gem-Diborylalkanes: recent advances in their preparation, transformation and application

Base-controlled highly selective synthesis of alkyl 1,2-bis(boronates) or 1,1,2-tris(boronates) from terminal alkynes

(2017) Guoliang Gao et al.   GREEN CHEMISTRY

Benzyltriboronates: Building Blocks for Diastereoselective Carbon–Carbon Bond Formation

(2017) W. Neil Palmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–O Functionalization of α-Oxyboronates: A Deoxygenative gem-Diborylation and gem-Silylborylation of Aldehydes and Ketones

(2017) Lu Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Tandem Bis-Electrophile Couplings of Diborylmethane

(2017) Stephanie A. Murray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-metal-free synthesis of 1,1-diboronate esters with a fully substituted benzylic center via diborylation of lithiated carbamates

(2017) Haonan Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition-Metal-Free Homologative Cross-Coupling of Aldehydes and Ketones with Geminal Bis(boron) Compounds

(2017) Thomas C. Stephens et al.   ORGANIC LETTERS

Copper-Mediated SN2′ Allyl–Alkyl and Allyl–Boryl Couplings of Vinyl Cyclic Carbonates

(2017) Núria Miralles et al.   ORGANIC LETTERS

Chemo- and Stereoselective Crotylation of Aldehydes and Cyclic Aldimines with Allylic gem-Diboronate Ester

(2017) Jinyoung Park et al.   ORGANIC LETTERS

Selective uni- and bidirectional homologation of diborylmethane

(2017) Daniel J. Blair et al.   Chemical Science

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

(2017) Lei Li et al.   Nature Communications

Catalytic SN 2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis

(2016) Ying Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Diastereoselective 1,2-Additions to α-Ketoesters with Diborylmethane and Substituted 1,1-Diborylalkanes

(2016) Stephanie A. Murray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Regioselective Alkylation of Pyridine N -Oxides Using 1,1-Diborylalkanes as Alkylating Reagents

(2016) Woohyun Jo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed cross-coupling reactions of epoxides with gem-diborylmethane: access to γ-hydroxyl boronic esters

(2016) Ahmed Ebrahim-Alkhalil et al.   CHEMICAL COMMUNICATIONS

Opportunegem-Silylborylation of Carbonyl Compounds: A Modular and Stereocontrolled Entry to Tetrasubstituted Olefins

(2016) Enrico La Cascia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp3)–H Bonds

(2016) W. Neil Palmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis

(2016) Colin Diner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective Coupling of 1,1-Bis[(pinacolato)boryl]alkanes for the Transition-Metal-Free Borylation of Aryl and Vinyl Halides: A Combined Experimental and Theoretical Investigation

(2016) Yeosan Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese-Catalyzed Borylation of Unactivated Alkyl Chlorides

(2016) Thomas C. Atack et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed SN2′-Selective Allylic Substitution Reaction of gem-Diborylalkanes

(2016) Zhen-Qi Zhang et al.   ORGANIC LETTERS

Modular, Catalytic Enantioselective Construction of Quaternary Carbon Stereocenters by Sequential Cross-Coupling Reactions

(2016) Bowman Potter et al.   ORGANIC LETTERS

Copper-Catalyzed Diastereoselective Addition of Diborylmethane to N-tert-Butanesulfinyl Aldimines: Synthesis of β-Aminoboronates

(2016) Jinyoung Park et al.   ORGANIC LETTERS

Silver-Assisted, Iridium-Catalyzed Allylation of Bis[(pinacolato)boryl]methane Allows the Synthesis of Enantioenriched Homoallylic Organoboronic Esters

(2016) Miao Zhan et al.   ACS Catalysis

Pd-catalyzed cross-coupling of 1,1-diborylalkanes with aryl triflates

(2016) Long-Can Cui et al.   RSC Advances

Synthesis of 1,1-diboronate esters by cobalt-catalyzed sequential hydroboration of terminal alkynes

(2016) Ziqing Zuo et al.   Organic Chemistry Frontiers

Silver(I)-Catalyzed Diastereoselective Synthesis ofanti-1,2-Hydroxyboronates

(2015) Matthew V. Joannou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes

(2015) Junghoon Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron-selective reactions as powerful tools for modular synthesis of diverse complex molecules

