Copper-catalysed ring-opening trifluoromethylation of cyclopropanols

Simple access to β-trifluoromethyl-substituted ketones via copper-catalyzed ring-opening trifluoromethylation of substituted cyclopropanols

(2015) Dzmitry G. Kananovich et al.   CHEMICAL COMMUNICATIONS

Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes

(2015) Concepción Alonso et al.   CHEMICAL REVIEWS

Silver-Catalyzed Ring-Opening Strategy for the Synthesis of β- and γ-Fluorinated Ketones

(2015) Huijun Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

(2015) Shichao Ren et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Efficient Synthesis of β-CF3/SCF3-Substituted Carbonyls via Copper-Catalyzed Electrophilic Ring-Opening Cross-Coupling of Cyclopropanols

(2015) Yong Li et al.   ORGANIC LETTERS

Oxidative Trifluoromethylation and Trifluoromethylthiolation Reactions Using (Trifluoromethyl)trimethylsilane as a Nucleophilic CF3 Source

(2014) Lingling Chu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Practical Methods for the Synthesis of Trifluoromethylated Alkynes: Oxidative Trifluoromethylation of Copper Acetylides and Alkynes

(2014) Cédric Tresse et al.   ADVANCED SYNTHESIS & CATALYSIS

Application of Langlois’ Reagent in Trifluoromethylation Reactions

(2014) Cai Zhang   ADVANCED SYNTHESIS & CATALYSIS

Trifluoromethylation of Alkenes with Concomitant Introduction of Additional Functional Groups

(2014) Hiromichi Egami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylation of arenediazonium salts with fluoroform-derived CuCF3in aqueous media

(2014) Anton Lishchynskyi et al.   CHEMICAL COMMUNICATIONS

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

(2014) Xiu-Hua Xu et al.   CHEMICAL REVIEWS

Trifluoromethyltrimethylsilane: Nucleophilic Trifluoromethylation and Beyond

(2014) Xiao Liu et al.   CHEMICAL REVIEWS

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

1-Trifluoromethylated isoquinolines via radical trifluoromethylation of isonitriles

(2014) Bo Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents

(2014) Cai Zhang   ORGANIC & BIOMOLECULAR CHEMISTRY

2-Trifluoromethylated Indoles via Radical Trifluoromethylation of Isonitriles

(2014) Bo Zhang et al.   ORGANIC LETTERS

Copper-mediated trifluoromethylation of potassium alkynyltrifluoroborates with Langlois' reagent

(2014) Srinivas Reddy Dubbaka et al.   TETRAHEDRON

Trifluoromethylation by Visible-Light-Driven Photoredox Catalysis

(2014) Takashi Koike et al.   TOPICS IN CATALYSIS

Sandmeyer Trifluoromethylation of Arenediazonium Tetrafluoroborates

(2013) Grégory Danoun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Controlled Trifluoromethylation Reactions of Alkynes through Visible-Light Photoredox Catalysis

(2013) Naeem Iqbal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

(2013) Zhi-Min Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Trifluoromethylating Sandmeyer Reaction: A Method for Transforming CN into CCF3

(2013) Duncan L. Browne   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation-Initiated Radical 1,2-Aryl Migration in α,α-Diaryl Allylic Alcohols

(2013) Xiaowu Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective 1,4-trifluoromethylation of α,β-unsaturated ketones via aS-(trifluoromethyl)diphenylsulfonium salts/copper system

(2013) Satoshi Okusu et al.   Beilstein Journal of Organic Chemistry

Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides

(2013) David Rosa et al.   CHEMICAL COMMUNICATIONS

Direct Synthesis of a Trifluoromethyl Copper Reagent from Trifluoromethyl Ketones: Application to Trifluoromethylation

(2013) Hiroki Serizawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of β-CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed isomerization

(2013) Vincent Bizet et al.   JOURNAL OF FLUORINE CHEMISTRY

Regio- and Stereoselective Allylic Trifluoromethylation and Fluorination using CuCF3 and CuF Reagents

(2013) Johanna M. Larsson et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation

(2013) Václav Matoušek et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Promoted Sandmeyer Trifluoromethylation Reaction

(2013) Jian-Jun Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group

(2013) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A sterically demanding organo-superbase avoids decomposition of a naked trifluoromethyl carbanion directly generated from fluoroform

(2013) Hiroyuki Kawai et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Trifluoromethylation of Allylsilanes under Photoredox Catalysis

(2013) Satoshi Mizuta et al.   ORGANIC LETTERS

γ-Carbonyl Quinones: Radical Strategy for the Synthesis of Evelynin and Its Analogues by C–H Activation of Quinones Using Cyclopropanols

(2013) Andivelu Ilangovan et al.   ORGANIC LETTERS

Fluoroform-Derived CuCF3for Low-Cost, Simple, Efficient, and Safe Trifluoromethylation of Aryl Boronic Acids in Air

(2012) Petr Novák et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation of Allylsilanes

(2012) Ryo Shimizu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SN2′ Alkylation of Cyclopropanols via Homoenolates

(2012) Pragna Pratic Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Promoted Trifluoromethylation of Primary and Secondary Alkylboronic Acids

(2012) Jun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tamed Arene and Heteroarene Trifluoromethylation

(2012) Tatiana Besset et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

(2012) Yi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Partially saturated fluorinated heterocycles: diastereo- and enantioselective synthesis of β-trifluoromethyl-pyrroline carboxylates

(2012) Hiroyuki Kawai et al.   CHEMICAL COMMUNICATIONS

Organic base-catalyzed stereodivergent synthesis of (R)- and (S)-3-amino-4,4,4-trifluorobutanoic acids

(2012) Norio Shibata et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Nucleophilic Trifluoromethylation of Allylic Halides: A Simple Approach to Allylic Trifluoromethylation

(2012) Yoshihiro Miyake et al.   CHEMISTRY-A EUROPEAN JOURNAL

The New Age of Electrophilic Perfluoro­alk­ylation Reactions

(2012) Yohan Macé et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis

(2012) Naeem Iqbal et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkenes Using Nucleophilic CF3SiMe3: Efficient C(sp3)–CF3 Bond Formation

(2012) Lingling Chu et al.   ORGANIC LETTERS

Taming of Fluoroform: Direct Nucleophilic Trifluoromethylation of Si, B, S, and C Centers

(2012) G. K. S. Prakash et al.   SCIENCE

Mild copper-catalyzed trifluoromethylation of terminal alkynes using an electrophilic trifluoromethylating reagent

(2012) Zhiqiang Weng et al.   TETRAHEDRON

Synthesis of trifluoromethylated acetylenes via copper-catalyzed trifluoromethylation of alkynyltrifluoroborates

(2012) Huidong Zheng et al.   TETRAHEDRON LETTERS

Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

(2011) Andrew T. Parsons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple, Stable, and Easily Accessible Well-Defined CuCF3 Aromatic Trifluoromethylating Agents

(2011) Olesya A. Tomashenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts

(2011) Cheng-Pan Zhang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent

(2011) Jun Xu et al.   CHEMICAL COMMUNICATIONS

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions

(2011) Irina P. Beletskaya et al.   CHEMICAL REVIEWS

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Transition-metal catalyzed oxidative cross-coupling reactions to form C–C bonds involving organometallic reagents as nucleophiles

(2011) Wei Shi et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond Activation

(2011) Jun Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Cupration of Fluoroform

(2011) Alessandro Zanardi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation

(2011) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent

(2011) Tianfei Liu et al.   ORGANIC LETTERS

Benzoyl peroxide (BPO)-promoted oxidative trifluoromethylation of tertiary amines with trimethyl(trifluoromethyl)silane

(2010) Lingling Chu et al.   CHEMICAL COMMUNICATIONS

Metal-catalysed cleavage of carbon–carbon bonds

(2010) Masahiro Murakami et al.   CHEMICAL COMMUNICATIONS

Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3

(2010) Lingling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryl−CF3Bond-Forming Reductive Elimination from Palladium(IV)

(2010) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Mediated Oxidative Trifluoromethylation of Boronic Acids

(2010) Lingling Chu et al.   ORGANIC LETTERS

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

(2010) E. J. Cho et al.   SCIENCE

New hypervalent iodine reagents for electrophilic trifluoromethylation and their precursors: synthesis, structure, and reactivity

(2010) Katrin Niedermann et al.   TETRAHEDRON

Efficient Access to Extended Yagupolskii-Umemoto-Type Reagents: Triflic Acid Catalyzed Intramolecular Cyclization of ortho-Ethynylaryltrifluoromethylsulfanes

(2009) Andrej Matsnev et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aromatic trifluoromethylation catalytic in copper

(2009) Masahiro Oishi et al.   CHEMICAL COMMUNICATIONS

Mn(III)-Mediated Reactions of Cyclopropanols with Vinyl Azides: Synthesis of Pyridine and 2-Azabicyclo[3.3.1]non-2-en-1-ol Derivatives

(2009) Yi-Feng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective metal-catalyzed activation of strained rings

(2009) Tobias Seiser et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents

(2008) Patrick Eisenberger et al.   CHEMICAL COMMUNICATIONS

Fluorinated Johnson Reagent for Transfer-Trifluoromethylation to Carbon Nucleophiles

(2008) Shun Noritake et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY