Chiral ligands designed in China

Regio- and Enantioselective Copper-Catalyzed 1,4-Conjugate Addition of Trimethylaluminium to Linear α,β,γ,δ-Unsaturated Alkyl Ketones

(2016) Xiaoting Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Chiral 1,4-Benzodioxanes and Chromans by Enantioselective Palladium-Catalyzed Alkene Aryloxyarylation Reactions

(2016) Naifu Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Asymmetric Allylic Allylation of Racemic Morita-Baylis-Hillman Adducts

(2016) Xubin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A ChiralN,N′-Dioxide-ZnIIComplex Catalyzes the Enantioselective [2+2] Cycloaddition of Alkynones with Cyclic Enol Silyl Ethers

(2016) Tengfei Kang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo- and Enantioselective Copper(I)-Catalyzed Intermolecular [3+2] Cycloaddition of Azomethine Ylides with β-Trifluoromethyl β,β-Disubstituted Enones

(2016) Zhan-Ming Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

P,S Ligands for the Asymmetric Construction of Quaternary Stereocenters in Palladium-Catalyzed Decarboxylative [4+2] Cycloadditions

(2016) Yi Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Desilylation-Activated Propargylic Transformation: Enantioselective Copper-Catalyzed [3+2] Cycloaddition of Propargylic Esters with β-Naphthol or Phenol Derivatives

(2016) Long Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bimetallic Gold(I)/Chiral N ,N′ -Dioxide Nickel(II) Asymmetric Relay Catalysis: Chemo- and Enantioselective Synthesis of Spiroketals and Spiroaminals

(2016) Jun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)/ChiralN,N′-Dioxide-Nickel(II) Relay Catalysis for Asymmetric Tandem Intermolecular Hydroalkoxylation/Claisen Rearrangement

(2016) Jun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds

(2016) Xiaoyu Ren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes

(2016) Jun Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Hydrogenation of α-Substituted Acrylic Acids Catalyzed by a Ruthenocenyl Phosphino-oxazoline–Ruthenium Complex

(2016) Jing Li et al.   ORGANIC LETTERS

Enantioselective Copper-Catalyzed Formal [4 + 2] Cycloaddition of o-Aminophenol Derivatives with Propargylic Esters for Synthesis of Optically Active 3,4-Dihydro-2H-1,4-benzoxazines

(2016) Zhen-Ting Liu et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Hydrogenation of α,β-Unsaturated Carbonyl Compounds via Thiourea Hydrogen Bonding

(2016) Jialin Wen et al.   ORGANIC LETTERS

Strong Brønsted acid promoted asymmetric hydrogenation of isoquinolines and quinolines catalyzed by a Rh–thiourea chiral phosphine complex via anion binding

(2016) Jialin Wen et al.   Chemical Science

Highly enantioselective Pd-catalyzed indole allylic alkylation using binaphthyl-based phosphoramidite-thioether ligands

(2016) Bin Feng et al.   Organic Chemistry Frontiers

Enantioselective gold-catalyzed intermolecular [2 + 2]-cycloadditions of 3-styrylindoles with N-allenyl oxazolidinone

(2016) Haoxiang Hu et al.   Organic Chemistry Frontiers

Asymmetric Hydrogenation of β-Secondary Amino Ketones Catalyzed by a Ruthenocenyl Phosphino-oxazoline-ruthenium Complex (RuPHOX-Ru): the Synthesis of γ-Secondary Amino Alcohols

(2015) Jianxia Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Enantioselective Nickel-Catalyzed Intramolecular Reductive Cyclization of Alkynones

(2015) Wenzhen Fu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Palladium-Catalyzed Dearomative Cyclization for the Efficient Synthesis of Terpenes and Steroids

(2015) Kang Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Enantioselective Dearomatization Reaction of β-Naphthol Usingmeso-Aziridine: A Bifunctional In Situ Generated Magnesium Catalyst

(2015) Dongxu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of a CC Bond-Forming Conjugate Addition Reaction in Asymmetric Dearomatization of β-Naphthols

(2015) Dongxu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Ring-Opening of Cyclopropyl Ketones with Thiol, Alcohol, and Carboxylic Acid Nucleophiles Catalyzed by a ChiralN,N′-Dioxide-Scandium(III) Complex

(2015) Yong Xia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Three-Component Borylstannation: Enantioselective Formation of CSn Bond

(2015) Tao Jia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric H2O-Nucleophilic Ring Opening of D–A Cyclopropanes: Catalyst Serves as a Source of Water