(2015) Liang Xu et al.   CHEMICAL SOCIETY REVIEWS

Reaction Optimization, Scalability, and Mechanistic Insight on the Catalytic Enantioselective Desymmetrization of 1,1-Diborylalkanes via Suzuki-Miyaura Cross-Coupling

(2015) Ho-Yan Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with 2,2′-Dibromobiphenyls: Synthesis of 9H-Fluorenes

(2015) Shuai Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations–Hydroboration

(2015) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Diastereoselective Synthesis of 1,2-Hydroxyboronates through Cu-Catalyzed Additions of Alkylboronates to Aldehydes

(2015) Matthew V. Joannou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkene Isomerization–Hydroboration Promoted by Phosphine-Ligated Cobalt Catalysts

(2015) Margaret L. Scheuermann et al.   ORGANIC LETTERS

Synthesis of Vinyl Boronates from Aldehydes by a Practical Boron–Wittig Reaction

(2015) John R. Coombs et al.   ORGANIC LETTERS

Palladium(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with Vinyl Bromides and 1,1-Dibromoalkenes

(2014) Huan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Synthesis of 1,1-Diborylalkanes through Regioselective Dihydroboration of Terminal Alkynes

(2014) Sumin Lee et al.   Chemistry-An Asian Journal

Nonracemic Allylic Boronates through Enantiotopic-Group-Selective Cross-Coupling of Geminal Bis(boronates) and Vinyl Halides

(2014) Bowman Potter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Access to Elusive α-Boryl Carbanions and Their Alkylation: An Umpolung Construction for Organic Synthesis

(2014) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiomerically Enriched Tris(boronates): Readily Accessible Conjunctive Reagents for Asymmetric Synthesis

(2014) John R. Coombs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed/Promoted Cross-coupling of gem-Diborylalkanes with Nonactivated Primary Alkyl Halides: An Alternative Route to Alkylboronic Esters

(2014) Zhen-Qi Zhang et al.   ORGANIC LETTERS

On the scope of the Pt-catalyzed Srebnik diborylation of diazoalkanes. An efficient approach to chiral tertiary boronic esters and alcohols via B-stabilized carbanions

(2014) Andrew J. Wommack et al.   TETRAHEDRON LETTERS

Regio- and Enantioselective Copper(I)-Catalyzed Hydroboration of Borylalkenes: Asymmetric Synthesis of 1,1-Diborylalkanes

(2013) Xinhui Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formal Carbon Insertion of N-Tosylhydrazone into B–B and B–Si Bonds: gem-Diborylation and gem-Silylborylation of sp3 Carbon

(2013) Huan Li et al.   ORGANIC LETTERS

Iridium-catalyzed diborylation of benzylic C–H bonds directed by a hydrosilyl group: synthesis of 1,1-benzyldiboronate esters

(2013) Seung Hwan Cho et al.   Chemical Science

Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature

(2012) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of Symmetrical and Unsymmetrical Diarylmethanes via Diborylmethane

(2012) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper(I)-Catalyzed Boryl Substitution of Unactivated Alkyl Halides

(2012) Hajime Ito et al.   ORGANIC LETTERS

Catalytic, Direct Synthesis of Bis(boronate) Compounds

(2012) Jun Takaya et al.   ACS Catalysis

Alkylboronic Esters from Copper-Catalyzed Borylation of Primary and Secondary Alkyl Halides and Pseudohalides

(2011) Chu-Ting Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of Allylsilanes Bearing Tetrasubstituted Olefin via 2,2-Diborylethylsilane

(2011) Kohei Endo et al.   CHEMISTRY LETTERS

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of Benzylboronates

(2011) Kohei Endo et al.   ORGANIC LETTERS

Formation and Synthetic Applications of Metalated Organoboranes

(2010) Tomasz Klis et al.   CURRENT ORGANIC CHEMISTRY

Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates

(2010) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature

(2010) Kohei Endo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 1,1-Organodiboronates via Rh(I)Cl-Catalyzed Sequential Regioselective Hydroboration of 1-Alkynes

(2009) Kohei Endo et al.   SYNLETT

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Polyborylated reagents for modern organic synthesis

(2008) Masaki SHIMIZU et al.   PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES