4.7 Article

Homoleptic gold(I) N-heterocyclic allenylidene complexes: excited-state properties and lyotropic chromonics

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 28, Pages 4983-4986

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc09571a

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Funding

  1. National Natural Science Foundation of China [21571096]
  2. National Key Basic Research Program of China (973 Program) [2013CB834802, 2013CB834803]

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A series of phosphorescent Au(I) bis(N-heterocyclic allenylidene) complexes, namely [Au(=C=C=(CRR2)-R-1)(2)]X-+(-), were synthesized and structurally characterized. These organometallic complexes exhibit panchromatic transient absorption upon electronic photo-excitation and can self-organize into lyotropic chromonic mesophases in aqueous solutions.

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