Boron-selective reactions as powerful tools for modular synthesis of diverse complex molecules

Direct introduction of a naphthalene-1,8-diamino boryl [B(dan)] group by a Pd-catalysed selective boryl transfer reaction

(2015) Liang Xu et al.   CHEMICAL COMMUNICATIONS

Hydroxyl-Directed Cross-Coupling: A Scalable Synthesis of Debromohamigeran E and Other Targets of Interest

(2015) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Synthesis of many different types of organic small molecules using one automated process

(2015) J. Li et al.   SCIENCE

Chemoselective Boronic Ester Synthesis by Controlled Speciation

(2014) James W. B. Fyfe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Differentiated Polyboron Arenes Prepared by Direct CH Borylation and Their Highly Selective Suzuki-Miyaura Cross-Coupling Reactions

(2014) Liang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with Vinyl Bromides and 1,1-Dibromoalkenes

(2014) Huan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonracemic Allylic Boronates through Enantiotopic-Group-Selective Cross-Coupling of Geminal Bis(boronates) and Vinyl Halides

(2014) Bowman Potter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

(2014) Chunrui Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Access to Elusive α-Boryl Carbanions and Their Alkylation: An Umpolung Construction for Organic Synthesis

(2014) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of most polyene natural product motifs using just 12 building blocks and one coupling reaction

(2014) Eric M. Woerly et al.   Nature Chemistry

Accessing 2-(Hetero)arylmethyl-, -allyl-, and -propargyl-2,1-borazaronaphthalenes: Palladium-Catalyzed Cross-Couplings of 2-(Chloromethyl)-2,1-borazaronaphthalenes

(2014) Gary A. Molander et al.   ORGANIC LETTERS

Boron-Selective Biaryl Coupling Approach to Versatile Dibenzoxaborins and Application to Concise Synthesis of Defucogilvocarcin M

(2014) Yuto Sumida et al.   ORGANIC LETTERS

Copper-Catalyzed/Promoted Cross-coupling of gem-Diborylalkanes with Nonactivated Primary Alkyl Halides: An Alternative Route to Alkylboronic Esters

(2014) Zhen-Qi Zhang et al.   ORGANIC LETTERS

Regio- and Enantioselective Copper(I)-Catalyzed Hydroboration of Borylalkenes: Asymmetric Synthesis of 1,1-Diborylalkanes

(2013) Xinhui Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Regio- and Stereocontrolled Access to γ-Boronated Unsaturated Amino Esters and Derivatives from (Z)-Alkenyl 1,2-Bis(boronates)

(2013) Tailor Sridhar et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of (Z)- and (E)-2-Methyl-1,5-anti-Pentenediols via an Allene Hydroboration–Double-Allylboration Reaction Sequence

(2013) Ming Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Diastereoselective Synthesis of N-Acetyl Dihydrotetrafibricin Methyl Ester

(2013) Philippe Nuhant et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

(2013) Scott N. Mlynarski et al.   NATURE

Diborylation of Alkynyl MIDA Boronates and Sequential Chemoselective Suzuki–Miyaura Couplings: A Formal Carboborylation of Alkynes

(2013) Keita Hyodo et al.   ORGANIC LETTERS

Formal Carbon Insertion of N-Tosylhydrazone into B–B and B–Si Bonds: gem-Diborylation and gem-Silylborylation of sp3 Carbon

(2013) Huan Li et al.   ORGANIC LETTERS

Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature

(2012) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic, Direct Synthesis of Bis(boronate) Compounds

(2012) Jun Takaya et al.   ACS Catalysis

Catalytic Enantioselective 1,2-Diboration of 1,3-Dienes: Versatile Reagents for Stereoselective Allylation

(2011) Laura T. Kliman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

A Simple and General Platform for Generating Stereochemically Complex Polyene Frameworks by Iterative Cross-Coupling

(2010) Suk Joong Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboroxines to Borylalkenes: Asymmetric Synthesis of β-Arylalkylboranes

(2010) Keigo Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates

(2010) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature

(2010) Kohei Endo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

(2010) Noriyuki Iwadate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Devising Boron Reagents for Orthogonal Functionalization through Suzuki-Miyaura Cross-Coupling

(2009) Mamoru Tobisu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Controlled Iterative Cross-Coupling: On the Way to the Automation of Organic Synthesis

(2009) Congyang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric 1,4-Dihydroxylation of 1,3-Dienes by Catalytic Enantioselective Diboration

(2009) Heather E. Burks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Utilization of Potassium Vinyltrifluoroborate in the Development of a 1,2-Dianion Equivalent

(2009) Gary A. Molander et al.   ORGANIC LETTERS

Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

(2009) Noriyuki Iwadate et al.   ORGANIC LETTERS

Orthogonal Reactivity in Boryl-Substituted Organotrifluoroborates

(2008) Gary A. Molander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differentially Protected Benzenediboronic Acids:  Divalent Cross-Coupling Modules for the Efficient Synthesis of Boron-Substituted Oligoarenes

(2008) Hiroyoshi Noguchi et al.   ORGANIC LETTERS

Simple, Efficient, and Modular Syntheses of Polyene Natural Products via Iterative Cross-Coupling

(2007) Suk Joong Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY