Journal
ORGANOMETALLICS
Volume 28, Issue 5, Pages 1275-1277Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om801206g
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- American Chemical Society
- University of California
- Allergan Foundation
- UCI UROP
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A new palladium-catalyzed syn carboauration of alkynes proceeds in 2 h at ambient temperature with complete regioselectivity. The resulting alpha-ester vinyl-gold intermediates art, resistant to rapid protodemetalation, permitting their participation in new one-pot palladium-and-gold cross-coupling reactions and electrophilic trapping reactions.
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