Journal
HETEROATOM CHEMISTRY
Volume 25, Issue 5, Pages 379-388Publisher
WILEY
DOI: 10.1002/hc.21158
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Funding
- MEXT
- JST
- ACT-C
- grants for Excellent Graduate School (Practical Chemical Wisdom), Waseda University, MEXT, Japan
- Grants-in-Aid for Scientific Research [25105748] Funding Source: KAKEN
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Various multicyclic heterocycles were synthesized via rollover as the key pathway using a Rh(III) catalyst with a catalytic amount of sodium pivalate or copper(II) acetate. 3-Alkynyl-2-heteroarylpyridines were transformed into tri- or tetracyclic heterocycles containing two heteroatoms via an intramolecular alkyne insertion. 3-Aryloyl-2-arylpyridines were derived into 4-azafluoren-9-ols via the intramolecular carbonyl insertion.
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