Palladium-Catalyzed Hydroalkylation of Alkynes with Cyclopropanols: Access to γ,δ-Unsaturated Ketones

Redox-Neutral Atom-Economic Pd(0)-Catalyzed Dearomatization of β-Naphthols with Alkynes toward Naphthalenones

(2018) Xinxin Fang et al.   ORGANIC LETTERS

AgII -Mediated Synthesis of β-Fluoroketones by Oxidative Cyclopropanol Opening

(2017) Yuanlin Deng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-catalyzed allylic alkylation with internal alkynes to construct C–C and C–N bonds in water

(2017) Shang Gao et al.   GREEN CHEMISTRY

Copper(i)-catalyzed ring-opening cyanation of cyclopropanols

(2017) Yi-Si Feng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Spiropentadiene Pyrazolones by Rh(III)-Catalyzed Formal sp3 C–H Activation/Annulation

(2017) Jiuan Zheng et al.   ORGANIC LETTERS

Radical Cyclopropanol Ring Opening Initiated Tandem Cyclizations for Efficient Synthesis of Phenanthridines and Oxindoles

(2017) Mingji Dai et al.   SYNLETT

Ring-opening selenation of cyclobutanols: synthesis of γ-selenylated alkyl ketones through C–C bond cleavage

(2017) Mingyang Wang et al.   Organic Chemistry Frontiers

C−C Bond-Forming Strategy by Manganese-Catalyzed Oxidative Ring-Opening Cyanation and Ethynylation of Cyclobutanol Derivatives

(2016) Rongguo Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic σ-activation of carbon–carbon triple bonds: reactions of propargylic alcohols and alkynes

(2016) Rapolu Kiran Kumar et al.   CHEMICAL COMMUNICATIONS

Manganese-catalyzed regiospecific sp3 C–S bond formation through C–C bond cleavage of cyclobutanols

(2016) Rongguo Ren et al.   CHEMICAL COMMUNICATIONS

Alkenylation of Arenes and Heteroarenes with Alkynes

(2016) Vadim P. Boyarskiy et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Rhodium(III)-Catalyzed Mild Alkylation of (Hetero)Arenes with Cyclopropanols via C–H Activation and Ring Opening

(2016) Xukai Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Hydroacylation of Styrenes with Simple Aldehydes: Reaction Development and Mechanistic Insights

(2016) Li-Jun Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic activation of carbon–carbon bonds in cyclopentanones

(2016) Ying Xia et al.   NATURE

C2-Alkylation and Alkenylation of Indoles Catalyzed by a Low-Valent Cobalt Complex in the Absence of Reductant

(2016) Brendan J. Fallon et al.   ORGANIC LETTERS

Palladium-Catalyzed Dearomative Allylic Alkylation of Indoles with Alkynes To Synthesize Indolenines with C3-Quarternary Centers

(2016) Shang Gao et al.   ORGANIC LETTERS

Regioselective Synthesis of Carbonyl-Containing Alkyl Chlorides via Silver-Catalyzed Ring-Opening Chlorination of Cycloalkanols

(2016) Feng-Qing Huang et al.   ORGANIC LETTERS

Cooperative Palladium/Proline-Catalyzed Direct α-Allylic Alkylation of Ketones with Alkynes

(2016) Chi Yang et al.   ORGANIC LETTERS

A New Powerful Approach to Multi-Substituted 3(2H)-Furanones via Brønsted Acid-Catalyzed Reactions of 4-Diazodihydrofuran-3-ones

(2016) Valerij Nikolaev et al.   SYNTHESIS-STUTTGART

Nickel N-Heterocyclic Carbene-Catalyzed C–Heteroatom Bond Formation, Reduction, and Oxidation: Reactions and Mechanistic Aspects

(2016) Vincent Ritleng et al.   ACS Catalysis

Density Functional Study of Nickel N-Heterocyclic Carbene Catalyzed C–O Bond Hydrogenolysis of Methyl Phenyl Ether: The Concerted β-H Transfer Mechanism

(2016) Taveechai Wititsuwannakul et al.   ACS Catalysis

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Regiospecific synthesis of distally chlorinated ketones via C–C bond cleavage of cycloalkanols

(2016) Xuefeng Fan et al.   Organic Chemistry Frontiers

Manganese-Catalyzed Oxidative Azidation of Cyclobutanols: Regiospecific Synthesis of Alkyl Azides by CC Bond Cleavage

(2015) Rongguo Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple access to β-trifluoromethyl-substituted ketones via copper-catalyzed ring-opening trifluoromethylation of substituted cyclopropanols

(2015) Dzmitry G. Kananovich et al.   CHEMICAL COMMUNICATIONS

Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals

(2015) Laetitia Souillart et al.   CHEMICAL REVIEWS

Silver-Catalyzed Ring-Opening Strategy for the Synthesis of β- and γ-Fluorinated Ketones

(2015) Huijun Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalysed ring-opening trifluoromethylation of cyclopropanols

(2015) Xia-Ping He et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

(2015) Shichao Ren et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

An Umpolung Strategy for the Synthesis of β-Aminoketones via Copper-Catalyzed Electrophilic Amination of Cyclopropanols

(2015) Zhishi Ye et al.   ORGANIC LETTERS

Copper-Catalyzed Cyclopropanol Ring Opening Csp3–Csp3 Cross-Couplings with (Fluoro)Alkyl Halides

(2015) Zhishi Ye et al.   ORGANIC LETTERS

Efficient Synthesis of β-CF3/SCF3-Substituted Carbonyls via Copper-Catalyzed Electrophilic Ring-Opening Cross-Coupling of Cyclopropanols

(2015) Yong Li et al.   ORGANIC LETTERS

Alkynylation of Tertiary Cycloalkanols via Radical C–C Bond Cleavage: A Route to Distal Alkynylated Ketones

(2015) Shun Wang et al.   ORGANIC LETTERS

Palladium-Catalyzed Cross-Coupling Reactions of Cyclopropanols

(2015) Arturo Orellana et al.   SYNLETT

Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C–H Activation and Ring Opening

(2015) Xukai Zhou et al.   ACS Catalysis

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Highly Enantioselective Rhodium(I)-Catalyzed Activation of Enantiotopic Cyclobutanone CC Bonds

(2014) Laetitia Souillart et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes

(2014) Joseph S. Bair et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative activation of cyclobutanones and olefins leads to bridged ring systems by a catalytic [4 + 2] coupling

(2014) Haye Min Ko et al.   Nature Chemistry

Palladium-Catalyzed Cross-Coupling of Benzyl Chlorides with Cyclopropanol-Derived Ketone Homoenolates

(2014) Nisha Nithiy et al.   ORGANIC LETTERS

Asymmetric Rhodium(I)-Catalyzed C–C Activations with Zwitterionic Bis-phospholane Ligands

(2014) Evelyne Parker et al.   ORGANOMETALLICS

Computational Study of Carbostannylation Implicating Bimetallic Catalysis Involving “AuI–Vinyl–PdII” Species

(2014) Alireza Ariafard et al.   ACS Catalysis

Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides

(2013) David Rosa et al.   CHEMICAL COMMUNICATIONS

Arylation of Aldehyde Homoenolates with Aryl Bromides

(2013) Kevin Cheng et al.   ORGANIC LETTERS

C-Acylation of Cyclopropanols: Preparation of Functionalized 1,4-Diketones

(2013) Bibhuti Bhusan Parida et al.   ORGANIC LETTERS

Rh-Catalyzed CC Cleavage of Benzyl/Allylic Alcohols to Produce Benzyl/Allylic Amines or other Alcohols by Nucleophilic Addition of Intermediate Rhodacycles to Aldehydes and Imines

(2012) Xi-Sha Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-catalyzed C-C Bond Cleavage Reactions - An Update

(2012) Ales Korotvicka et al.   CURRENT ORGANIC CHEMISTRY

Highly Enantioselective Rh-Catalyzed Carboacylation of Olefins: Efficient Syntheses of Chiral Poly-Fused Rings

(2012) Tao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Pyridinyl Directed Alkenylation with Olefins via Rh(III)-Catalyzed C–C Bond Cleavage of Secondary Arylmethanols

(2011) Hu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-catalysed cleavage of carbon–carbon bonds

(2010) Masahiro Murakami et al.   CHEMICAL COMMUNICATIONS

Functionalization of Organic Molecules by Transition-Metal-Catalyzed C(sp3)H Activation

(2010) Rodolphe Jazzar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper Catalyzed Arylation/C−C Bond Activation: An Approach toward α-Aryl Ketones

(2010) Chuan He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Substitution Reactions of Propargylic Amines: Importance of C(sp)−C(sp3) Bond Cleavage in Generation of Iminium Intermediates

(2010) Tsuyuka Sugiishi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Decarboxylative Coupling of 2-Phenylbenzoic Acids with Alkynes via C−H and C−C Bond Activation

(2010) Congyang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Cross-Coupling of Cyclopropanols with Aryl Halides Under Mild Conditions

(2010) David Rosa et al.   ORGANIC LETTERS

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Carboauration of Alkynes and Palladium/Gold Cross-Coupling

(2009) Yili Shi et al.   ORGANOMETALLICS

Combining the Concepts: Dual Catalysis with Carbophilic Lewis Acids

(2008) Alexander Duschek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective CC Bond Activation of Allenyl Cyclobutanes: Access to Cyclohexenones with Quaternary Stereogenic Centers

(2008) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkynes as Stille Reaction Pseudohalides:  Gold- and Palladium-Cocatalyzed Synthesis of Tri- and Tetra-Substituted Olefins

(2008) Yili Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY