Simple access to β-trifluoromethyl-substituted ketones via copper-catalyzed ring-opening trifluoromethylation of substituted cyclopropanols

Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes

(2015) Concepción Alonso et al.   CHEMICAL REVIEWS

Insight into the Mechanism and Stereochemistry of the Transformations of Alkyltitanium Ate-Complexes. An Enhanced Enantioselectivity in the Cyclopropanation of the Carboxylic Esters with Titanacyclopropane Reagents

(2014) Oleg G. Kulinkovich et al.   ADVANCED SYNTHESIS & CATALYSIS

Rapid Access to β-Trifluoromethyl-Substituted Ketones: Harnessing Inductive Effects in Wacker-Type Oxidations of Internal Alkenes

(2014) Michael M. Lerch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic asymmetric conjugate addition of terminal alkynes to β-trifluoromethyl α,β-enones

(2014) Amparo Sanz-Marco et al.   CHEMICAL COMMUNICATIONS

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

Recent Advances in Trifluoromethylation Reactions with Electrophilic Trifluoromethylating Reagents

(2014) Sebastián Barata-Vallejo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent progress in transition-metal-catalyzed trifluoromethylation of olefins using electrophilic CF3 reagents

(2014) Takashi Koike et al.   JOURNAL OF FLUORINE CHEMISTRY

Palladium-Catalyzed Cross-Coupling of Benzyl Chlorides with Cyclopropanol-Derived Ketone Homoenolates

(2014) Nisha Nithiy et al.   ORGANIC LETTERS

A highly stereoselective route to medium-ring-sized trans-alkenolides via oxidative fragmentation of bicyclic oxycyclopropane precursors: application to the synthesis of (+)-recifeiolide

(2014) Dzmitry M. Zubrytski et al.   TETRAHEDRON

Controlled Trifluoromethylation Reactions of Alkynes through Visible-Light Photoredox Catalysis

(2013) Naeem Iqbal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols

(2013) Zhi-Min Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation ofN,N-Dialkylhydrazones

(2013) Etienne Pair et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Trifluoromethylation-Initiated Radical 1,2-Aryl Migration in α,α-Diaryl Allylic Alcohols

(2013) Xiaowu Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective 1,4-trifluoromethylation of α,β-unsaturated ketones via aS-(trifluoromethyl)diphenylsulfonium salts/copper system

(2013) Satoshi Okusu et al.   Beilstein Journal of Organic Chemistry

Recent advances in transition metal-catalyzed Csp2-monofluoro-, difluoro-, perfluoromethylation and trifluoromethylthiolation

(2013) Grégory Landelle et al.   Beilstein Journal of Organic Chemistry

CuCl-catalyzed ortho trifluoromethylation of arenes and heteroarenes with a pivalamido directing group

(2013) Shangjun Cai et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed cross-coupling of cyclopropanol-derived ketone homoenolates with aryl bromides

(2013) David Rosa et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed trifluoromethylation with concomitant C–C bond formation via 1,2-migration of an aryl group

(2013) Hiromichi Egami et al.   CHEMICAL COMMUNICATIONS

Boron-trihalide-promoted regioselective ring-opening reactions of gem-difluorocyclopropyl ketones

(2013) Tang-Po Yang et al.   CHEMICAL COMMUNICATIONS

Synthesis of β-CF3 ketones from trifluoromethylated allylic alcohols by ruthenium catalyzed isomerization

(2013) Vincent Bizet et al.   JOURNAL OF FLUORINE CHEMISTRY

Palladium-Catalyzed Trifluoroethylation of Terminal Alkynes with 1,1,1-Trifluoro-2-iodoethane

(2013) Yi-Si Feng et al.   ORGANIC LETTERS

Arylation of Aldehyde Homoenolates with Aryl Bromides

(2013) Kevin Cheng et al.   ORGANIC LETTERS

Copper-Catalyzed Direct C–H Trifluoromethylation of Quinones

(2013) Xi Wang et al.   ORGANIC LETTERS

A Facile Parallel Synthesis of Trifluoroethyl-Substituted Alkynes

(2012) Cui-Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A “Renaissance” in Radical Trifluoromethylation

(2012) Armido Studer   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Kulinkovich hydroxycyclopropanation reaction in natural product synthesis

(2012) Isabell Haym et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(i)-catalyzed 1,4-conjugate arylation toward β-fluoroalkylated electron-deficient alkenes: a new entry to a construction of a tertiary carbon center possessing a fluoroalkyl group

(2012) Atsunori Morigaki et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly enantioselective yttrium(iii)-catalyzed Friedel–Crafts alkylation of β-trichloro(trifluoro)methyl aryl enones with indoles

(2011) Wentao Wang et al.   CHEMICAL COMMUNICATIONS

Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

(2011) David Rosa et al.   CHEMICAL COMMUNICATIONS

Aromatic Trifluoromethylation with Metal Complexes

(2011) Olesya A. Tomashenko et al.   CHEMICAL REVIEWS

Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation

(2011) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Functionalized Indoles with a Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Atom Through an Enantioselective Friedel-Crafts Alkylation with β-Trifluoromethyl-α,β-enones

(2010) Gonzalo Blay et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrophilic trifluoromethylation of arenes and N-heteroarenes using hypervalent iodine reagents

(2010) Matthias S. Wiehn et al.   JOURNAL OF FLUORINE CHEMISTRY

Palladium-Catalyzed Cross-Coupling of Cyclopropanols with Aryl Halides Under Mild Conditions

(2010) David Rosa et al.   ORGANIC LETTERS

Zinc-Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation Reagents

(2009) Raffael Koller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A first high enantiocontrol of an asymmetric tertiary carbon center attached with a fluoroalkyl group via Rh(I)-catalyzed conjugate addition reaction

(2008) Tsutomu Konno et al.   TETRAHEDRON LETTERS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS