Base-controlled highly selective synthesis of alkyl 1,2-bis(boronates) or 1,1,2-tris(boronates) from terminal alkynes

Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes

(2016) Kai Yang et al.   GREEN CHEMISTRY

Modular, Catalytic Enantioselective Construction of Quaternary Carbon Stereocenters by Sequential Cross-Coupling Reactions

(2016) Bowman Potter et al.   ORGANIC LETTERS

Diborane-Mediated Deoxygenation of o-Nitrostyrenes To Form Indoles

(2016) Kai Yang et al.   ORGANIC LETTERS

Chemoselective catalytic reduction of conjugated α,β-unsaturated ketones to saturated ketones via a hydroboration/protodeboronation strategy

(2016) Wen Ding et al.   Organic Chemistry Frontiers

Reaction Optimization, Scalability, and Mechanistic Insight on the Catalytic Enantioselective Desymmetrization of 1,1-Diborylalkanes via Suzuki-Miyaura Cross-Coupling

(2015) Ho-Yan Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations–Hydroboration

(2015) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyl-Directed Cross-Coupling: A Scalable Synthesis of Debromohamigeran E and Other Targets of Interest

(2015) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Diastereoselective Synthesis of 1,2-Hydroxyboronates through Cu-Catalyzed Additions of Alkylboronates to Aldehydes

(2015) Matthew V. Joannou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Vinyl Boronates from Aldehydes by a Practical Boron–Wittig Reaction

(2015) John R. Coombs et al.   ORGANIC LETTERS

Palladium(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with Vinyl Bromides and 1,1-Dibromoalkenes

(2014) Huan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of (+)-Discodermolide by Catalytic Stereoselective Borylation Reactions

(2014) Zhiyong Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solvent- and Ligand-free Diboration of Alkynes and Alkenes Catalyzed by Platinum Nanoparticles on Titania

(2014) Francisco Alonso et al.   ChemCatChem

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

(2014) Chunrui Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Access to Elusive α-Boryl Carbanions and Their Alkylation: An Umpolung Construction for Organic Synthesis

(2014) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiomerically Enriched Tris(boronates): Readily Accessible Conjunctive Reagents for Asymmetric Synthesis

(2014) John R. Coombs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyl-Directed Stereoselective Diboration of Alkenes

(2014) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assembly-line synthesis of organic molecules with tailored shapes

(2014) Matthew Burns et al.   NATURE

Silver-Catalyzed Highly Regioselective Formal Hydroboration of Alkynes

(2014) Hiroto Yoshida et al.   ORGANIC LETTERS

A Catalytic Enantioselective Tandem Allylation Strategy for Rapid Terpene Construction: Application to the Synthesis of Pumilaside Aglycon

(2013) Grace E. Ferris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric synthesis from terminal alkenes by cascades of diboration and cross-coupling

(2013) Scott N. Mlynarski et al.   NATURE

Formal Regiocontrolled Hydroboration of Unbiased Internal Alkynes via Borylation/Allylic Alkylation of Terminal Alkynes

(2013) Abraham L. Moure et al.   ORGANIC LETTERS

Remarkable Catalytic Property of Nanoporous Gold on Activation of Diborons for Direct Diboration of Alkynes

(2013) Qiang Chen et al.   ORGANIC LETTERS

Transition-Metal-Free Synthesis of Pinacol Alkylboronates from Tosylhydrazones

(2012) Huan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium Catalyzed Hydroboration of Terminal Alkynes to Z-Vinylboronates

(2012) Chidambaram Gunanathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric total syntheses of xanthatin and 11,13-dihydroxanthatin using a stereocontrolled conjugate allylation to γ-butenolide

(2012) Kenji Matsumoto et al.   TETRAHEDRON

Total synthesis, stereochemical elucidation and biological evaluation of Ac2SGL; a 1,3-methyl branched sulfoglycolipid from Mycobacterium tuberculosis

(2012) Danny Geerdink et al.   Chemical Science

Catalytic, Direct Synthesis of Bis(boronate) Compounds

(2012) Jun Takaya et al.   ACS Catalysis

Catalytic Enantioselective 1,2-Diboration of 1,3-Dienes: Versatile Reagents for Stereoselective Allylation

(2011) Laura T. Kliman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates

(2010) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature

(2010) Kohei Endo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of cis-vinyltrimethylstannanes and cis-vinylpinacolboronates in a two-step highly regio and stereoselective process

(2009) Paul Malek Mirzayans et al.   TETRAHEDRON

Highly Stereoselective Synthesis ofcis-Alkenyl Pinacolboronates and Potassiumcis-Alkenyltrifluoroborates via a Hydroboration/ Protodeboronation Approach

(2008) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY