Nickel-catalyzed arylation of heteroaryl-containing diarylmethanes: exceptional reactivity of the Ni(NIXANTPHOS)-based catalyst

Nickel-Catalyzed Monoarylation of Ammonia

(2015) Andrey Borzenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalyzed thiolation of unactivated aryl C–H bonds: efficient access to diverse aryl sulfides

(2015) Sheng-Yi Yan et al.   CHEMICAL COMMUNICATIONS

Ni-Catalyzed Alkenylation of Ketone Enolates under Mild Conditions: Catalyst Identification and Optimization

(2015) Michael Grigalunas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed α-Arylation of Aryl Acetic Acid Derivatives via Dienolate Intermediates with Aryl Chlorides and Bromides

(2015) Sheng-Chun Sha et al.   ORGANIC LETTERS

Nickel-Catalyzed Direct Thioetherification of β-C(sp3)–H Bonds of Aliphatic Amides

(2015) Cong Lin et al.   ORGANIC LETTERS

Selective synthesis of either enantiomer of an anti-breast cancer agent via a common enantioenriched intermediate

(2015) Aaron George Johnson et al.   TETRAHEDRON LETTERS

Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp3)–H bonds

(2015) José A. Fernández-Salas et al.   Chemical Science

Nickel N-Heterocyclic Carbene-Catalyzed C–C Bond Formation: Reactions and Mechanistic Aspects

(2015) Mickaël Henrion et al.   ACS Catalysis

Recent Advances in the Synthesis of Triarylmethanes by Transition Metal Catalysis

(2015) Masakazu Nambo et al.   ACS Catalysis

Ni(ii) source as a pre-catalyst for the cross-coupling of benzylic pivalates with arylboronic acids: facile access to tri- and diarylmethanes

(2015) Qiang Chen et al.   RSC Advances

Nickel-Catalyzed Dehydrogenative Cross-Coupling: Direct Transformation of Aldehydes into Esters and Amides

(2014) Aaron M. Whittaker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed CH Alkylations: Direct Secondary Alkylations and Trifluoroethylations of Arenes

(2014) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-catalyzed chelation-assisted direct arylation of unactivated C(sp3)–H bonds with aryl halides

(2014) Mingliang Li et al.   CHEMICAL COMMUNICATIONS

Metal-catalyzed activation of ethers via C–O bond cleavage: a new strategy for molecular diversity

(2014) Josep Cornella et al.   CHEMICAL SOCIETY REVIEWS

Nickel-Catalyzed Site-Selective Amidation of Unactivated C(sp3)H Bonds

(2014) Xuesong Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient C-N and C-S Bond Formation Using the Highly Active [Ni(allyl)Cl(IPr*OMe)] Precatalyst

(2014) Anthony R. Martin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Triarylmethanes by Palladium-Catalyzed C–H/C–O Coupling of Oxazoles and Diarylmethanol Derivatives

(2014) Sho Tabuchi et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Site-Selective Alkylation of Unactivated C(sp3)–H Bonds

(2014) Xuesong Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes

(2014) Joseph S. Bair et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NiXantphos: A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides

(2014) Jiadi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex

(2014) Shaozhong Ge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Palladium-Catalyzed Regioselective Arylation of 1,1,3-Triaryl-2-azaallyl Anions with Aryl Chlorides

(2014) Minyan Li et al.   ORGANIC LETTERS

Synthesis of diarylmethylamines via palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions

(2014) Minyan Li et al.   Chemical Science

Modular Synthesis of Triarylmethanes through Palladium-Catalyzed Sequential Arylation of Methyl Phenyl Sulfone

(2013) Masakazu Nambo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combined Experimental and Theoretical Study on the Reductive Cleavage of Inert C–O Bonds with Silanes: Ruling out a Classical Ni(0)/Ni(II) Catalytic Couple and Evidence for Ni(I) Intermediates

(2013) Josep Cornella et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Direct Arylation of Methyl Sulfoxides with Aryl Halides

(2013) Tiezheng Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Retention or Inversion in Stereospecific Nickel-Catalyzed Cross-Coupling of Benzylic Carbamates with Arylboronic Esters: Control of Absolute Stereochemistry with an Achiral Catalyst

(2013) Michael R. Harris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Couplings of Benzylic Pivalates with Arylboroxines: Stereospecific Formation of Diarylalkanes and Triarylmethanes

(2013) Qi Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Impact of copper-catalyzed cross-coupling reactions in natural product synthesis: the emergence of new retrosynthetic paradigms

(2013) Gwilherm Evano et al.   NATURAL PRODUCT REPORTS

Synthesis of Enantioenriched Triarylmethanes by Stereospecific Cross-Coupling Reactions

(2012) Buck L. H. Taylor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and General Conditions for Negishi Cross-Coupling Enabled by the Use of Palladacycle Precatalysts

(2012) Yang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Arylation of a CH Bond in Pyridine and Related Six-Membered N-Heteroarenes Using Organozinc Reagents

(2012) Isao Hyodo et al.   Chemistry-An Asian Journal

An Efficient Class of P,N-Type “PhMezole-phos” Ligands: Applications in Palladium-Catalyzed Suzuki Coupling of Aryl Chlorides

(2012) Shun Man Wong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed C(sp3)–H Arylation of Diarylmethanes at Room Temperature: Synthesis of Triarylmethanes via Deprotonative-Cross-Coupling Processes

(2012) Jiadi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design and preparation of new palladium precatalysts for C–C and C–N cross-coupling reactions

(2012) Nicholas C. Bruno et al.   Chemical Science

Additive effects on palladium-catalyzed deprotonative-cross-coupling processes (DCCP) of sp3C–H bonds in diarylmethanes

(2012) Ana Bellomo et al.   Chemical Science

User-Friendly [(Diglyme)NiBr2]-Catalyzed Direct Alkylations of Heteroarenes with Unactivated Alkyl Halides through CH Bond Cleavages

(2011) Lutz Ackermann et al.   ADVANCED SYNTHESIS & CATALYSIS

PdCl2-catalyzed efficient allylation and benzylation of heteroarenes under ligand, base/acid, and additive-free conditions

(2011) Feng-Quan Yuan et al.   CHEMICAL COMMUNICATIONS

Triphenylmethyl Derivatives Enhances the Anticancer Effect of Immunotoxins

(2011) Karianne Risberg et al.   JOURNAL OF IMMUNOTHERAPY

Nickel-Catalyzed Asymmetric α-Arylation and Heteroarylation of Ketones with Chloroarenes: Effect of Halide on Selectivity, Oxidation State, and Room-Temperature Reactions

(2011) Shaozhong Ge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Arylation of 1H-Perfluoroalkanes

(2011) Ilya Popov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Chelation-Assisted Transformations Involving Ortho C–H Bond Activation: Regioselective Oxidative Cycloaddition of Aromatic Amides to Alkynes

(2011) Hirotaka Shiota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Decarboxylative Arylation of Potassium Cyanoacetate: Synthesis of α-Diaryl Nitriles from Aryl Halides

(2011) Pui Yee Yeung et al.   ORGANIC LETTERS

Pd(0)-Catalyzed Diarylation of sp3C−H Bond in (2-Azaaryl)methanes

(2011) Guoyong Song et al.   ORGANIC LETTERS

Synthesis of Polyarylated Methanes through Cross-Coupling of Tricarbonylchromium-Activated Benzyllithiums

(2010) Genette I. McGrew et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

(2010) Brad M. Rosen et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Direct Arylation of Heteroarenes with Aryl Mesylates

(2010) Chau Ming So et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Controlled Regioselectivity in Palladium-Catalyzed Cross Coupling Reactions

(2010) Franziska Schoenebeck et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids

(2010) Tom Kinzel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Heterocycle and Arene Deprotonative Alkylation

(2010) Ly Dieu Tran et al.   ORGANIC LETTERS

Diamine ligands in copper-catalyzed reactions

(2010) David S. Surry et al.   Chemical Science

Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

(2010) David S. Surry et al.   Chemical Science

Cross Dehydrogenative Arylation (CDA) of a Benzylic CH Bond with Arenes by Iron Catalysis

(2009) Yi-Zhou Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and applications of Rhodamine derivatives as fluorescent probes

(2009) Mariana Beija et al.   CHEMICAL SOCIETY REVIEWS

Coming of Age: Sustainable Iron-Catalyzed Cross-Coupling Reactions

(2009) Waldemar Maximilian Czaplik et al.   ChemSusChem

Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes

(2009) Fabiola Barrios-Landeros et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies on Ni(dppe)Cl2-Catalyzed Chain-Growth Polymerizations: Evidence for Rate-Determining Reductive Elimination

(2009) Erica L. Lanni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Cross-Coupling Reaction of Secondary Benzylic Bromides with Grignard Reagents

(2009) Ana López-Pérez et al.   ORGANIC LETTERS

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Development of Versatile Methods for Palladium-Catalyzed Coupling Reactions of Aryl Electrophiles through the Use of P(t-Bu)3and PCy3as Ligands

(2008) Gregory C. Fu   ACCOUNTS OF CHEMICAL RESEARCH

The Promise and Challenge of Iron-Catalyzed Cross Coupling

(2008) Benjamin D. Sherry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Cross-Coupling of Non-Activated Secondary Alkyl Halides

(2008) Frank Glorius   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biaryl Phosphane Ligands in Palladium-Catalyzed Amination

(2008) David S. Surry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Reduction-Triggered Fluorescence Probe for Sensing Nucleic Acids

(2008) Hiroshi Abe et al.   BIOCONJUGATE CHEMISTRY

Cobalt-catalyzed cross-coupling reactions

(2008) Corinne Gosmini et al.   CHEMICAL COMMUNICATIONS

Catalytic selective bis-arylation of imines with anisole, phenol, thioanisole and analogues

(2008) Cong-Rong Liu et al.   CHEMICAL COMMUNICATIONS

A new trend in rhodamine-based chemosensors: application of spirolactam ring-opening to sensing ions

(2008) Ha Na Kim et al.   CHEMICAL SOCIETY REVIEWS

Covalent radii revisited

(2008) Beatriz Cordero et al.   DALTON TRANSACTIONS

Understanding the Behavior ofN-Tosyl andN-2-Pyridylsulfonyl Imines in CuII-Catalyzed Aza-Friedel−Crafts Reactions

(2008) Inés Alonso et al.   JOURNAL OF ORGANIC CHEMISTRY

A General Method for Copper-Catalyzed Arylation of Arene C−H Bonds

(2008) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Suzuki-Miyaura Coupling of Diarylmethyl Carbonates with Arylboronic Acids:  A New Access to Triarylmethanes

(2008) Jung-Yi Yu et al.   ORGANIC LETTERS

FeCl3: an efficient catalyst for reactions of electron-rich arenes with imines or aziridines

(2008) Zhiyong Wang et al.   TETRAHEDRON

A general and efficient synthesis of substituted fluorenes and heterocycle-fused indenes containing thiophene or indole rings utilizing a Suzuki–Miyaura coupling and acid-catalyzed Friedel–Crafts reactions as key steps

(2008) Guijie Li et al.   TETRAHEDRON

A simple access to triarylmethane derivatives from aromatic aldehydes and electron-rich arenes catalyzed by FeCl3

(2007) Zhongxian Li et al.   TETRAHEDRON