Recent Advances in [Cp*MIII ] (M = Co, Rh, Ir)-Catalyzed Intramolecular Annulation Through C-H Activation

Increasing Catalyst Efficiency in C−H Activation Catalysis

(2018) Tobias Gensch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Synthesis of Spiropiperidine Derivatives via C–H Activation

(2018) Augustin Peneau et al.   JOURNAL OF ORGANIC CHEMISTRY

Isocanthine Synthesis via Rh(III)-Catalyzed Intramolecular C–H Functionalization

(2017) Anthony Y. Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams

(2017) John H. Conway et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed C–H Activation/Heterocyclization as a Macrocyclization Strategy. Synthesis of Macrocyclic Pyridones

(2017) Jean-Philippe Krieger et al.   ORGANIC LETTERS

Rh(iii)-catalyzed double C–H activation of aldehyde hydrazones: a route for functionalized 1H-indazole synthesis

(2017) Pan Xu et al.   Chemical Science

Mechanistic Investigation into RhIII -Catalyzed Intramolecular Redox-Neutral Annulation of Aryl Hydrazines with a Tethered Alkyne

(2017) Weirong Wu et al.   Asian Journal of Organic Chemistry

Ruthenium-Catalyzed Hydroarylation and One-Pot Twofold Unsymmetrical C−H Functionalization of Arenes

(2016) Koushik Ghosh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A concise gram-scale synthesis of ht-13-A via a rhodium-catalyzed intramolecular C–H activation reaction

(2016) Pengyu Tao et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Cobalt(III)-Catalyzed Intramolecular Cross-Dehydrogenative C−H/X−H Coupling: Efficient Synthesis of Indoles and Benzofurans

(2016) Jayanta Ghorai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Harnessing C−H Activation of Benzhydroxamates as a Macrocyclization Strategy: Synthesis of Structurally Diverse Macrocyclic Isoquinolones

(2016) Jean-Philippe Krieger et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Natural Product-like Polyheterocycles via One-Pot Cascade Oximation, C–H Activation, and Alkyne Annulation

(2016) Liyao Zheng et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-catalyzed C–C coupling reactions via double C–H activation

(2016) Shuai-Shuai Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)-Catalyzed Synthesis of Aryl Spirocycles by Aromatic CH Activation/Intramolecular Heck-Type Reaction

(2015) Laurent Chabaud et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Allylic C(sp3)-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles

(2015) Alexis Archambeau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-catalyzed Intramolecular Ar–H/Ar–H Coupling Directed by Carboxylic Group to Produce Dibenzofuran Carboxylic Acids

(2015) Takeshi Okada et al.   CHEMISTRY LETTERS

Total Synthesis ofcis-Clavicipitic Acid from Asparagine via Ir-Catalyzed CH bond Activation as a Key Step

(2015) Yu-ki Tahara et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Synthesis of Protoberberine Alkaloids by Rh-Catalyzed C−H Bond Activation as the Key Step

(2015) Jayachandran Jayakumar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Sequential Dehydrogenation/Deoxygenation in One-Pot: Efficient Synthesis of Dibenzothiophene Derivatives from Diaryl Sulfoxides

(2015) Qiufeng Huang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Synthesis of N-H Carbazoles via Iridium(III)-Catalyzed Intramolecular C–H Amination

(2015) Chiharu Suzuki et al.   ORGANIC LETTERS

Mechanistic Insights of a Concerted Metalation–Deprotonation Reaction with [Cp*RhCl2]2

(2015) Aaron P. Walsh et al.   ORGANOMETALLICS

Chiral Cyclopentadienyl Ligands Enable a Rhodium(III)-Catalyzed Enantioselective Access to Hydroxychromanes and Phthalides

(2015) Nicolai Cramer et al.   SYNLETT

Rhodium(III)-Catalyzed C–H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylate

(2015) Tomislav Rovis et al.   SYNLETT

Transition-Metal-Catalyzed Direct C–H Functionalization under External-Oxidant-Free Conditions

(2015) Xiuling Cui et al.   SYNTHESIS-STUTTGART

Total synthesis of Sparstolonin B, a potent anti-inflammatory agent

(2015) Yongqiang Wang et al.   RSC Advances

Sulfone promoted Rh(iii)-catalyzed C–H activation and base assisted 1,5-H shift strategy for the construction of seven-membered rings

(2015) Dianpeng Chen et al.   Organic Chemistry Frontiers

Rhodium-catalyzed intramolecular annulation via C–H activation leading to fused tricyclic indole scaffolds

(2014) Pengyu Tao et al.   CHEMICAL COMMUNICATIONS

Rh(iii)-Catalyzed intramolecular redox-neutral cyclization of alkenes via C–H activation

(2014) Zhuangzhi Shi et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed intramolecular amidoarylation and hydroarylation of alkyne via C–H activation: switchable synthesis of 3,4-fused tricyclic indoles and chromans

(2014) Xue Zhang et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed Intramolecular Dehydrogenative Aryl–Aryl Coupling Using Air as Terminal Oxidant

(2014) Hannah Baars et al.   CHEMISTRY LETTERS

Rhodium(III)-Catalyzed Intramolecular Redox-Neutral Annulation of Tethered Alkynes: Formal Total Synthesis of (±)-Goniomitine

(2014) Bing Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Multicyclic Heterocycles Initiated by C-H Bond Activation Along with “Rollover” Using a Rh(III) Catalyst

(2014) Takanori Shibata et al.   HETEROATOM CHEMISTRY

Rh(III)-Catalyzed Intramolecular Redox-Neutral or Oxidative Cyclization of Alkynes: Short, Efficient Synthesis of 3,4-Fused Indole Skeletons

(2014) Bing Zhou et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Selective Coupling of N-Methoxy-1H-indole-1-carboxamides and Aryl Boronic Acids

(2014) Jing Zheng et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Intramolecular Hydroarylation, Amidoarylation, and Heck-type Reaction: Three Distinct Pathways Determined by an Amide Directing Group

(2013) Tyler A. Davis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Cp-Rhodium(III)-Catalyzed Asymmetric Hydroarylations of 1,1-Disubstituted Alkenes

(2013) Baihua Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Phenanthridinones fromN-Methoxybenzamides and Aryltriethoxysilanes through RhIII-Catalyzed CH and NH Bond Activation

(2013) Natarajan Senthilkumar et al.   Chemistry-An Asian Journal

Rhodium- and Iridium-Catalyzed Dehydrogenative Cyclization through Double C–H Bond Cleavages To Produce Fluorene Derivatives

(2013) Masaki Itoh et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of imidazo and benzimidazo[2,1-a]isoquinolines by rhodium-catalyzed intramolecular double C–H bond activation

(2013) Vutukuri Prakash Reddy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(iii)-catalyzed intramolecular annulations involving amide-directed C–H activations: synthetic scope and mechanistic studies

(2013) Noelia Quiñones et al.   Chemical Science

Synthesis of Fluorene Derivatives through Rhodium-Catalyzed Dehydrogenative Cyclization

(2012) Keisuke Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Intramolecular Annulation through CH Activation: Total Synthesis of (±)-Antofine, (±)-Septicine, (±)-Tylophorine, and Rosettacin

(2012) Xianxiu Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Oxidative CH Coupling ofN-Methoxybenzamides with Aryl Boronic Acids: One-Pot Synthesis of Phenanthridinones

(2012) Jaganathan Karthikeyan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(iii)-catalyzed allylic C–H bond amination. Synthesis of cyclic amines from ω-unsaturated N-sulfonylamines

(2012) Thomas Cochet et al.   CHEMICAL COMMUNICATIONS

Rhodium(III)-Catalyzed Cyclization–Olefination of N-Acetoxyl Ketoimine-Alkynes

(2012) Peng Zhao et al.   ORGANIC LETTERS

Rhodium-Catalyzed Xanthone Formation from 2-Aryloxybenzaldehydes via Cross-Dehydrogenative Coupling (CDC)

(2012) Ping Wang et al.   ORGANIC LETTERS

Rh(III)-Catalyzed C–H Bond Activation along with “Rollover” for the Synthesis of 4-Azafluorenes

(2012) Takanori Shibata et al.   ORGANIC LETTERS

Iridium(III) Cp* Complexes for the Efficient Hydroamination of Internal Alkynes

(2012) Katherine Gray et al.   ORGANOMETALLICS

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir(III)-Catalyzed Room-Temperature Synthesis of Multisubstituted Benzofurans Initiated by C-H Activation of α-Aryloxy Ketones

(2011) Takanori Shibata et al.   SYNLETT

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Selective Synthesis of 4-Substituted Benzofurans and IndolesviaDirected Cyclodehydration

(2009) Kyoji Tsuchikama et al.   ADVANCED SYNTHESIS & CATALYSIS

C−H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2(M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism

(2009) Ling Li et al.   ORGANOMETALLICS

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes

(2008) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY