Journal
ORGANIC LETTERS
Volume 17, Issue 19, Pages 4894-4897Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02463
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Funding
- National Natural Science Foundation of China [21272150, 21072125]
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The first copper-catalyzed enantioselective propargylation of trialkyl methantricarboxylate with propargylic alcohol derivatives was developed. The tricarboxylate unit in the obtained adducts could be easily transformed into a malonate moiety by treating with in situ generated NaOEt in excellent yield without racemization.
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