Featuring Xantphos

Enantioselective Terminal Addition to Allenes by Dual Chiral Primary Amine/Palladium Catalysis

(2017) Han Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiospecific Total Synthesis of the Highly Strained (−)-Presilphiperfolan-8-ol via a Pd-Catalyzed Tandem Cyclization

(2017) Pengfei Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Allylic C(sp3)–H Carboxylation with CO2

(2017) Kenichi Michigami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The first example of palladium-catalyzed cascade amidine arylation–intramolecular ester amidation for the synthesis of hypoxanthines: application to the synthesis of 8-azanebularine analogues

(2017) Wu Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Gold/silver-catalyzed controllable regioselective vinylcarbene insertion into O–H bonds

(2017) Guangyang Xu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A room temperature cyanation of (hetero)aromatic chlorides by an air stable nickel(ii) XantPhos precatalyst and Zn(CN)2

(2017) D. Dawson Beattie et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-Catalyzed Intermolecular Carbonylative [2 + 2 + 1] Cycloaddition of Alkynes Using Alcohol as the Carbon Monoxide Source for the Formation of Cyclopentenones

(2017) Ju Hyun Kim et al.   ORGANIC LETTERS

Synthesis of Benzyl-, Allyl-, and Allenyl-boronates via Copper-Catalyzed Borylation of Alcohols

(2017) Lujia Mao et al.   ORGANIC LETTERS

Nickel-Catalyzed Synthesis of Quinazolinediones

(2017) Gregory L. Beutner et al.   ORGANIC LETTERS

Nickel-catalyzed decarboxylative coupling of an alkynyl carboxylic acid with aryl iodides

(2017) Yujeong Son et al.   TETRAHEDRON LETTERS

Electronic and bite angle effects in catalytic C–O bond cleavage of a lignin model compound using ruthenium Xantphos complexes

(2017) Luke Shaw et al.   Catalysis Science & Technology

One-pot synthesis of benzazoles and quinazolinones via iron pentacarbonyl mediated carbonylation of aryl iodides under microwave irradiation

(2017) Wun-Huei Lin et al.   Organic Chemistry Frontiers

Miyaura Borylation and One-Pot Two-Step Homocoupling of Aryl Chlorides and Bromides under Solvent-Free Conditions

(2016) Pavel B. Dzhevakov et al.   ADVANCED SYNTHESIS & CATALYSIS

Carbonylation of Difluoroalkyl Bromides Catalyzed by Palladium

(2016) Hai-Yang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Borylcupration of Allenylsilanes

(2016) Weiming Yuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C−H Arylation of α,β-Unsaturated Imines: Catalyst-Controlled Synthesis of Enamine and Allylic Amine Derivatives

(2016) Minyan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Overcoming Phase-Transfer Limitations in the Conversion of Lipophilic Oleo Compounds in Aqueous Media-A Thermomorphic Approach

(2016) Tom Gaide et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Access to α,α-Difluoroacylated Arenes by Palladium-Catalyzed Carbonylation of (Hetero)Aryl Boronic Acid Derivatives

(2016) Thomas L. Andersen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tandem Rh-catalysis: decarboxylative β-keto acid and alkyne cross-coupling

(2016) Faben A. Cruz et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed dearomatizing 2,5-alkoxyarylation of furan rings: diastereospecific access to spirooxindoles

(2016) Jianchao Liu et al.   CHEMICAL COMMUNICATIONS

The drastic effect of cobalt and chromium catalysts in the borylation of arylzinc reagents

(2016) Kimihiro Komeyama et al.   CHEMICAL COMMUNICATIONS

Palladium-catalysed hydroamidocarbonylation of 1,3-dienes

(2016) Haoquan Li et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed cascade cyclization of allylamine-tethered alkylidenecyclopropanes: facile access to iodine/difluoromethylene- and perfluoroalkyl-containing 1-benzazepine scaffolds

(2016) Liu-Zhu Yu et al.   CHEMICAL COMMUNICATIONS

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

(2016) Paula Ruiz-Castillo et al.   CHEMICAL REVIEWS

The Origin of Anti-Markovnikov Regioselectivity in Alkene Hydroamination Reactions Catalyzed by [Rh(DPEphos)]+

(2016) Almudena Couce-Rios et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Chemoselective and Biocompatible Functionalization of Cysteine-Containing Molecules at Room Temperature

(2016) Riyadh Ahmed Atto Al-Shuaeeb et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Aminocarbonylation of Allylic Alcohols

(2016) Haoquan Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Initiated Radical Cascade Stereoselective Iodofluoroalkylation/Cycloisomerization of Ene-vinylidenecyclopropanes

(2016) Song Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Thermodynamically Favorable Synthesis of 2-Oxazolidinones through Silver-Catalyzed Reaction of Propargylic Alcohols, CO2, and 2-Aminoethanols

(2016) Qing-Wen Song et al.   ChemSusChem

A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate

(2016) Laurian Botez et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Synthesis of Allylic Ureas via an Isocyanate Intermediate

(2016) Lucien P. Jay et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Application of Isocyanides as Amide Surrogates in the Synthesis of Diverse Isoindolin-1-one Derivatives by a Palladium-Catalyzed Tandem Carboxamidation/Hydroamidation Reaction

(2016) Ramdas S Pathare et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Discovery of 2-((R)-4-(2-Fluoro-4-(methylsulfonyl)phenyl)-2-methylpiperazin-1-yl)-N-((1R,2s,3S,5S,7S)-5-hydroxyadamantan-2-yl)pyrimidine-4-carboxamide (SKI2852): A Highly Potent, Selective, and Orally Bioavailable Inhibitor of 11β-Hydroxysteroid Dehydrogenase Type 1 (11β-HSD1)

(2016) Je Ho Ryu et al.   JOURNAL OF MEDICINAL CHEMISTRY

Catalytic Chemo- and Regioselective Coupling of 1,3-Dicarbonyls with N-Heterocyclic Nucleophiles

(2016) Miles Kenny et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Alkynylation of 3H-Imidazo[4,5-b]pyridines Using gem-Dibromoalkenes as Alkynes Source

(2016) Jessy Aziz et al.   JOURNAL OF ORGANIC CHEMISTRY

Phosphine ligands stabilized Cu(I) catalysts for carbene insertion into the N–H bond

(2016) Kankanala Ramakrishna et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Stereoselective and Versatile Preparation of Tri- and Tetrasubstituted Allylic Amine Scaffolds under Mild Conditions

(2016) Wusheng Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed C(sp3)–H Functionalization/Carbenoid Insertion: All-Carbon Quaternary Centers via Multiple C–C Bond Formation

(2016) Álvaro Gutiérrez-Bonet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Allylation/Benzylation of H-Phosphinate Esters with Alcohols

(2016) Anthony Fers-Lidou et al.   MOLECULES

Competing amination and C–H arylation pathways in Pd/xantphos-catalyzed transformations of binaphthyl triflates: switchable routes to chiral amines and helicene derivatives

(2016) Aaron A. Ruch et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Platform for Ring-Fluorinated Benzoheterole Derivatives: Palladium-Catalyzed Regioselective 1,1-Difluoroallylation and Heck Cyclization

(2016) Takeshi Fujita et al.   ORGANIC LETTERS

Palladium-Catalyzed Benzylic Arylation of Pyridylmethyl Silyl Ethers: One-Pot Synthesis of Aryl(pyridyl)methanols

(2016) Alexandra R. Rivero et al.   ORGANIC LETTERS

Palladium-Catalyzed Synthesis of Aryl Vinyl Sulfides via 1,3-Oxathiolanes As Vinyl Sulfide Surrogates

(2016) Jason R. Schmink et al.   ORGANIC LETTERS

Palladium-Catalyzed Selective α-Alkenylation of Pyridylmethyl Ethers with Vinyl Bromides

(2016) Xiaodong Yang et al.   ORGANIC LETTERS

Palladium-Catalyzed Stereoselective Formation of Substituted Allylic Thioethers and Sulfones

(2016) José Enrique Gómez et al.   ORGANIC LETTERS

Palladium-Catalyzed Regioselective Difluoroalkylation and Carbonylation of Alkynes

(2016) Qiang Wang et al.   ORGANIC LETTERS

Palladium-Catalyzed Modular Synthesis of Substituted Piperazines and Related Nitrogen Heterocycles

(2016) Thomas D. Montgomery et al.   ORGANIC LETTERS

Copper-Catalyzed trans-Hydroboration of Terminal Aryl Alkynes: Stereodivergent Synthesis of Alkenylboron Compounds

(2016) Won Jun Jang et al.   ORGANIC LETTERS

Computational Studies on an Aminomethylation Precursor: (Xantphos)Pd(CH2NBn2)+

(2016) Xiaotian Qi et al.   ORGANOMETALLICS

Sonogashira coupling catalyzed by the Cu(Xantphos)I–Pd(OAc)2 system

(2016) Meilin Liu et al.   TETRAHEDRON LETTERS

Palladium-catalyzed hydroaminocarbonylation of alkenes with amines promoted by weak acid

(2016) Guoying Zhang et al.   TETRAHEDRON LETTERS

Facile Pd-catalyzed chemoselective transfer hydrogenation of olefins using formic acid in water

(2016) Tianxiang Liu et al.   TETRAHEDRON LETTERS

Nickel-catalyzed arylation of heteroaryl-containing diarylmethanes: exceptional reactivity of the Ni(NIXANTPHOS)-based catalyst

(2016) Xinyu Cao et al.   Chemical Science

Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation

(2016) Rajith S. Manan et al.   Nature Communications

Dearomatized Alkylidene Dihydropyridines as Substrates for Mizoroki–Heck Cyclizations

(2016) Madhur S. Joshi et al.   ACS Catalysis

Cobalt-Catalyzed Regiodivergent Hydrosilylation of Vinylarenes and Aliphatic Alkenes: Ligand- and Silane-Dependent Regioselectivities

(2016) Chao Wang et al.   ACS Catalysis

First efficient catalyst recycling for the iridium-catalysed hydroformylation of 1-octene

(2016) A. Behr et al.   Catalysis Science & Technology

Palladium-catalyzed alkoxycarbonylation of aryl halides with phenols employing formic acid as the CO source

(2016) Xinxin Qi et al.   Catalysis Science & Technology

Palladium-catalyzed radical cascade difluoroalkylation/cyclization of acrylamide with ethyl difluorobromoacetate

(2016) Xiao-Feng Xia et al.   RSC Advances

Glycerol Upgrading via Hydrogen Borrowing: Direct Ruthenium-Catalyzed Amination of the Glycerol Derivative Solketal

(2016) Anna Said Stålsmeden et al.   ACS Sustainable Chemistry & Engineering

Palladium-Catalyzed Direct Benzylation of Polyfluoroarenes with Benzyl Carbonates through Selective C−H Functionalization

(2016) Guanghui Yang et al.   Asian Journal of Organic Chemistry

Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

(2016) Alois Fürstner   ACS Central Science

Controlled generation and use of CO in flow

(2016) Steffen V. F. Hansen et al.   Reaction Chemistry & Engineering

The Retro-Hydroformylation Reaction

(2015) Shuhei Kusumoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Z-Selective Hydrothiolation of Racemic 1,3-Disubstituted Allenes: An Atom-Economic Rhodium-Catalyzed Dynamic Kinetic Resolution

(2015) Adrian B. Pritzius et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Alkenes

(2015) Wei Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

PC-Activated Bimetallic Rhodium Xantphos Complexes: Formation and Catalytic Dehydrocoupling of Amine-Boranes

(2015) Heather C. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aqueous phase catalytic hydroformylation reactions of alkenes

(2015) Sumeet K. Sharma et al.   CATALYSIS TODAY

Rhodium versus Iridium Catalysts in the Controlled Tandem Hydroformylation-Isomerization of Functionalized Unsaturated Fatty Substrates

(2015) Jérémy Ternel et al.   ChemCatChem

Practical catalytic method for synthesis of sterically hindered anilines

(2015) Melrose Mailig et al.   CHEMICAL COMMUNICATIONS

Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes

(2015) Concepción Alonso et al.   CHEMICAL REVIEWS

Katalysatorvergleich bei der Hydroesterifizierung von 10-Undecensäuremethylester in thermomorphen Lösungsmittelsystemen

(2015) Tom Gaide et al.   CHEMIE INGENIEUR TECHNIK

Direct Synthesis of an α,ω-Diester from 2,7-Octadienol as Bulk Feedstock in Three Tandem Catalytic Steps

(2015) Karoline A. Ostrowski et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Hydroformylation of Long-Chain Olefins in Aqueous Multiphase Systems in a Continuously Operated Miniplant

(2015) Tobias Pogrzeba et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Electronic Structure and Bonding in Iron(II) and Iron(I) Complexes Bearing Bisphosphine Ligands of Relevance to Iron-Catalyzed C–C Cross-Coupling

(2015) Jared L. Kneebone et al.   INORGANIC CHEMISTRY

Impact of Coordination Geometry, Bite Angle, and Trans Influence on Metal–Ligand Covalency in Phenyl-Substituted Phosphine Complexes of Ni and Pd

(2015) Courtney M. Donahue et al.   INORGANIC CHEMISTRY

Rh catalyzed multicomponent tandem and one-pot reactions under hydroformylation conditions

(2015) Bojan P. Bondžić   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Selectivity controlled by ligand tuning in the palladium-catalysed cyclocarbonylation: Synthesis of new γ and δ lactones from a natural sesquiterpene

(2015) Jamal El Karroumi et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Synthesis of Biheterocycles Based on Quinolinone, Chromone, and Coumarin Scaffolds by Palladium-Catalyzed Decarboxylative Couplings

(2015) K. Harsha Vardhan Reddy et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Disubstituted Dithioethers: tert-Butoxide Promoted Elimination/Ring Opening of 1,3-Dithianes Followed by Palladium-Catalyzed C–S Bond Formation

(2015) Nissa Abidi et al.   JOURNAL OF ORGANIC CHEMISTRY

Mono-Oxidation of Bidentate Bis-phosphines in Catalyst Activation: Kinetic and Mechanistic Studies of a Pd/Xantphos-Catalyzed C–H Functionalization

(2015) Yining Ji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Palladium-Catalyzed Alkoxycarbonylation of Allenes: Regioselective Synthesis of α,β- and β,γ-Unsaturated Esters

(2015) Jie Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conclusive Evidence on the Mechanism of the Rhodium-Mediated Decyanative Borylation

(2015) Miguel A. Esteruelas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient 11C-Carbonylation of Isolated Aryl Palladium Complexes for PET: Application to Challenging Radiopharmaceutical Synthesis

(2015) Thomas L. Andersen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Dimerization/Cyclization of Itaconates

(2015) Zhiqiang Li et al.   MOLECULES

Palladium-Catalyzed Benzylic C–H Arylation of Azaarylmethylamines

(2015) Byeong-Seon Kim et al.   ORGANIC LETTERS

Controlled Rh-Catalyzed Mono- and Double-decarbonylation of Alkynyl α-Diones To Form Conjugated Ynones and Disubstituted Alkynes

(2015) Rachel E. Whittaker et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Intramolecular Hydroalkoxylation of Unactivated Alkenes

(2015) Hiroaki Murayama et al.   ORGANIC LETTERS

Synthesis of Polycyclic Nitrogen Heterocycles via Cascade Pd-Catalyzed Alkene Carboamination/Diels–Alder Reactions

(2015) Derick R. White et al.   ORGANIC LETTERS

Regioselective Rhodium-Catalyzed Addition of 1,3-Dicarbonyl Compounds to Terminal Alkynes

(2015) Thorsten M. Beck et al.   ORGANIC LETTERS

Access to Difluoromethylated Arenes by Pd-Catalyzed Reaction of Arylboronic Acids with Bromodifluoroacetate

(2015) Zhang Feng et al.   ORGANIC LETTERS

Palladium Catalyzed Diaryl Sulfoxide Generation from Aryl Benzyl Sulfoxides and Aryl Chlorides

(2015) Tiezheng Jia et al.   ORGANIC LETTERS

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers with Isotopically-Labeled Grignard Reagents

(2015) David D. Dawson et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Development of the Commercial Route for the Manufacture of a 5-Lipoxygenase Inhibitor PF-04191834

(2015) Brian Chekal et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Chiral Wide-Bite-Angle Diphosphine Ligands: Synthesis, Coordination Chemistry, and Application in Pd-Catalyzed Allylic Alkylation

(2015) Christine F. Czauderna et al.   ORGANOMETALLICS

Synthesis of Adipic Aldehyde by n-Selective Hydroformylation of 4-Pentenal

(2015) Jaroslaw Mormul et al.   ORGANOMETALLICS

Importance of Long-Range Noncovalent Interactions in the Regioselectivity of Rhodium-Xantphos-Catalyzed Hydroformylation

(2015) Manoj Kumar et al.   ORGANOMETALLICS

Ru(II)-Triphos Catalyzed Amination of Alcohols with Ammonia via Ionic Species

(2015) Eric J. Derrah et al.   ORGANOMETALLICS

Rh–POP Pincer Xantphos Complexes for C–S and C–H Activation. Implications for Carbothiolation Catalysis

(2015) Peng Ren et al.   ORGANOMETALLICS

Uncovering the Mechanism of Homogeneous Methyl Methacrylate Formation with P,N Chelating Ligands and Palladium: Favored Reaction Channels and Selectivities

(2015) Luke Crawford et al.   ORGANOMETALLICS

POP–Rhodium-Promoted C–H and B–H Bond Activation and C–B Bond Formation

(2015) Miguel A. Esteruelas et al.   ORGANOMETALLICS

Rh-catalyzed C-C bond cleavage by transfer hydroformylation

(2015) S. K. Murphy et al.   SCIENCE

Rh-catalyzed decarbonylation of conjugated ynones via carbon–alkyne bond activation: reaction scope and mechanistic exploration via DFT calculations

(2015) Alpay Dermenci et al.   Chemical Science

Catalytic Isomerizing ω-Functionalization of Fatty Acids

(2015) Verena Goldbach et al.   ACS Catalysis

Palladium catalyzed oxidative carbonylation of alcohols: effects of diphosphine ligands

(2015) Emanuele Amadio et al.   Catalysis Science & Technology

Room-temperature palladium-catalysed Suzuki–Miyaura coupling of arylboric acid with aryl chlorides

(2015) Dan Wang et al.   RSC Advances

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Reversed-Polarity Synthesis of Diaryl Ketones through Palladium-Catalyzed Direct Arylation of 2-Aryl-1,3-dithianes

(2014) Baris Yucel et al.   ADVANCED SYNTHESIS & CATALYSIS

A General Synthesis of Fluoroalkylated Alkenes by Palladium-Catalyzed Heck-Type Reaction of Fluoroalkyl Bromides

(2014) Zhang Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computational Ligand Design for the Reductive Elimination of ArCF3from a Small Bite Angle PdIIComplex: Remarkable Effect of a Perfluoroalkyl Phosphine

(2014) Mads C. Nielsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand Bite Angle-Dependent Palladium-Catalyzed Cyclization of Propargylic Carbonates to 2-Alkynyl Azacycles or Cyclic Dienamides

(2014) David S. B. Daniels et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Insertion of an Allene into an Aminal: Aminomethylamination of Allenes by CN Bond Activation

(2014) Jianhua Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Room-temperature palladium-catalyzed direct 2-arylation of benzoxazoles with aryl and heteroaryl bromides

(2014) Feng Gao et al.   CHEMICAL COMMUNICATIONS

Synthesis, mechanism of formation, and catalytic activity of Xantphos nickel π-complexes

(2014) Nicholas D. Staudaher et al.   CHEMICAL COMMUNICATIONS

The activation strain model and molecular orbital theory: understanding and designing chemical reactions

(2014) Israel Fernández et al.   CHEMICAL SOCIETY REVIEWS

Mono- vs. Dinuclear Gold-Catalyzed Intermolecular Hydroamidation

(2014) Juan M. Serrano-Becerra et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Highly selective hydroformylation of 3,3,3-trifluoropropene to 4,4,4-trifluorobutanal using Rh/Xantphos catalyst

(2014) Yuhki Ohtsuka et al.   JOURNAL OF FLUORINE CHEMISTRY

Metal–Ligand Binding Interactions in Rhodium/Palladium-Catalyzed Synthesis of Dihydroquinolines

(2014) Lei Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Regiocontrolled Palladium-Catalyzed Arylative Cyclizations of Alkynols

(2014) Daishi Fujino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of the Dehydrocoupling and Dehydropolymerization of Amine–Boranes Using a [Rh(Xantphos)]+ Catalyst

(2014) Heather C. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Aminocyanation of Alkenes by Cooperative Palladium/Boron Catalysis

(2014) Yosuke Miyazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NiXantphos: A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides

(2014) Jiadi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Transformation of Terminal Alkynes to Branched Allylic Sulfones

(2014) Kun Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbonylation of Ethene Catalysed by Pd(II)-Phosphine Complexes

(2014) Gianni Cavinato et al.   MOLECULES

Palladium-Catalyzed Debenzylative Cross-Coupling of Aryl Benzyl Sulfides with Aryl Bromides: Synthesis of Diaryl Sulfides

(2014) Jianyou Mao et al.   ORGANIC LETTERS

Mild Pd-Catalyzed Aminocarbonylation of (Hetero)Aryl Bromides with a Palladacycle Precatalyst

(2014) Stig D. Friis et al.   ORGANIC LETTERS

Palladium-Catalyzed Phthalazinone Synthesis Using Paraformaldehyde as Carbon Source

(2014) Huamin Wang et al.   ORGANIC LETTERS

Palladium-Catalyzed Cross-Coupling of 2-Aryl-1,3-dithianes

(2014) Summer A. Baker Dockrey et al.   ORGANIC LETTERS

Highly Enantioselective Hydrogenation of Steric Hindrance Enones Catalyzed by Ru Complexes with Chiral Diamine and Achiral Phosphane

(2014) Xiangning Chen et al.   ORGANIC LETTERS

Facile Access to Functionalized Spiro[indoline-3,2′-pyrrole]-2,5′-diones via Post-Ugi Domino Buchwald–Hartwig/Michael Reaction

(2014) Nandini Sharma et al.   ORGANIC LETTERS

Catalytic Activity and Fluxional Behavior of Complexes Based on RuHCl(CO)(PPh3)3 and Xantphos-Type Ligands

(2014) Dennis Pingen et al.   ORGANOMETALLICS

On the Feasibility of Nickel-Catalyzed Trifluoromethylation of Aryl Halides

(2014) Jesús Jover et al.   ORGANOMETALLICS

The Challenge of Palladium-Catalyzed Aromatic Azidocarbonylation: From Mechanistic and Catalyst Deactivation Studies to a Highly Efficient Process

(2014) Fedor M. Miloserdov et al.   ORGANOMETALLICS

Mechanistic Study on the Ruthenium-Catalyzed Direct Amination of Alcohols

(2014) Dennis Pingen et al.   ORGANOMETALLICS

Synthesis of diarylmethylamines via palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions

(2014) Minyan Li et al.   Chemical Science

A synthetic and mechanistic investigation into the cobalt(i) catalyzed amination of aryl halides

(2014) Marshall R. Brennan et al.   Chemical Science

Isomerization–Hydroformylation Tandem Reactions

(2014) Marcelo Vilches-Herrera et al.   ACS Catalysis

Death and Rebirth: Photocatalytic Hydrogen Production by a Self-Organizing Copper–Iron System

(2014) Steffen Fischer et al.   ACS Catalysis

Exploring the mechanism of the hydroboration of alkenes by amine–boranes catalysed by [Rh(xantphos)]+

(2014) Heather C. Johnson et al.   Catalysis Science & Technology

Palladium-catalyzed carbonylation of allylamines via C–N bond activation leading to β,γ-unsaturated amides

(2014) Hui Yu et al.   RSC Advances

Computational Perspective on Pd-Catalyzed C–C Cross-Coupling Reaction Mechanisms

(2013) Max García-Melchor et al.   ACCOUNTS OF CHEMICAL RESEARCH

Dehydrogenative Boron Homocoupling of an Amine-Borane

(2013) Heather C. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diaryl Sulfoxides from Aryl Benzyl Sulfoxides: A Single Palladium-Catalyzed Triple Relay Process

(2013) Tiezheng Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Three-Component Diaryl Sulfone Synthesis Exploiting the Sulfur Dioxide Surrogate DABSO

(2013) Edward J. Emmett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroformylation of 1-Dodecene with Water-Soluble Rhodium Catalysts with Bidentate Ligands in Multiphase Systems

(2013) Tobias Hamerla et al.   ChemCatChem

Utilization of Common Ligands for the Ruthenium-Catalyzed Amination of Alcohols

(2013) Wolfgang Baumann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemo- and Regioselective Homogeneous Rhodium-Catalyzed Hydroamidomethylation of Terminal Alkenes toN-Alkylamides

(2013) Saeed Raoufmoghaddam et al.   ChemSusChem

Hybrid diphosphorus ligands in rhodium catalysed asymmetric hydroformylation

(2013) Samir H. Chikkali et al.   COORDINATION CHEMISTRY REVIEWS

Catalyst recycling via specific non-covalent adsorption on modified silicas

(2013) Alexander M. Kluwer et al.   DALTON TRANSACTIONS

POP-Pincer Silyl Complexes of Group 9: Rhodium versus Iridium

(2013) Miguel A. Esteruelas et al.   INORGANIC CHEMISTRY

Synthesis of Quinazolin-4(3H)-ones via Amidine N-Arylation

(2013) Bryan Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Difunctionalization of Enol Ethers to Amino Acetals with Aminals and Alcohols

(2013) Yinjun Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Isomerization/Hydroformylation/Hydrogenation of Internal Alkenes to n-Alcohols Using Rh/Ru Dual- or Ternary-Catalyst Systems

(2013) Yamato Yuki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

(2013) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of the Rhodium Catalyzed Propargylic CH Activation

(2013) Urs Gellrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Cyclic Guanidines via Pd-Catalyzed Alkene Carboamination

(2013) Blane P. Zavesky et al.   ORGANIC LETTERS

Mechanism of the Platinum/Tin-Catalyzed Asymmetric Hydroformylation of Styrene: A Detailed Computational Investigation of the Chiral Discrimination

(2013) Tamara Papp et al.   ORGANOMETALLICS

Rhodium catalyzed hydroformylation with formaldehyde and an external H2-source

(2013) Marcus Uhlemann et al.   TETRAHEDRON LETTERS

(POP)Rh pincer hydride complexes: unusual reactivity and selectivity in oxidative addition and olefin insertion reactions

(2013) Michael C. Haibach et al.   Chemical Science

Mechanistic Study of a Ru-Xantphos Catalyst for Tandem Alcohol Dehydrogenation and Reductive Aryl-Ether Cleavage

(2013) Stephen C. Chmely et al.   ACS Catalysis

An Efficient Palladium-Catalyzed N-Alkylation of Amines Using Primary and Secondary Alcohols

(2013) Tuan Thanh Dang et al.   ACS Catalysis

Regioselective Pd-catalyzed hydroamination of substituted dienes

(2013) Arnaud Perrier et al.   Catalysis Science & Technology

Formation of Acetals under Rhodium-Catalyzed Hydroformylation Conditions in Alcohols

(2012) Olivier Diebolt et al.   ADVANCED SYNTHESIS & CATALYSIS

Straightforward Synthesis of Allylated Keto Esters: The Palladium-Catalysed Haloketone Alkoxycarbonylation/ Allylation Domino Reaction

(2012) Benoit Wahl et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Highly Selective Semihydrogenation of Non-Polar Carbon-Carbon Multiple Bonds using a Silane and an Alcohol

(2012) Kazuhiko Semba et al.   ADVANCED SYNTHESIS & CATALYSIS

Cooperative Ligand Effects in Phase-Switching Homogeneous Catalysts

(2012) Molise Mokhadinyana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Alkyl-Alkyl Suzuki-Miyaura Coupling

(2012) Takuji Hatakeyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Hindered Anilines: Copper-Catalyzed Electrophilic Amination of Aryl Boronic Esters

(2012) Richard P. Rucker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts fornormal-Selective Hydroformylation

(2012) Kohei Takahashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroaminomethylation of eugenol with di-n-butylamine catalyzed by rhodium complexes: Bringing light on the promoting effect of Brönsted acids

(2012) Kelley C.B. Oliveira et al.   APPLIED CATALYSIS A-GENERAL

Microwave-Assisted Transfer Hydrogenation of Ketones by Ru(xantphos) Arene Complexes

(2012) Thashree Marimuthu et al.   ChemCatChem

Applied Hydroformylation

(2012) Robert Franke et al.   CHEMICAL REVIEWS

Transition metal catalyzed nucleophilic allylic substitution: activation of allylic alcohols via π-allylic species

(2012) Basker Sundararaju et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Mono-α-Arylation of Acetone with Aryl Imidazolylsulfonates

(2012) Lutz Ackermann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Vinylation of Aminals with Simple Alkenes: A New Strategy To Construct Allylamines

(2012) Yinjun Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Hydroformylation/Hydrogenation of Alkenes to Normal Alcohols Using Rh/Ru Dual Catalyst or Ru Single Component Catalyst

(2012) Kohei Takahashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Oxycyanation of Alkenes by Cooperative Pd/BPh3 Catalysis

(2012) Dennis C. Koester et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Asymmetric Rh-Catalyzed Hydroformylation of Heterocyclic Olefins

(2012) Samir H. Chikkali et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Carbonylation of Benzylic C–H Bonds via Nondirected C(sp3)–H Activation

(2012) Pan Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Room Temperature, Palladium-Mediated P–Arylation of Secondary Phosphine Oxides

(2012) Aaron J. Bloomfield et al.   ORGANIC LETTERS

Intermolecular Alkyne Hydroacylation. Mechanistic Insight from the Isolation of the Vinyl Intermediate That Precedes Reductive Elimination

(2012) Rebekah J. Pawley et al.   ORGANOMETALLICS

O–CN Bond Cleavage of Cyanates by a Transition-Metal Complex

(2012) Kozo Fukumoto et al.   ORGANOMETALLICS

Hydroformylation Catalysis at Eastman Chemical: Generations of Catalysts

(2012) Thomas A. Puckette   TOPICS IN CATALYSIS

Factors Influencing the Activity, Selectivity, and Stability of Rh-Based Supported Ionic Liquid Phase (SILP) Catalysts for Hydroformylation of Propene

(2012) Sankaranarayanapillai Shylesh et al.   ACS Catalysis

Strong π-Acceptor Ligands in Rhodium-Catalyzed Hydroformylation of Ethene and 1-Octene: Operando Catalysis

(2012) Olivier Diebolt et al.   ACS Catalysis

Bifunctional Organorhodium Solid Acid Catalysts for Methanol Carbonylation

(2012) Lee D. Dingwall et al.   ACS Catalysis

Operando Spectroscopy in Catalytic Carbonylation Reactions

(2012) Olivier Diebolt et al.   ACS Catalysis

Palladium-Catalyzed Hydroesterification of Alkynes Employing Aryl Formates without the Use of External Carbon Monoxide

(2011) Yuko Katafuchi et al.   ADVANCED SYNTHESIS & CATALYSIS

Homogeneous Hydrogenations of Nitriles Catalyzed by Rhenium Complexes

(2011) Kunjanpillai Rajesh et al.   ADVANCED SYNTHESIS & CATALYSIS

A Serendipitous Discovery: Nickel Catalyst for the Cycloaddition of Diynes with Unactivated Nitriles

(2011) Puneet Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Improved Ruthenium-Catalyzed Amination of Alcohols with Ammonia: Synthesis of Diamines and Amino Esters

(2011) Sebastian Imm et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine−Phosphinite and Phosphine−Phosphite Ligands: Preparation and Applications in Asymmetric Catalysis

(2011) Héctor Fernández-Pérez et al.   CHEMICAL REVIEWS

Reductive Elimination of ArCF3 from Bidentate PdII Complexes: A Computational Study

(2011) Philipp Anstaett et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism of the Dehydrogenative Silylation of Alcohols Catalyzed by Cationic Gold Complexes: An Experimental and Theoretical Study

(2011) Stéphanie Labouille et al.   CHEMISTRY-A EUROPEAN JOURNAL

A General Cyclocarbonylation of Aryl Bromides and Triflates with Acetylenes: Palladium-Catalyzed Synthesis of 3-Alkylidenefuran-2-ones

(2011) Xiao-Feng Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Steric nature of the bite angle. A closer and a broader look

(2011) Willem-Jan van Zeist et al.   DALTON TRANSACTIONS

Highly selective hydroformylation of long-chain alkenes in a supercritical fluid ionic liquid biphasic system

(2011) Thulani E. Kunene et al.   GREEN CHEMISTRY

Cobalt−Xantphos-Catalyzed, LiCl-Mediated Preparation of Arylzinc Reagents from Aryl Iodides, Bromides, and Chlorides

(2011) Meng-Yi Jin et al.   JOURNAL OF ORGANIC CHEMISTRY

A theoretical study of the electronic effect of the ligand bite angle on the hydrosilylation reaction of ketones by Cu(I) diphosphine complexes

(2011) Thomas Gathy et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Cationic iridium complexes of the Xantphos ligand. Flexible coordination modes and the isolation of the hydride insertion product with an alkene

(2011) Ashley J. Pontiggia et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Rhenium in Homogeneous Catalysis: [ReBrH(NO)(labile ligand)(large-bite-angle diphosphine)] Complexes as Highly Active Catalysts in Olefin Hydrogenations

(2011) Balz Dudle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2011) Alexandre Lumbroso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Borylation of Nitriles through the Cleavage of Carbon–Cyano Bonds

(2011) Mamoru Tobisu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C3-Benzylation of Indoles

(2011) Ye Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-catalysed oxidative synthesis of heterocycles from alcohols

(2011) Andrew J. A. Watson et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Cross-Coupling of Benzyl Thioacetates and Aryl Halides

(2011) Krista M. Wager et al.   ORGANIC LETTERS

A Practical Synthesis of Biaryls via a Thermal Decarboxylative Pd-Catalyzed Cross-Coupling Reaction Operating at Moderate Temperature

(2011) David Mitchell et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Intramolecular Insertion of Alkenes into Pd−N Bonds. Effects of Substrate and Ligand Structure on the Reactivity of (P−P)Pd(Ar)[N(Ar1)(CH2)3CR═CHR′] Complexes

(2011) Joshua D. Neukom et al.   ORGANOMETALLICS

Rhenium Nitrosyl Complexes Bearing Large-Bite-Angle Diphosphines

(2011) Balz Dudle et al.   ORGANOMETALLICS

DFT Study of the Homogeneous Hydroformylation of Propene Promoted by a Heterobimetallic Pt–Sn Catalyst

(2011) Roberta P. Dias et al.   ORGANOMETALLICS

Mechanistic Study of Rhodium/xantphos-Catalyzed Methanol Carbonylation

(2011) Gary L. Williams et al.   ORGANOMETALLICS

CF3–Ph Reductive Elimination from [(Xantphos)Pd(CF3)(Ph)]

(2011) Vladimir I. Bakhmutov et al.   ORGANOMETALLICS

Highly Efficient Nickel-Catalyzed 2-Methyl-3-butenenitrile Isomerization: Applications and Mechanistic Studies Employing the TTP Ligand Family

(2011) Michael E. Tauchert et al.   ORGANOMETALLICS

Copper-catalyzed boration of activated alkynes. Chiral boranes via a one-pot copper-catalyzed boration and reduction protocol

(2011) Ho-Young Jung et al.   TETRAHEDRON

Practical procedure for copper(I)-catalyzed allylic boryl substitution with stoichiometric alkoxide base

(2011) Hajime Ito et al.   TETRAHEDRON

“On-water” rhodium-catalysed hydroformylation for the production of linear alcohols

(2011) Olivier Diebolt et al.   Catalysis Science & Technology

Palladium-Catalyzed Aryl Amination Reactions of 6-Bromo- and 6-Chloropurine Nucleosides

(2010) Paul F. Thomson et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Linear-Selective Hydroformylation of 1-Alkenes using Formaldehyde as a Syngas Substitute

(2010) Gouki Makado et al.   ADVANCED SYNTHESIS & CATALYSIS

High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System

(2010) Kohei Takahashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General and Efficient Iridium-Catalyzed Hydroformylation of Olefins

(2010) Irene Piras et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Amination of Secondary Alcohols Using Ammonia

(2010) Dennis Pingen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum(ii)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines

(2010) Kristina L. Toups et al.   CHEMICAL COMMUNICATIONS

Iridium-catalysed amine alkylation with alcohols in water

(2010) Ourida Saidi et al.   CHEMICAL COMMUNICATIONS

Ordered mesoporous materials as solid supports for rhodium–diphosphine catalysts with remarkable hydroformylation activity

(2010) Fabrizio Marras et al.   CHEMICAL COMMUNICATIONS

Reaction Mechanism for the LiCl-Mediated Directed Zinc Insertion: A Computational and Experimental Study

(2010) Ching-Yuan Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Competitive and Selective Csp3Br versus Csp2Br Bond Activation in Palladium-Catalysed Suzuki Cross-Coupling: An Experimental and Theoretical Study of the Role of Phosphine Ligands

(2010) Cristian Mollar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rational design of diphosphorus ligands – a route to superior catalysts

(2010) Jason A. Gillespie et al.   DALTON TRANSACTIONS

Synthesis and Structure of Intermediates in Copper-Catalyzed Alkylation of Diphenylphosphine

(2010) Matthew F. Cain et al.   INORGANIC CHEMISTRY

Thermodynamic Studies of [H2Rh(diphosphine)2]+and [HRh(diphosphine)2(CH3CN)]2+Complexes in Acetonitrile

(2010) Aaron D. Wilson et al.   INORGANIC CHEMISTRY

15N Double-Labeled Guanosine from Inosine through Ring-Opening−Ring-Closing and One-Pot Pd-Catalyzed C−O and C−N Cross-Coupling Reactions

(2010) Joaquim Caner et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselectivity and memory effects in palladium catalyzed allylic alkylations with bidentate P^PS donor ligands

(2010) Suzanna C. Milheiro et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Regiocontrol in the palladium-catalyzed hydrophosphinylation of terminal alkynes

(2010) Yamina Belabassi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Dienyl Homoallyl Alcohols via Palladium Catalyzed Ene-Type Reaction of Aldehydes with 1,3-Dienes

(2010) Masahiro Fukushima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C−O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin-Related Polymers

(2010) Jason M. Nichols et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Efficient Palladium/Copper Cocatalytic System for Direct Arylation of Heteroarenes: An Unexpected Effect of Cu(Xantphos)I

(2010) Jinkun Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroformylation Reaction of Alkylidenecyclopropane Derivatives: A New Pathway for the Formation of Acyclic Aldehydes Containing Quaternary Stereogenic Carbons

(2010) Samah Simaan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of benzylphosphonates via a palladium(0)-catalyzed cross-coupling of H-phosphonate diesters with benzyl halides. Synthetic and mechanistic studies

(2010) Gaston Lavén et al.   NEW JOURNAL OF CHEMISTRY

Strategies for the asymmetric synthesis of H-phosphinate esters

(2010) Karla Bravo-Altamirano et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Controlling Selectivity in Intermolecular Alkene or Aldehyde Hydroacylation Reactions Catalyzed by {Rh(L2)}+Fragments

(2010) Rebekah J. Pawley et al.   ORGANOMETALLICS

Phenoxaphosphine-Based Diphosphine Ligands. Synthesis and Application in the Hydroformylation Reaction

(2010) Erik Zuidema et al.   ORGANOMETALLICS

New Low-Temperature NMR Studies Establish the Presence of a Second Equatorial−Apical Isomer of [(R,S)-Binaphos](CO)2RhH

(2010) Dante A. Castillo Molina et al.   ORGANOMETALLICS

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

(2010) E. J. Cho et al.   SCIENCE

Addition reaction of 2-phenylbenzoic acid onto unactivated olefins catalyzed by Ru(II)–xantphos catalysis

(2010) Yohei Oe et al.   TETRAHEDRON LETTERS

Highlights of the Rh-catalysed asymmetric hydroformylation of alkenes using phosphorus donor ligands

(2010) Aitor Gual et al.   TETRAHEDRON-ASYMMETRY

Vinylogous reactivity of silver(i) vinylcarbenoids

(2010) Jørn H. Hansen et al.   Chemical Science

Fast and Selective Hydroaminomethylation Using Xanthene-Based Amino-Functionalized Ligands

(2009) Bart Hamers et al.   ChemCatChem

Bite angle effects of diphosphines in C–C and C–X bond forming cross coupling reactions

(2009) Mandy-Nicole Birkholz (née Gensow) et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Isomerization and Hydroformylation of Olefins

(2009) Reiko Jennerjahn et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Steric Nature of the Bite Angle

(2009) Willem-Jan van Zeist et al.   CHEMISTRY-A EUROPEAN JOURNAL

Away from phosgene: reductive carbonylation of nitroarenes and oxidative carbonylation of amines, understanding the mechanism to improve performance

(2009) Fabio Ragaini   DALTON TRANSACTIONS

Dicarbonylruthenium(II) complexes of diphosphine ligands and their catalytic activity

(2009) Biswajit Deb et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Mechanistic investigation of platinum-catalysed hydroformylation of propene: A density functional study

(2009) Anikó Bedekovits et al.   INORGANICA CHIMICA ACTA

Trans-chelating ligands in palladium-catalyzed carbonylative coupling and methoxycarbonylation of aryl halides

(2009) Luba Kaganovsky et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Pd-Catalyzed N-Arylation of Secondary Acyclic Amides: Catalyst Development, Scope, and Computational Study

(2009) Jacqueline D. Hicks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Biaryl Cross-Coupling Reactions between Aryl Halides and Aryl Grignard Reagents: A New Catalyst Combination ofN-Heterocyclic Carbenes and Iron, Cobalt, and Nickel Fluorides

(2009) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Platinum-Catalyzed Direct Amination of Allylic Alcohols under Mild Conditions: Ligand and Microwave Effects, Substrate Scope, and Mechanistic Study

(2009) Takashi Ohshima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-CatalyzedN-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

(2009) M. Haniti S. A. Hamid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Amidines UsingN-Allyl Ynamides. A Palladium-Catalyzed Allyl Transfer through an Ynamido−π-Allyl Complex

(2009) Yu Zhang et al.   ORGANIC LETTERS

Synthesis of Benzazoles by Hydrogen-Transfer Catalysis

(2009) A. John Blacker et al.   ORGANIC LETTERS

Palladium-Catalyzed Cross-Coupling Reaction of Secondary Benzylic Bromides with Grignard Reagents

(2009) Ana López-Pérez et al.   ORGANIC LETTERS

Cu(I)-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes Bearing a Primary or Secondary Amino Group in Alcoholic Solvents

(2009) Hirohisa Ohmiya et al.   ORGANIC LETTERS

Factors Controlling the Selective Hydroformylation of Internal Alkenes to Linear Aldehydes. 1. The Isomerization Step

(2009) Maria Àngels Carvajal et al.   ORGANOMETALLICS

Synthesis of benzamide-C-ribonucleosides by Pd-catalyzed aminocarbonylations

(2009) Martin Štefko et al.   TETRAHEDRON

Alkynylcyanation of alkynes and dienes catalyzed by nickel

(2009) Yasuhiro Hirata et al.   TETRAHEDRON

Efficient synthesis of mono- and diarylphosphinic acids: a microwave-assisted palladium-catalyzed cross-coupling of aryl halides with phosphinate

(2009) Marcin Kalek et al.   TETRAHEDRON

Enantioselective Hydrogenation of Enones with a Hydroformylation Catalyst

(2008) Caroline J. Scheuermann née Taylor et al.   ADVANCED SYNTHESIS & CATALYSIS

Hydroaminomethylation ofn-Alkenes in a Biphasic Ionic Liquid System

(2008) Bart Hamers et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium Nanoparticles in Allylic Alkylations and Heck Reactions: The Molecular Nature of the Catalyst Studied in a Membrane Reactor

(2008) Montserrat Diéguez et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative

(2008) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Synthesis of Primary Amines Directly from Alcohols and Ammonia

(2008) Chidambaram Gunanathan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed addition of diboron reagents to α,β-acetylenic esters: efficient synthesis of β-boryl-α,β-ethylenic esters

(2008) Ji-Eon Lee et al.   CHEMICAL COMMUNICATIONS

Intermolecular Alkene and Alkyne Hydroacylation with β-S-Substituted Aldehydes: Mechanistic Insight into the Role of a Hemilabile P-O-P Ligand

(2008) Gemma L. Moxham et al.   CHEMISTRY-A EUROPEAN JOURNAL

Why Platinum Catalysts Involving Ligands with Large Bite Angle Are so Efficient in the Allylation of Amines: Design of a Highly Active Catalyst and Comprehensive Experimental and DFT Study

(2008) Guilhem Mora et al.   CHEMISTRY-A EUROPEAN JOURNAL

Green, Palladium-Catalyzed Synthesis of BenzylicH-Phosphinates from Hypophosphorous Acid and Benzylic Alcohols

(2008) Laëtitia Coudray et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Effects of ligands on the rhodium-catalyzed hydroformylation of acrylate

(2008) Ourida Saidi et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Palladium-Catalyzed Carbonylation Reactions of Aryl Bromides at Atmospheric Pressure: A General System Based on Xantphos

(2008) Joseph R. Martinelli et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Weinreb Amides via Pd-Catalyzed Aminocarbonylation of Heterocyclic-Derived Triflates

(2008) A. Deagostino et al.   JOURNAL OF ORGANIC CHEMISTRY

Xantphos as an Efficient Ligand for Palladium-Catalyzed Cross-Coupling Reactions of Aryl Bromides and Triflates with Allyl Acetates and Indium

(2008) Dong Seomoon et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Reactions of Hypophosphorous Compounds with Allenes, Dienes, and Allylic Electrophiles:  Methodology for the Synthesis of AllylicH-Phosphinates

(2008) Karla Bravo-Altamirano et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates

(2008) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of the Fully Protected Phosphoramidite of the Benzene-DNA Adduct,N2-(4-Hydroxyphenyl)-2′-Deoxyguanosine and Incorporation of the Later into DNA Oligomers

(2008) Ahmed Chenna et al.   NUCLEOSIDES NUCLEOTIDES & NUCLEIC ACIDS

Allylic Phosphinates via Palladium-Catalyzed Allylation ofH-Phosphinic Acids with Allylic Alcohols

(2008) Laëtitia Coudray et al.   ORGANIC LETTERS

Pd-Catalyzed Carboetherification of β,γ-Unsaturated Oximes: A Novel Approach to Δ2-Isoxazolines

(2008) Dahong Jiang et al.   ORGANIC LETTERS

An Improved Protocol for the Pd-Catalyzed α-Arylation of Aldehydes with Aryl Halides

(2008) Rubén Martín et al.   ORGANIC LETTERS

First Copper(I) Ferrocenyltetraphosphine Complexes: Possible Involvement in Sonogashira Cross-Coupling Reaction?

(2008) Matthieu Beaupérin et al.   ORGANOMETALLICS

Enantioselective Addition of Terminal Alkynes to Aromatic Aldehydes Catalyzed by Copper(I) Complexes with Wide-Bite-Angle Chiral Bisphosphine Ligands: Optimization, Scope, and Mechanistic Studies

(2008) Yohsuke Asano et al.   ORGANOMETALLICS

Palladium-catalyzed cascade one-pot synthesis of 5-arylmethylisoxazolidines from N-homoallylhydroxylamines with aryl bromides

(2008) Dahong Jiang et al.   TETRAHEDRON

Palladium-catalyzed monoamination of dihalogenated benzenes

(2008) Simon Birksø Larsen et al.   TETRAHEDRON

The Rate-Determining Step in the Rhodium–Xantphos-Catalysed Hydroformylation of 1-Octene

(2007) Erik Zuidema et al.   CHEMISTRY-A EUROPEAN JOURNAL

Study of bite angle effects in hydroformylation

(2007) Patrick D. Achord et al.   JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM