Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 355, Issue 7, Pages 1297-1302Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201201125
Keywords
arylboronic acids; chiral phosphorus ligands; nucleophilic addition; rhodium; trifluoromethyl ketones
Categories
Funding
- State Key Laboratory of Bioorganic and Natural Products Chemistry
Ask authors/readers for more resources
A new C2-symmetrical, chiral bisphosphorus ligand proved to be efficient for the rhodium-catalyzed nucleophilic addition of arylboronic acids to trifluoromethyl ketones, providing a series of chiral trifluoromethyl-substituted tertiary alcohols in high yields (up to 93%) and excellent enantioselectivities (>99%).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
