Mechanism and reactivity of catalytic propargylic substitution reactions via metal–allenylidene intermediates: a theoretical perspective

Regio- and Stereospecific Copper-Catalyzed Substitution Reaction of Propargylic Ammonium Salts with Aryl Grignard Reagents

(2017) Manuel Guisán-Ceinos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Substituent on the Mechanism and Chemoselectivity of the Gold(I)-Catalyzed Propargyl Ester Tandem Cyclization

(2017) Yunhe Li et al.   ORGANOMETALLICS

Recent Advances in Catalytic Transformations Involving Copper Acetylides

(2017) Christopher Cordier et al.   SYNTHESIS-STUTTGART

Enantioselective propargylic [1,3]-rearrangements: copper-catalyzed O-to-N migrations toward C–N bond formation

(2017) Li-Jie Cheng et al.   Chemical Science

Enantioselective Copper-Catalyzed Propargylic Etherification of Propargylic Esters with Phenols Promoted by Inorganic Base Additives

(2016) Long Shao et al.   ADVANCED SYNTHESIS & CATALYSIS

Construction of Chiral Tri- and Tetra-Arylmethanes Bearing Quaternary Carbon Centers: Copper-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters

(2016) Kouhei Tsuchida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homoleptic gold(i) N-heterocyclic allenylidene complexes: excited-state properties and lyotropic chromonics

(2016) Xin-Shan Xiao et al.   CHEMICAL COMMUNICATIONS

Enantioconvergent Nucleophilic Substitution Reaction of Racemic Alkyne–Dicobalt Complex (Nicholas Reaction) Catalyzed by Chiral Brønsted Acid

(2016) Masahiro Terada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric [4 + 1] Annulation of Sulfur Ylides with Copper–Allenylidene Intermediates

(2016) Qiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Copper-Catalyzed Formal [4 + 2] Cycloaddition of o-Aminophenol Derivatives with Propargylic Esters for Synthesis of Optically Active 3,4-Dihydro-2H-1,4-benzoxazines

(2016) Zhen-Ting Liu et al.   ORGANIC LETTERS

Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes

(2016) Liqun Jin et al.   Chemical Science

Palladium-catalysed formation of vicinal all-carbon quaternary centres via propargylation

(2016) Xin Huang et al.   Nature Communications

Highly diastereo-/enantioselective Cu-catalyzed propargylic alkylations of propargyl acetates with cyclic enamines

(2016) Cheng Zhang et al.   RSC Advances

HBF4-Catalysed Nucleophilic Substitutions of Propargylic Alcohols

(2015) Elena Barreiro et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Enantioselective Propargylic Etherification of Propargylic Esters with Alcohols

(2015) Kazunari Nakajima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trialkyl Methanetricarboxylate as Dialkyl Malonate Surrogate in Copper-Catalyzed Enantioselective Propargylic Substitution

(2015) Guanxin Huang et al.   ORGANIC LETTERS

Recent Advances in Catalytic Stereocontrolled Cycloaddition with Terminal Propargylic Compounds

(2015) Xiang-Ping Hu et al.   SYNTHESIS-STUTTGART

Enantioselective Synthesis of Highly Functionalized Dihydrofurans through Copper-Catalyzed Asymmetric Formal [3+2] Cycloaddition of β-Ketoesters with Propargylic Esters

(2014) Fu-Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective intramolecular propargylic amination using chiral copper–pybox complexes as catalysts

(2014) Masashi Shibata et al.   CHEMICAL COMMUNICATIONS

Chiral Propargylic Cations as Intermediates in SN1-Type Reactions: Substitution Pattern, Nuclear Magnetic Resonance Studies, and Origin of the Diastereoselectivity

(2014) Dominik Nitsch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the mechanism of Pd(0)-catalyzed coupling of propargylic carbonates with N-tosylhydrazones: density functional theory survey

(2014) Wei-Wei Ping et al.   TETRAHEDRON

Ruthenium-Triggered Ring Opening of Ethynylcyclopropanes: [3+2] Cycloaddition with Aldehydes and Aldimines Involving Metal Allenylidene Intermediates

(2013) Yoshihiro Miyake et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargyl β-Ketoesters with a Chiral Ketimine P,N,N-Ligand

(2013) Fu-Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum(II) and Gold(III) Allenylidene Complexes: Phosphorescence, Self-Assembled Nanostructures and Cytotoxicity

(2013) Xin-Shan Xiao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold–allenylidenes – an experimental and theoretical study

(2013) Max M. Hansmann et al.   Chemical Science

Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles

(2012) Cheng Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Computational Study of the Mechanism and Selectivity of Palladium-Catalyzed Propargylic Substitution with Phosphorus Nucleophiles

(2012) J. Oscar C. Jiménez-Halla et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Enantioselective Cross-Couplings of Racemic Secondary Electrophiles That Bear an Oxygen Leaving Group

(2012) Alexander J. Oelke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Enantioselective Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Nucleophiles

(2012) Yoshiaki Nishibayashi   SYNTHESIS-STUTTGART

Metal Complexes Containing Allenylidene and Higher Cumulenylidene Ligands: A Theoretical Perspective

(2011) Cecilia Coletti et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Asymmetric Propargylation

(2011) Chang-Hua Ding et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalysed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)-Anisomycin and (−)-Cytoxazone

(2011) Remko J. Detz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cooperative Catalytic Reactions Using Lewis Acids and Organocatalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols Bearing an Internal Alkyne with Aldehydes

(2011) Kazuki Motoyama et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes

(2011) Akiko Yoshida et al.   ORGANIC LETTERS

Copper-Catalyzed Enantioselective Propargylic Amination of Nonaromatic Propargylic Esters with Amines

(2011) Akiko Yoshida et al.   ORGANIC LETTERS

AuCl3-Catalyzed Propargylation of Arenes with N-Tosylpropargyl Amine: Synthesis of 1,3-Diarylpropynes

(2010)   BULLETIN OF THE KOREAN CHEMICAL SOCIETY

Propargylic Activation Across a Heterobimetallic Ir−Sn Catalyst: Nucleophilic Substitution and Indene Formation with Propargylic Alcohols

(2010) Paresh Nath Chatterjee et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper−Allenylidene Complexes as Key Intermediates

(2010) Gaku Hattori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile one-pot synthesis of three different substituted thiazoles from propargylic alcohols

(2010) Xun Gao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ruthenium-catalyzed addition of carboxylic acids or cyclic 1,3-dicarbonyl compounds to propargyl alcohols

(2010) Stefanie Berger et al.   TETRAHEDRON LETTERS

Synthesis of Allenylidene Lithium and Silver Complexes, and Subsequent Transmetalation Reactions

(2009) Matt Asay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Propargylic Substitution Reactions

(2009) Yoshihiro Miyake et al.   ChemCatChem

Copper-Catalyzed Diastereo- and Enantioselective Sequential Reactions of Propargylic Acetates with (E)-2,4-Pentadienylamine

(2009) Gaku Hattori et al.   ChemCatChem

Allenylidene and Higher Cumulenylidene Complexes

(2009) Victorio Cadierno et al.   CHEMICAL REVIEWS

Catalyzed Propargylic Substitution

(2009) Remko J. Detz et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Atom-economic transformations of propargylic alcohols catalyzed by the 16-electron allyl-ruthenium(II) complex [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6] (dppf=1,1′-bis(diphenylphosphino)ferrocene)

(2009) Victorio Cadierno et al.   INORGANICA CHIMICA ACTA

Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper−Allenylidene Intermediates: Efficient Approach to Chiral β-Amino Alcohols

(2009) Gaku Hattori et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Copper-Catalyzed Propargylic Substitution Reaction of Propargylic Acetates with Enamines

(2009) Ping Fang et al.   ORGANIC LETTERS

Nickel-Catalyzed Negishi Cross-Couplings of Secondary Nucleophiles with Secondary Propargylic Electrophiles at Room Temperature

(2008) Sean W. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Propargylic Amination

(2008) Remko J. Detz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Acetates with Amines

(2008) Gaku Hattori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Propargylic Substitution

(2008) Natalie Ljungdahl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A DFT Study on the Reaction Pathways for CarbonCarbon Bond-Forming Reactions between Propargylic Alcohols and Alkenes or Ketones Catalyzed by Thiolate-Bridged Diruthenium Complexes

(2008) Ken Sakata et al.   Chemistry-An Asian Journal

Au(I)- and Pt(II)-Catalyzed Cycloetherification of ω-Hydroxy Propargylic Esters

(2008) Jef K. De Brabander et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Dienyne Formation from Propargylic Alcohols and 1,3-Conjugated Dienes

(2008) Masaki Daini et al.   ORGANOMETALLICS

Gold(III)-catalyzed direct nucleophilic substitution of propargylic alcohols

(2008) Marie Georgy et al.   TETRAHEDRON