and Cross-Coupling of 2-Naphthols Catalyzed by Chiral Iron Phosphate Complexes

(2016) Sachin Narute et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Allylic C–H Alkylation of Terminal Olefins with Pyrazol-5-ones Enabled by Cooperative Catalysis of Palladium Complex and Brønsted Acid

(2016) Hua-Chen Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Dual-Catalytic Strategy To Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes

(2016) Jin-Shun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric copper-catalyzed C-N cross-couplings induced by visible light

(2016) Q. M. Kainz et al.   SCIENCE

Getting Down to Earth: The Renaissance of Catalysis with Abundant Metals

(2015) Paul Chirik et al.   ACCOUNTS OF CHEMICAL RESEARCH

Stereochemical Communication within a Chiral Ion Pair Catalyst

(2015) Christian Merten et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Organocatalytic Asymmetric Prins Cyclization

(2015) Gavin Chit Tsui et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

Iron/Brønsted Acid Catalyzed Asymmetric Hydrogenation: Mechanism and Selectivity-Determining Interactions

(2015) Kathrin H. Hopmann   CHEMISTRY-A EUROPEAN JOURNAL

Relay Iron/Chiral Brønsted Acid Catalysis: Enantioselective Hydrogenation of Benzoxazinones

(2015) Liang-Qiu Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Asymmetric Amination of Alcohols: From A Mixture of Four Isomers to Diastereo- and Enantiopure α-Branched Amines

(2015) Zi-Qiang Rong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective cooperative catalysis

(2015) Suleman M. Inamdar et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Diamination of Olefins via N–N Bond Activation

(2014) Yingguang Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Organocatalysis Combined with Metal Catalysis: Concept, Proof of Concept, and Beyond

(2014) Dian-Feng Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cooperative Catalysis with Iron and a Chiral Brønsted Acid for Asymmetric Reductive Amination of Ketones

(2014) Shaolin Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Iron Cyclopentadienone Complexes: Discovery, Properties, and Catalytic Reactivity

(2014) Adrien Quintard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective CH Bond Functionalization Triggered by Radical Trifluoromethylation of Unactivated Alkene

(2014) Peng Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted Acid Catalyzed, Conjugate Addition of β-Dicarbonyls to In Situ Generatedortho-Quinone Methides-Enantioselective Synthesis of 4-Aryl-4H-Chromenes

(2014) Osama El-Sepelgy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Prins cyclization: BINOL-derived phosphoric acid and CuCl synergistic catalysis

(2014) Claudia Lalli et al.   CHEMICAL COMMUNICATIONS

Enantioselective Cobalt-Catalyzed Transformations

(2014) Hélène Pellissier et al.   CHEMICAL REVIEWS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Taming Living Carbocations in Catalytic Direct Conjugate Addition of Simple Alkenes to α,β-Enones

(2014) Jian Lv et al.   CHEMISTRY-A EUROPEAN JOURNAL

Planar Chiral Phosphoric Acids with Biphenylene-Tethered Paracyclophane Scaffolds: Synthesis, Characterization, and Catalytic Screening

(2014) Kévin Isaac et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Reactions by Metal and Chiral Phosphoric Acid Sequential Catalysis

(2014) Ze-Peng Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Studies of Highly Enantio- and Diastereoselective Aza-Petasis–Ferrier Rearrangement Catalyzed by Chiral Phosphoric Acid

(2014) Masahiro Terada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation

(2014) Nathan D. Schley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Sc(OTf)3-Catalyzed Transfer Diazenylation of 1,3-Dicarbonyls with Triazenes via N–N Bond Cleavage

(2014) Cong Liu et al.   ORGANIC LETTERS

Development of Chiral Phosphoric Acids based on Ferrocene-Bridged Paracyclophane Frameworks

(2013) Jérémy Stemper et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Synthesis of β-Substituted α-Methylenebutyro- lactonesviaTRIP-Catalyzed Allylation: Mechanistic Studies and Application to the Synthesis of (S)-(−)-Hydroxymatairesinol

(2013) Michael Fuchs et al.   ADVANCED SYNTHESIS & CATALYSIS

Switchable Diastereoselectivity in Enantioselective [4+2] Cycloadditions with Simple Olefins by Asymmetric Binary Acid Catalysis

(2013) Jian Lv et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Copper(II) Phosphate Catalyzed Enantioselective Synthesis of Isochromene Derivatives by Sequential Intramolecular Cyclization and Asymmetric Transfer Hydrogenation ofo-Alkynylacetophenones

(2013) Kodai Saito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Silver Phosphate Catalyzed Transformation ofortho-Alkynylaryl Ketones into 1H-Isochromene Derivatives through an Intramolecular-Cyclization/Enantioselective-Reduction Sequence

(2013) Masahiro Terada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[3,3]Paracyclophanes as planar chiral scaffolds for the synthesis of new phosphoric acids

(2013) Jérémy Stemper et al.   CHEMICAL COMMUNICATIONS

Cooperative Iron-Brønsted Acid Catalysis: Enantioselective Hydrogenation of Quinoxalines and 2 H-1,4-Benzoxazines

(2013) Steffen Fleischer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synergistic Effects between Lewis and Brønsted Acids: Application to the Prins Cyclization

(2013) Martin Breugst et al.   JOURNAL OF ORGANIC CHEMISTRY

Theoretical Study on the Acidities of Chiral Phosphoric Acids in Dimethyl Sulfoxide: Hints for Organocatalysis

(2013) Chen Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of Anti Homoallylic Alcohols from Terminal Alkynes and Aldehydes Based on Concomitant Use of a Cationic Iridium Complex and a Chiral Phosphoric Acid

(2013) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Counteranion-Directed Iron Catalysis: A Highly Enantioselective Sulfoxidation

(2012) Saihu Liao et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Ion-Pairing Catalysis

(2012) Katrien Brak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Counteranion-Directed Catalysis: Concept, Definition, and Applications

(2012) Manuel Mahlau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric binary acid catalysis: chiral phosphoric acid as dual ligand and acid

(2012) Jian Lv et al.   CHEMICAL COMMUNICATIONS

Combining transition metal catalysis and organocatalysis – an update

(2012) Zhenting Du et al.   CHEMICAL SOCIETY REVIEWS

Consecutive Intermolecular Reductive Hydroamination: Cooperative Transition-Metal and Chiral Brønsted Acid Catalysis

(2012) Steffen Fleischer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective tert-Aminocyclization by Asymmetric Binary Acid Catalysis (ABC): Stereospecific 1,5-Hydrogen Transfer

(2012) Liujuan Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Electrophilic α-Bromination of Enecarbamates: Chiral Phosphoric Acid and Calcium Phosphate Salt Catalysts

(2012) Aurélien Alix et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The progression of chiral anions from concepts to applications in asymmetric catalysis

(2012) Robert J. Phipps et al.   Nature Chemistry

Metallic organophosphates as catalysts in asymmetric synthesis: a return journey

(2012) Alejandro Parra et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A novel class of tunable cyclopropanation reagents (RXZnCH2Y) and their synthetic applications

(2012) Richard G. Cornwall et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

(2012) J. R. Zbieg et al.   SCIENCE

Synergistic catalysis: A powerful synthetic strategy for new reaction development

(2012) Anna E. Allen et al.   Chemical Science

Step-Economical Synthesis of Tetrahydroquinolines by Asymmetric Relay Catalytic Friedländer Condensation/Transfer Hydrogenation

(2011) Lei Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Transition-Metal and Chiral Brønsted Acid Catalysis: Enantioselective Hydrogenation of Imines To Form Amines

(2011) Shaolin Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acids in enantioselective carbonyl activations – activation modes and applications

(2011) Magnus Rueping et al.   CHEMICAL SOCIETY REVIEWS

Cooperative Activation of Alkyne and Thioamide Functionalities; Direct Catalytic Asymmetric Conjugate Addition of Terminal Alkynes to α,β-Unsaturated Thioamides

(2011) Ryo Yazaki et al.   Chemistry-An Asian Journal

Developments in Chiral Binaphthyl-Derived Brønsted/Lewis Acids and Hydrogen-Bond-Donor Organocatalysis

(2011) Sebastian Schenker et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cu(I)-Catalyzed Diamination of Conjugated Dienes. Complementary Regioselectivity from Two Distinct Mechanistic Pathways Involving Cu(II) and Cu(III) Species

(2011) Baoguo Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselectively Switchable Enantioselective Trapping of Carbamate Ammonium Ylides with Imines

(2011) Jun Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Highly Substituted Furans by a Copper(II)-Catalyzed Cycloisomerization–Indole Addition Reaction

(2011) Vivek Rauniyar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of a GPR40 Agonist AMG 837 via Catalytic Asymmetric Conjugate Addition of Terminal Alkyne to α,β-Unsaturated Thioamide

(2011) Ryo Yazaki et al.   ORGANIC LETTERS

The Origin of the High Enantioselectivity in Asymmetric Cyclopropanation of Unfunctionalized Olefins

(2010) Yiying Zheng et al.   ADVANCED SYNTHESIS & CATALYSIS

Which Is the Actual Catalyst: Chiral Phosphoric Acid or Chiral Calcium Phosphate?

(2010) Manabu Hatano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Carbon–Carbon Bond Forming Reactions

(2010) Masahiro Terada   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Unifying Metal and Brønsted Acid Catalysis-Concepts, Mechanisms, and Classifications

(2010) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

When Organocatalysis Meets Transition-Metal Catalysis

(2010) Cheng Zhong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Preparation of a Storable Zinc Carbenoid Species and Its Application in Cyclopropanation, Chain Extension, and [2,3]-Sigmatropic Rearrangement Reactions

(2010) Arnaud Voituriez et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu(I)-Catalyzed Regioselective Diamination of Conjugated Dienes via Dual Mechanistic Pathways

(2010) Baoguo Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Conjugate Addition of Terminal Alkynes to α,β-Unsaturated Thioamides

(2010) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

(2010) Masahiro Terada   SYNTHESIS-STUTTGART

Asymmetric Counteranion-Directed Transition-Metal Catalysis: Enantioselective Epoxidation of Alkenes with Manganese(III) Salen Phosphate Complexes

(2009) Saihu Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Construction of Polycyclic Indoles through Olefin Cross-Metathesis/Intramolecular Friedel-Crafts Alkylation under Sequential Catalysis

(2009) Quan Cai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combining transition metal catalysis and organocatalysis: a broad new concept for catalysis

(2009) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

Chiral Brønsted Acid Directed Iron-Catalyzed Enantioselective Friedel-Crafts Alkylation of Indoles with β-Aryl α′-Hydroxy Enones

(2009) Lei Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cu(I)-Catalyzed Diamination of Conjugated Olefins with Tunable Anionic Counterions. A Possible Approach to Asymmetric Diamination

(2009) Baoguo Zhao et al.   JOURNAL OF ORGANIC CHEMISTRY

Double Bond Isomerization/Enantioselective Aza-Petasis−Ferrier Rearrangement Sequence as an Efficient Entry to Anti- and Enantioenriched β-Amino Aldehydes

(2009) Masahiro Terada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Brønsted Acid-CatalyzedN-Acyliminium Cyclization Cascades

(2009) Michael E. Muratore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Consecutive Intramolecular Hydroamination/Asymmetric Transfer Hydrogenation under Relay Catalysis of an Achiral Gold Complex/Chiral Brønsted Acid Binary System

(2009) Zhi-Yong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Synthesis of Chiral Secondary Amines by Gold(I)/Chiral Brønsted Acid Catalyzed Tandem Intermolecular Hydroamination and Transfer Hydrogenation Reactions

(2009) Xin-Yuan Liu et al.   ORGANIC LETTERS

Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon–carbon bond forming reactions

(2008) Masahiro Terada   CHEMICAL COMMUNICATIONS

Chiral Counteranion-Aided Asymmetric Hydrogenation of Acyclic Imines

(2008) Chaoqun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Asymmetric Negishi Cross-Couplings of Secondary Allylic Chlorides with Alkylzincs

(2008) Sunghee Son et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Catalysis with Chiral Brønsted Acid-Rh2(OAc)4: Highly Enantioselective Three-Component Reactions of Diazo Compounds with Alcohols and Imines

(2008) Wenhao Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Relay Catalysis by a Metal-Complex/Brønsted Acid Binary System in a Tandem Isomerization/Carbon−Carbon Bond Forming Sequence

(2008) Keiichi Sorimachi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY