Journal
RSC ADVANCES
Volume 6, Issue 18, Pages 14763-14767Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ra25627e
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Funding
- National Natural Science Foundation of China [21572226, 21262011]
- Dalian Institute of Chemical Physics
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Highly diastereo- and enantioselective copper-catalyzed propargylic alkylations of propargylic acetates with morpholine-derived cyclic enamines for the construction of vicinal tertiary stereocenters have been developed. By the employment of a less sterically hindered chiral tridentate P,N,N-ligand, good to excellent diastereo- (up to > 98 : 2 dr) and enantioselectivity (up to 99% ee) could be achieved for a wide range of substrates.
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