(2015) Qi-Kai Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes

(2015) Tao Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Annulation of Donor–Acceptor Cyclopropanes with Dienes

(2015) Hao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Intramolecular Asymmetric Allylic Dearomatization Reaction of Pyridines, Pyrazines, Quinolines, and Isoquinolines

(2015) Ze-Peng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Enantioselective Alkoxycarbonylative Amination of Terminal Allenes Catalyzed by a Spiroketal-Based Diphosphine/Pd(II) Complex

(2015) Jiawang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Chiral α-Amino Tertiary Boronic Esters by Enantioselective Hydroboration of α-Arylenamides

(2015) Naifu Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Direct Functionalization of Indoles by Pd/Sulfoxide-Phosphine-Catalyzed N-Allylic Alkylation

(2015) Li-Yan Chen et al.   ORGANIC LETTERS

One-Pot Catalytic Asymmetric Synthesis of Tetrahydrocarbazoles

(2015) Qiong-Jie Liu et al.   ORGANIC LETTERS

Facile Development of Chiral Alkenylboranes from Chiral Diynes for Asymmetric Hydrogenation of Silyl Enol Ethers

(2015) Xiaoyu Ren et al.   ORGANIC LETTERS

Enantioselective Metal-Free Hydrogenations of Disubstituted Quinolines

(2015) Zhenhua Zhang et al.   ORGANIC LETTERS

Synthesis of Chiral β-Amino Nitroalkanes via Rhodium-Catalyzed Asymmetric Hydrogenation

(2015) Pan Li et al.   ORGANIC LETTERS

Polymer-Bound Chiral Gold-Based Complexes as Efficient Heterogeneous Catalysts for Enantioselectivity Tunable Cycloaddition

(2015) Mingjin Chen et al.   ACS Catalysis

Simple Open-Chain Phosphite-Olefin as Ligand for Rh-Catalyzed Asymmetric Arylation of Cyclic Ketimines: Enantioselective Access to gem-Diaryl α-Amino Acid Derivatives

(2015) Yi Li et al.   ACS Catalysis

Copper-Catalyzed Asymmetric Formal [3 + 2] Cycloaddition of Propargylic Acetates with Hydrazines: Enantioselective Synthesis of Optically Active 2-Pyrazolines

(2015) De-Yang Zhang et al.   ACS Catalysis

Enantioselective nickel-catalyzed alkylative alkyne–aldehyde cross-couplings

(2015) Ming Nie et al.   Organic Chemistry Frontiers

Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization

(2015) Guangqing Xu et al.   Organic Chemistry Frontiers

Magical Chiral Spiro Ligands

(2015) Jianhua Xie et al.   ACTA CHIMICA SINICA

Side Arm Strategy for Catalyst Design: Modifying Bisoxazolines for Remote Control of Enantioselection and Related

(2014) Saihu Liao et al.   ACCOUNTS OF CHEMICAL RESEARCH

SpinPhox/Iridium(I)-Catalyzed Asymmetric Hydrogenation of Cyclic α-Alkylidene Carbonyl Compounds

(2014) Xu Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Arylation of β,γ-Unsaturated α-Ketoamides for the Construction of Nonracemic γ,γ-Diarylcarbonyl Compounds

(2014) Juanjuan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereo- and Enantioselective Palladium-Catalyzed [3+2] Cycloaddition of Vinyl Aziridines and α,β-Unsaturated Ketones

(2014) Chao-Fan Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel(II)-Catalyzed Asymmetric Propargyl and Allyl Claisen Rearrangements to Allenyl- and Allyl-Substituted β-Ketoesters

(2014) Yangbin Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of 2,3-Dihydropyrroles by Ring-Opening/Cyclization of Cyclopropyl Ketones Using Primary Amines

(2014) Yong Xia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Hydrogenation of Unprotected NH Imines Assisted by a Thiourea

(2014) Qingyang Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions

(2014) Zhan-Ming Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Highly Functionalized Dihydrofurans through Copper-Catalyzed Asymmetric Formal [3+2] Cycloaddition of β-Ketoesters with Propargylic Esters

(2014) Fu-Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rational design of sulfoxide–phosphine ligands for Pd-catalyzed enantioselective allylic alkylation reactions

(2014) Hong-Gang Cheng et al.   CHEMICAL COMMUNICATIONS

Palladium/sulfoxide–phosphine-catalyzed highly enantioselective allylic etherification and amination

(2014) Bin Feng et al.   CHEMICAL COMMUNICATIONS

Highly diastereo- and enantioselective copper-catalyzed propargylic alkylation of acyclic ketone enamines for the construction of two vicinal stereocenters

(2014) De-Yang Zhang et al.   CHEMICAL COMMUNICATIONS

Catalytic Asymmetric 1,3-Dipolar [3 + 6] Cycloaddition of Azomethine Ylides with 2-Acyl Cycloheptatrienes: Efficient Construction of Bridged Heterocycles Bearing Piperidine Moiety

(2014) Qing-Hua Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Aminocyanation of Alkenes by Cooperative Palladium/Boron Catalysis

(2014) Yosuke Miyazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Enantioselective Hydrogenation of Silyl Enol Ethers Catalyzed by Chiral Frustrated Lewis Pairs

(2014) Simin Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Ester Group Leads to Efficient Kinetic Resolution of Racemic Aliphatic Alcohols via Asymmetric Hydrogenation

(2014) Xiao-Hui Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Highly Enantioselective Arylation of Cyclic Diketimines: Efficient Synthesis of Chiral Tetrasubstituted 1,2,5-Thiadiazoline 1,1-Dioxides

(2014) Hui Wang et al.   ORGANIC LETTERS

Asymmetric hydrogenation of α-arylacrylic and β-arylbut-3-enoic acids catalyzed by a Rh(i) complex of a monodentate secondary phosphine oxide ligand

(2014) Kaiwu Dong et al.   Organic Chemistry Frontiers

Design of a new series of chiral phosphite–olefin ligands and their application in asymmetric catalysis

(2014) Yue-Na Yu et al.   Organic Chemistry Frontiers

Chiral N,N′-dioxide ligands: synthesis, coordination chemistry and asymmetric catalysis

(2014) Xiaohua Liu et al.   Organic Chemistry Frontiers

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Trifluoromethyl Ketones

(2013) Renshi Luo et al.   ADVANCED SYNTHESIS & CATALYSIS

Design of Phosphorus Ligands with Deep Chiral Pockets: Practical Synthesis of Chiral β-Arylamines by Asymmetric Hydrogenation

(2013) Guodu Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Asymmetric Hydrogenation of α-Alkylidene Succinimides

(2013) Yuanyuan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with Donor-Acceptor Cyclopropanes: Accessing3a-Hydroxy [n.3.0]Carbobicycles

(2013) Hao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fulvenes as Effective Dipolarophiles in Copper(I)-Catalyzed [6+3] Cycloaddition of Azomethine Ylides: Asymmetric Construction of Piperidine Derivatives

(2013) Zhao-Lin He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen-Bond-Promoted Palladium Catalysis: Allylic Alkylation of Indoles with Unsymmetrical 1,3-Disubstituted Allyl Acetates Using Chiral Bis(sulfoxide) Phosphine Ligands

(2013) Le Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Scandium(III)-Catalyzed Enantioselective α-Arylation of N-Unprotected 3-Substituted Oxindoles with Diaryliodonium Salts

(2013) Jing Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions

(2013) Guangqing Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Efficient and Enantioselective Intramolecular Cannizzaro Reaction under TOX/Cu(II) Catalysis

(2013) Pan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Highly Enantioselective Cyclopentannulation of Indoles with Donor–Acceptor Cyclopropanes

(2013) Hu Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Dienes as “Ligands” for Borane-Catalyzed Metal-Free Asymmetric Hydrogenation of Imines

(2013) Yongbing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita–Baylis–Hillman Adducts: Exceptionally High Efficiency and New Mechanism

(2013) Xiaoming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Branched Sulfur–Olefins as Chiral Ligands for Rh-Catalyzed Asymmetric Arylation of Cyclic Ketimines: Highly Enantioselective Construction of Tetrasubstituted Carbon Stereocenters

(2013) Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Stereoselective Olefin Cyclopropanation of Diazooxindoles Catalyzed by a C2-Symmetric Spiroketal Bisphosphine/Au(I) Complex

(2013) Zhong-Yan Cao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed B–H Bond Insertion Reaction: A Highly Efficient and Enantioselective C–B Bond-Forming Reaction with Amine–Borane and Phosphine–Borane Adducts

(2013) Qing-Qing Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Novel Chiral Bisphosphine-Thiourea Ligand for Asymmetric Hydrogenation of β,β-Disubstituted Nitroalkenes

(2013) Qingyang Zhao et al.   ORGANIC LETTERS

Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds

(2013) Fu-Zhong Han et al.   ORGANIC LETTERS

Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles

(2012) Cheng Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Aromatic Spiroketal Bisphosphine Ligands: Palladium-Catalyzed Asymmetric Allylic Amination of Racemic Morita-Baylis-Hillman Adducts

(2012) Xiaoming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Hydrogenation of α-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands

(2012) Shou-Fei Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereo- and Enantioselective Cyclopropanation of 1,2-Disubstituted Alkenes

(2012) Jun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective [3+3] Cycloaddition of Aromatic Azomethine Imines with Cyclopropanes Directed by π-π Stacking Interactions

(2012) You-Yun Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective asymmetric hydrogenation of (E)-β,β-disubstituted α,β-unsaturated Weinreb amides catalyzed by Ir(i) complexes of SpinPhox ligands

(2012) Jian Shang et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Enantioselective Addition to Unsymmetrical α-Diketones: Tandem One-Pot Synthesis of Optically Active 3-Tetrasubstituted Isochroman Derivatives

(2012) Ting-Shun Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

CuII-Catalyzed Asymmetric Hydrosilylation of Diaryl- and Aryl Heteroaryl Ketones: Application in the Enantioselective Synthesis of Orphenadrine and Neobenodine

(2012) Yao-Zong Sui et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Construction of Spiro(γ-butyrolactam-γ-butyrolactone) Moieties through Sequential Reactions of Cyclic Imino Esters with Morita-Baylis-Hillman Bromides

(2012) Huai-Long Teng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regio- and Enantioselective Palladium-Catalyzed Allylic Alkylation of Nitromethane with Monosubstituted Allyl Substrates: Synthesis of (R)-Rolipram and (R)-Baclofen

(2012) Xiao-Fei Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands: Scope and Mechanistic Studies

(2012) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(I)-Catalyzed Enantioselective Hydrogenation of α-Substituted Ethenylphosphonic Acids

(2012) Kaiwu Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereo- and Enantioselective Cu-Catalyzed [3 + 3] Cycloaddition of Propargyl Esters with Cyclic Enamines toward Chiral Bicyclo[n.3.1] Frameworks

(2012) Cheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor–Acceptor Cyclopropanes with Amines

(2012) You-Yun Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalyzed enantioselective 1,2-addition of arylboronic acids to heteroaryl α-ketoesters for synthesis of heteroaromatic α-hydroxy esters

(2012) Hui Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki–Miyaura Coupling Reactions

(2012) Wenjun Tang et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Formal Cycloadditions of Racemic Butadiene Monoxide with Imines

(2012) Zhaoqun Liu et al.   ORGANIC LETTERS

Efficient Ru(II)-catalyzed asymmetric hydrogenation of simple ketones with C2-symmetric planar chiral metallocenyl phosphinooxazoline ligands

(2012) Hui Guo et al.   TETRAHEDRON

ChiralN,N′-Dioxides: New Ligands and Organocatalysts for Catalytic Asymmetric Reactions

(2011) XiaoHua Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Hydrogenation of α- and β-Enamido Phosphonates: Rhodium(I)/Monodentate Phosphoramidite Catalyst

(2011) Jinzhu Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Additional Coordination Group Leads to Extremely Efficient Chiral Iridium Catalysts for Asymmetric Hydrogenation of Ketones

(2011) Jian-Hua Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed, Highly Enantioselective 1,2-Addition of Aryl Boronic Acids to α-Ketoesters and α-Diketones Using Simple, Chiral Sulfur-Olefin Ligands

(2011) Ting-Shun Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Sulfoxide-Olefin Ligands: Completely Switchable Stereoselectivity in Rhodium-Catalyzed Asymmetric Conjugate Additions

(2011) Guihua Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design of N-sulfinyl homoallylic amines as novel sulfinamide-olefin hybrid ligands for asymmetric catalysis: application in Rh-catalyzed enantioselective 1,4-additions

(2011) Shen-Shuang Jin et al.   CHEMICAL COMMUNICATIONS

Pd-Catalyzed Asymmetric Allylic Etherizations with Oximes by Chiral Alkene-Phosphine Ligands

(2011) Ziping Cao et al.   JOURNAL OF ORGANIC CHEMISTRY

A Class of Benzene Backbone-Based Olefin–Sulfoxide Ligands for Rh-Catalyzed Enantioselective Addition of Arylboronic Acids to Enones

(2011) Feng Xue et al.   JOURNAL OF ORGANIC CHEMISTRY

A Facile Cu(I)/TF-BiphamPhos-Catalyzed Asymmetric Approach to Unnatural α-Amino Acid Derivatives Containinggem-Bisphosphonates

(2011) Zhi-Yong Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Arylation ofN-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes

(2011) Zhe Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly effective chiral phosphorus amidite–olefin ligands for palladium-catalyzed asymmetric allylic substitutions

(2011) Zhaoqun Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Design of N-cinnamyl sulfinamides as new sulfur-containing olefin ligands for asymmetric catalysis: achieving structural simplicity with a categorical linear framework

(2011) Shen-Shuang Jin et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of β-Amino Acid Derivatives via Copper-Catalyzed Asymmetric 1,4-Reduction of β-(Acylamino)acrylates

(2011) Yan Wu et al.   ORGANIC LETTERS

SimpleN-Sulfinyl-Based Chiral Sulfur–Olefin Ligands for Rhodium-Catalyzed Asymmetric 1,4-Additions

(2011) Xiangqing Feng et al.   ORGANIC LETTERS

Design of Chiral Sulfoxide–Olefins as a New Class of Sulfur-Based Olefin Ligands for Asymmetric Catalysis

(2011) Wei-Yi Qi et al.   ORGANIC LETTERS

Pd-Catalyzed Asymmetric Allylic Alkylation of Indoles and Pyrroles by Chiral Alkene-Phosphine Ligands

(2011) Ziping Cao et al.   ORGANIC LETTERS

Spiro-2,2′-bichroman-based bisoxazoline (SPANbox) ligands for ZnII-catalyzed enantioselective hydroxylation of β-keto esters and 1,3-diester

(2011) Jie Li et al.   Chemical Science

Asymmetric dearomatization of pyrrolesviaIr-catalyzed allylic substitution reaction: enantioselective synthesis of spiro-2H-pyrroles

(2011) Chun-Xiang Zhuo et al.   Chemical Science

tert-Butanesulfinylphosphines: Simple Chiral Ligands in Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Electron-Deficient Olefins

(2010) Feng Lang et al.   ADVANCED SYNTHESIS & CATALYSIS

Iridium-Catalyzed Highly Enantioselective Hydrogenation of Exocyclic α,β-Unsaturated Carbonyl Compounds

(2010) Fengtao Tian et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Asymmetric Mannich Reaction of Glycine Derivatives with N-Tosylimines using Copper(I)/TF-BiphamPhos Complex

(2010) Gang Liang et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Enantioselective Hydrogenation of Quinoline and Pyridine Derivatives with Iridium-(P-Phos) Catalyst

(2010) Wei-Jun Tang et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Asymmetric Bromoamination of Chalcones: Highly Efficient Synthesis of Chiral α-Bromo-β-Amino Ketone Derivatives

(2010) Yunfei Cai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes Using Chiral Bicyclo[3.3.0] Diene Ligands

(2010) Zhi-Qian Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric 1,4-Addition of Arylboronic Acids to 2,3-Dihydro-4-pyridones Catalyzed by Axially Chiral NHC−Pd(II) Complexes

(2010) Qin Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective Hydrogenation of α-Arylmethylene Cycloalkanones Catalyzed by Iridium Complexes of Chiral Spiro Aminophosphine Ligands

(2010) Jian-Bo Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Nickel-Catalyzed Reductive Coupling of Alkynes and Imines

(2010) Chang-Yue Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates

(2010) Jian-Ping Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AC2-Symmetric Chiral Bis-Sulfoxide Ligand in a Rhodium-Catalyzed Reaction: Asymmetric 1,4-Addition of Sodium Tetraarylborates to Chromenones

(2010) Jun Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Roskamp Reaction of α-Alkyl-α-diazoesters with Aromatic Aldehydes: Highly Enantioselective Synthesis of α-Alkyl-β-keto Esters

(2010) Wei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective iron-catalysed O–H bond insertions

(2010) Shou-Fei Zhu et al.   Nature Chemistry

Efficient palladium-catalyzed asymmetric allylic alkylation of ketones and aldehydes

(2010) Xiaohu Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Development of Binaphthyl-Based Chiral Dienes for Rhodium(I)-Catalyzed Asymmetric Arylation ofN,N-Dimethylsulfamoyl-Protected Aldimines

(2010) Ziping Cao et al.   ORGANIC LETTERS

Chiral Diene as the Ligand for the Synthesis of Axially Chiral Compounds via Palladium-Catalyzed Suzuki−Miyaura Coupling Reaction

(2010) Shu-Sheng Zhang et al.   ORGANIC LETTERS

C1-Symmetric Dicyclopentadienes as New Chiral Diene Ligands for Asymmetric Rhodium-Catalyzed Arylation ofN-Tosylarylimines

(2010) Cheng Shao et al.   ORGANIC LETTERS

Vicinal-Diamine-Based Chiral Chain Dienes as Ligands for Rhodium(I)-Catalyzed Highly Enantioselective Conjugated Additions

(2010) Yazhou Wang et al.   ORGANIC LETTERS

Development of Chiral Terminal-Alkene−Phosphine Hybrid Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions

(2010) Zhaoqun Liu et al.   ORGANIC LETTERS

Catalytic Enantioselective Addition of Cyclic β-Keto Esters with Activated Olefins and N-Boc Imines Using ChiralC2-Symmetric Cationic Pd2+N-Heterocyclic Carbene (NHC) Diaqua Complexes

(2010) Zhen Liu et al.   ORGANOMETALLICS

From C2- to D2-symmetry: atropos phosphoramidites with a D2-symmetric backbone as highly efficient ligands in Cu-catalyzed conjugate additions

(2010) Hui Zhang et al.   TETRAHEDRON LETTERS

Effective Chiral Ferrocenyl Phosphine-Thioether Ligands in Enantioselective Palladium-Catalyzed Allylic Alkylations

(2009) Hong Yee Cheung et al.   ADVANCED SYNTHESIS & CATALYSIS

Spiro[4,4]-1,6-nonadiene-Based Phosphine-Oxazoline Ligands for Iridium-Catalyzed Enantioselective Hydrogenation of Ketimines

(2009) Zhaobin Han et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly enantioselective hydrogenation of α-aryl-β-substituted acrylic acids catalyzed by Ir-SpinPHOX

(2009) Yi Zhang et al.   CHEMICAL COMMUNICATIONS

Recent Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis

(2009) Gráinne C. Hargaden et al.   CHEMICAL REVIEWS

Application of Copper(II)-Dipyridylphosphine Catalyst in the Asymmetric Hydrosilylation of Simple Ketones in Air

(2009) Xi-Chang Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetic Resolution of 2,3-Dihydro-2-substituted 4-Quinolones by Palladium-Catalyzed Asymmetric Allylic Alkylation

(2009) Bai-Lin Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereo- and Enantioselective Pd-Catalyzed Cyclopropanation of Acyclic Amides with Substituted Allyl Carbonates

(2009) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphine-oxazoline ligands with an axial-unfixed biphenyl backbone: the effects of the substituent at oxazoline ring and P phenyl ring on Pd-catalyzed asymmetric allylic alkylation

(2009) Fengtao Tian et al.   TETRAHEDRON

Chiral Diphosphine and Monodentate Phosphorus Ligands on a Spiro Scaffold for Transition-Metal-Catalyzed Asymmetric Reactions

(2008) Jian-Hua Xie et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium–(S,pR)-FerroNPS-Catalyzed Asymmetric Allylic Etherification: Electronic Effect of Nonconjugated Substituents on Benzylic Alcohols on Enantioselectivity

(2008) Fuk Loi Lam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Palladium-Catalyzed Alkylation of Acyclic Amides

(2008) Kai Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Highly Enantioselective Carbenoid Insertion into SiH Bonds

(2008) Yong-Zhen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Bidentate Bis(N-Heterocyclic Carbene)-Based Palladium Complexes Bearing Carboxylate Ligands: Highly Effective Catalysts for the Enantioselective Conjugate Addition of Arylboronic Acids to Cyclic Enones

(2008) Tao Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spiro Skeletons: A Class of Privileged Structure for Chiral Ligand Design

(2008) Kuiling Ding et al.   Chemistry-An Asian Journal

Nickel-Catalyzed Enantioselective Alkylative Coupling of Alkynes and Aldehydes: Synthesis of Chiral Allylic Alcohols with Tetrasubstituted Olefins

(2008) Yun Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides Catalyzed by Copper(I)/TF-BiphamPhos Complexes

(2008) Chun-Jiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Axial 4,4′,6,6′-Tetrakis-trifluoromethyl-biphenyl-2,2′-diamine (TF-BIPHAM): Resolution and Applications in Asymmetric Hydrogenation

(2008) Chun-Jiang Wang et al.   ORGANIC LETTERS