Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations

Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants

(2017) Subhasree Kal et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Non-Heme Imine-Based Iron Complexes as Catalysts for Oxidative Processes

(2016) Giorgio Olivo et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Enantioselective Iron-Catalyzed cis -Dihydroxylation of Alkenes with Hydrogen Peroxide Oxidant via an FeIII -OOH Reactive Intermediate

(2016) Chao Zang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exceedingly Fast Oxygen Atom Transfer to Olefins via a Catalytically Competent Nonheme Iron Species

(2016) Joan Serrano-Plana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Readily Accessible Bulky Iron Catalysts exhibiting Site Selectivity in the Oxidation of Steroidal Substrates

(2016) David Font et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ferrous iron and α-ketoglutarate-dependent dioxygenases in the biosynthesis of microbial natural products

(2016) Long-Fei Wu et al.   BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS

From DNA to catalysis: a thymine-acetate ligated non-heme iron(iii) catalyst for oxidative activation of aliphatic C–H bonds

(2016) Afnan Al-hunaiti et al.   CHEMICAL COMMUNICATIONS

Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes

(2016) Giorgio Olivo et al.   Chemistry-An Asian Journal

Catalytic strategies of the non-heme iron dependent oxygenases and their roles in plant biology

(2016) Mark D White et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

Conflicting Role of Water in the Activation of H2O2 and the Formation and Reactivity of Non-Heme FeIII–OOH and FeIII–O–FeIII Complexes at Room Temperature

(2016) Sandeep K. Padamati et al.   INORGANIC CHEMISTRY

Iron Catalyzed Highly Enantioselective Epoxidation of Cyclic Aliphatic Enones with Aqueous H2O2

(2016) Olaf Cussó et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mononuclear Nonheme High-Spin Iron(III)-Acylperoxo Complexes in Olefin Epoxidation and Alkane Hydroxylation Reactions

(2016) Bin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Dioxygen by Iron and Manganese Complexes: A Heme and Nonheme Perspective

(2016) Sumit Sahu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative diversification of amino acids and peptides by small-molecule iron catalysis

(2016) Thomas J. Osberger et al.   NATURE

Aerobic alcohol oxidation and oxygen atom transfer reactions catalyzed by a nonheme iron(ii)–α-keto acid complex

(2016) Debobrata Sheet et al.   Chemical Science

Dramatic Effect of Carboxylic Acid on the Electronic Structure of the Active Species in Fe(PDP)-Catalyzed Asymmetric Epoxidation

(2016) Alexandra M. Zima et al.   ACS Catalysis

Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

(2016) Alois Fürstner   ACS Central Science

Synthetic Mononuclear Nonheme Iron–Oxygen Intermediates

(2015) Wonwoo Nam   ACCOUNTS OF CHEMICAL RESEARCH

Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes

(2015) Mayank Puri et al.   ACCOUNTS OF CHEMICAL RESEARCH

Bioinspired Nonheme Iron Catalysts for C–H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants

(2015) Williamson N. Oloo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Olefincis-Dihydroxylation and Aliphatic CH Bond Oxygenation by a Dioxygen-Derived Electrophilic Iron-Oxygen Oxidant

(2015) Sayanti Chatterjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Photooxygenation of Alkyl Benzenes Catalyzed by Riboflavin Tetraacetate and a Non-Heme Iron Catalyst

(2015) Bernd Mühldorf et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Interplay of a Non-Heme Iron Catalyst and Amino Acid Coligands in H2O2Activation for Asymmetric Epoxidation of α-Alkyl-Substituted Styrenes

(2015) Olaf Cussó et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rate-Determining Attack on Substrate Precedes Rieske Cluster Oxidation during Cis-Dihydroxylation by Benzoate Dioxygenase

(2015) Brent S. Rivard et al.   BIOCHEMISTRY

Molecular iron complexes as catalysts for selective C–H bond oxygenation reactions

(2015) A. C. Lindhorst et al.   CHEMICAL COMMUNICATIONS

Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives

(2015) Olaf Cussó et al.   CHEMICAL COMMUNICATIONS

Computational Insight into the Mechanism of Alkane Hydroxylation by Non-heme Fe(PyTACN) Iron Complexes. Effects of the Substrate and Solvent

(2015) Verònica Postils et al.   INORGANIC CHEMISTRY

C–H Bond Cleavage by Bioinspired Nonheme Oxoiron(IV) Complexes, Including Hydroxylation of n-Butane

(2015) Scott T. Kleespies et al.   INORGANIC CHEMISTRY

C–H Bond Oxidation Catalyzed by an Imine-Based Iron Complex: A Mechanistic Insight

(2015) Giorgio Olivo et al.   INORGANIC CHEMISTRY

Catalytic Mechanisms of Fe(II)- and 2-Oxoglutarate-dependent Oxygenases

(2015) Salette Martinez et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Determination of Spin Inversion Probability, H-Tunneling Correction, and Regioselectivity in the Two-State Reactivity of Nonheme Iron(IV)-Oxo Complexes

(2015) Yoon Hye Kwon et al.   Journal of Physical Chemistry Letters

Green and Efficient: Iron-Catalyzed Selective Oxidation of Olefins to Carbonyls with O2

(2015) Angela Gonzalez-de-Castro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modeling TauD-J: A High-Spin Nonheme Oxoiron(IV) Complex with High Reactivity toward C–H Bonds

(2015) Achintesh N. Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Oxidation of Aliphatic C–H Bonds in Nitrogen-Containing Molecules

(2015) Jennifer M. Howell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C—H Bonds with Stereoretention

(2015) Joan Serrano-Plana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

EPR Spectroscopic Detection of the Elusive FeV═O Intermediates in Selective Catalytic Oxofunctionalizations of Hydrocarbons Mediated by Biomimetic Ferric Complexes

(2015) Oleg Y. Lyakin et al.   ACS Catalysis

Highly Selective but Multifunctional Oxygenases in Secondary Metabolism

(2014) Rachel V. K. Cochrane et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes

(2014) Wonwoo Nam et al.   ACCOUNTS OF CHEMICAL RESEARCH

Biomimetic Iron-Catalyzed Asymmetric Epoxidations: Fundamental Concepts, Challenges and Opportunities

(2014) Feyissa Gadissa Gelalcha   ADVANCED SYNTHESIS & CATALYSIS

The Iron(II) Complex [Fe(CF3SO3)2(mcp)] as a Convenient, Readily Available Catalyst for the Selective Oxidation of Methylenic Sites in Alkanes

(2014) Mercè Canta et al.   ADVANCED SYNTHESIS & CATALYSIS

Practical Iron-Catalyzed Hydrogen Peroxide Epoxidation of Aromatic Olefins using a Combination of Two Kinds of Simple Picolinate Ligands under Halide-Free Reaction Conditions

(2014) Takefumi Chishiro et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Organocatalytic Epoxidations: Reactions, Scope, Mechanisms, and Applications

(2014) Rebecca L. Davis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A chameleon catalyst for nonheme iron-promoted olefin oxidation

(2014) Shyam R. Iyer et al.   CHEMICAL COMMUNICATIONS

Organocatalytic Asymmetric Epoxidation and Aziridination of Olefins and Their Synthetic Applications

(2014) Yingguang Zhu et al.   CHEMICAL REVIEWS

Active sites and mechanisms of bioinspired oxidation with H2O2, catalyzed by non-heme Fe and related Mn complexes

(2014) Konstantin P. Bryliakov et al.   COORDINATION CHEMISTRY REVIEWS

Triggering the Generation of an Iron(IV)-Oxo Compound and Its Reactivity toward Sulfides by RuII Photocatalysis

(2014) Anna Company et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrogenative α-Oxygenation of Ethers with an Iron Catalyst

(2014) Angela Gonzalez-de-Castro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Status of Reactive Non-Heme Metal–Oxygen Intermediates in Chemical and Enzymatic Reactions

(2014) Kallol Ray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C–H Bonds

(2014) Munmun Ghosh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrocarbon oxidation catalyzed by a cheap nonheme imine-based iron(ii) complex

(2014) Giorgio Olivo et al.   Catalysis Science & Technology

Fe(PyTACN)-Catalyzedcis-Dihydroxylation of Olefins with Hydrogen Peroxide

(2013) Irene Prat et al.   ADVANCED SYNTHESIS & CATALYSIS

Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins

(2013) Xiaoe Wang et al.   ChemCatChem

H2O2activation with biomimetic non-haem iron complexes and AcOH: connecting the g = 2.7 EPR signal with a visible chromophore

(2013) Olga V. Makhlynets et al.   CHEMICAL COMMUNICATIONS

Evidence that steric factors modulate reactivity of tautomeric iron–oxo species in stereospecific alkane C–H hydroxylation

(2013) Mainak Mitra et al.   CHEMICAL COMMUNICATIONS

The Mechanism of Stereospecific CH Oxidation by Fe(Pytacn) Complexes: Bioinspired Non-Heme Iron Catalysts Containingcis-Labile Exchangeable Sites

(2013) Irene Prat et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fe-Catalyzed One-Pot Oxidative Cleavage of Unsaturated Fatty Acids into Aldehydes with Hydrogen Peroxide and Sodium Periodate

(2013) Peter Spannring et al.   CHEMISTRY-A EUROPEAN JOURNAL

Assessing the Impact of Electronic and Steric Tuning of the Ligand in the Spin State and Catalytic Oxidation Ability of the FeII(Pytacn) Family of Complexes

(2013) Irene Prat et al.   INORGANIC CHEMISTRY

Substituent Effects on the Catalytic Activity of Bipyrrolidine-Based Iron Complexes

(2013) Giorgio Olivo et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselective Oxidation of Nonactivated Alkyl C–H Groups Using Highly Structured Non-Heme Iron Catalysts

(2013) Laura Gómez et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-heme Iron Catalysts

(2013) Olaf Cussó et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rate-Determining Water-Assisted O–O Bond Cleavage of an FeIII-OOH Intermediate in a Bio-inspired Nonheme Iron-Catalyzed Oxidation

(2013) Williamson N. Oloo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled Aliphatic C–H Oxidations with a Predictive Model for Site-Selectivity

(2013) Paul E. Gormisky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclohexene as a substrate probe for the nature of the high-valent iron-oxo oxidant in Fe(TPA)-catalyzed oxidations

(2013) Williamson N. Oloo et al.   NEW JOURNAL OF CHEMISTRY

Highly Stereoselective Epoxidation with H2O2 Catalyzed by Electron-Rich Aminopyridine Manganese Catalysts

(2013) Olaf Cussó et al.   ORGANIC LETTERS

Mechanism and Catalytic Diversity of Rieske Non-Heme Iron-Dependent Oxygenases

(2013) Sarah M. Barry et al.   ACS Catalysis

Nonheme Iron Oxidant Formed in the Presence of H2O2 and Acetic Acid Is the Cyclic Ferric Peracetate Complex, Not a Perferryloxo Complex

(2013) Yong Wang et al.   ACS Catalysis

An Iron(III)-Monoamidate Complex Catalyst for Selective Hydroxylation of Alkane CH Bonds with Hydrogen Peroxide

(2012) Yutaka Hitomi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

EPR detection of Fe(V)=O active species in nonheme iron-catalyzed oxidations

(2012) Oleg Y. Lyakin et al.   CATALYSIS COMMUNICATIONS

Highly Enantioselective Epoxidation of Multisubstituted Enones Catalyzed by Non-Heme Iron Catalysts

(2012) Bin Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Iron Catalyst for Oxidation of Alkyl CH Bonds Showing Enhanced Selectivity for Methylenic Sites

(2012) Irene Prat et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemo- and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

(2012) Evgenii P. Talsi et al.   COORDINATION CHEMISTRY REVIEWS

High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

(2012) Aidan R. McDonald et al.   COORDINATION CHEMISTRY REVIEWS

Directed Metal (Oxo) Aliphatic C–H Hydroxylations: Overriding Substrate Bias

(2012) Marinus A. Bigi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evidence for an Alternative to the Oxygen Rebound Mechanism in C–H Bond Activation by Non-Heme FeIVO Complexes

(2012) Kyung-Bin Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of unsaturated steroid ketones with hydrogen peroxide catalyzed by Fe(bpmen)(OTf)2. New methodology to access biologically active steroids by chemo-, and stereoselective processes

(2012) David Clemente-Tejeda et al.   TETRAHEDRON

Nonheme oxoiron(iv) complexes of pentadentate N5 ligands: spectroscopy, electrochemistry, and oxidative reactivity

(2012) Dong Wang et al.   Chemical Science

Asymmetric Epoxidations with H2O2 on Fe and Mn Aminopyridine Catalysts: Probing the Nature of Active Species by Combined Electron Paramagnetic Resonance and Enantioselectivity Study

(2012) Oleg Y. Lyakin et al.   ACS Catalysis

Chiral Bioinspired Non-Heme Iron Complexes for Enantioselective Epoxidation of α,β-Unsaturated Ketones

(2011) Mei Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidative Decarboxylation of Benzilic Acid by a Biomimetic Iron(II) Complex: Evidence for an Iron(IV)-Oxo-Hydroxo Oxidant from O2

(2011) Sayantan Paria et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Biomimetic Iron Catalyst for the Epoxidation of Olefins with Molecular Oxygen at Room Temperature

(2011) Kristin Schröder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A new efficient ironcatalyst for olefinepoxidation with hydrogen peroxide

(2011) Elena A. Mikhalyova et al.   CHEMICAL COMMUNICATIONS

Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts

(2011) Chi-Ming Che et al.   CHEMICAL SOCIETY REVIEWS

Modeling the cis-Oxo-Labile Binding Site Motif of Non-Heme Iron Oxygenases: Water Exchange and Oxidation Reactivity of a Non-Heme Iron(IV)-Oxo Compound Bearing a Tripodal Tetradentate Ligand

(2011) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective C–H oxidation catalyzed by metalloporphyrins

(2011) Miquel Costas   COORDINATION CHEMISTRY REVIEWS

EPR,1H and2H NMR, and Reactivity Studies of the Iron–Oxygen Intermediates in Bioinspired Catalyst Systems

(2011) Oleg Y. Lyakin et al.   INORGANIC CHEMISTRY

Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

(2011) Irene Prat et al.   Nature Chemistry

Regio- and stereoselectivity of P450-catalysed hydroxylation of steroids controlled by laboratory evolution

(2011) Sabrina Kille et al.   Nature Chemistry

A mononuclear nonheme iron(iv)-oxo complex which is more reactive than cytochrome P450 model compound I

(2011) Mi Sook Seo et al.   Chemical Science

Iron-Catalyzed Epoxidation of Aromatic Olefins and 1,3-Dienes

(2010) Kristin Schröder et al.   ADVANCED SYNTHESIS & CATALYSIS

Design of a bio-inspired imidazole-based iron catalyst for epoxidation of olefins: Mechanistic insights

(2010) Kristin Schröder et al.   CATALYSIS TODAY

Osmium-free direct syn-dihydroxylation of alkenes

(2010) Carole J. R. Bataille et al.   CHEMICAL SOCIETY REVIEWS

Formamidines - Versatile Ligands for Zinc-Catalyzed Hydrosilylation and Iron-Catalyzed Epoxidation Reactions

(2010) Stephan Enthaler et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

OlefinCis-Dihydroxylation with Bio-Inspired Iron Catalysts. Evidence for an FeII/FeIVCatalytic Cycle

(2010) Paul D. Oldenburg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

cis-Dihydroxylation of Alkenes with Oxone Catalyzed by Iron Complexes of a Macrocyclic Tetraaza Ligand and Reaction Mechanism by ESI-MS Spectrometry and DFT Calculations

(2010) Toby Wai-Shan Chow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE

Stereospecific CH Oxidation with H2O2Catalyzed by a Chemically Robust Site-Isolated Iron Catalyst

(2009) Laura Gómez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electro-Fenton Process and Related Electrochemical Technologies Based on Fenton’s Reaction Chemistry

(2009) Enric Brillas et al.   CHEMICAL REVIEWS

P450 Enzymes: Their Structure, Reactivity, and Selectivity—Modeled by QM/MM Calculations

(2009) Sason Shaik et al.   CHEMICAL REVIEWS

Design of and Mechanistic Studies on a Biomimetic Iron-Imidazole Catalyst System for Epoxidation of Olefins with Hydrogen Peroxide

(2009) Kristin Schröder et al.   CHEMISTRY-A EUROPEAN JOURNAL

Olefin-Dependent Discrimination between Two Nonheme HOFeVO Tautomeric Species in Catalytic H2O2Epoxidations

(2009) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation

(2009) Oleg Y. Lyakin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst Stability Determines the Catalytic Activity of Non-Heme Iron Catalysts in the Oxidation of Alkanes

(2008) Jason England et al.   ADVANCED SYNTHESIS & CATALYSIS

A Trispyrazolylborato Iron Malonato Complex as a Functional Model for the Acetylacetone Dioxygenase

(2008) Inke Siewert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Asymmetric Olefincis-Dihydroxylation with 97 % Enantiomeric Excess

(2008) Ken Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?

(2008) Stephan Enthaler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biomimetic Iron-Catalyzed Asymmetric Epoxidation of Aromatic Alkenes by Using Hydrogen Peroxide

(2008) Feyissa Gadissa Gelalcha et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Improved Iron-Catalyzed Epoxidation of Aromatic and Aliphatic Olefins with Hydrogen Peroxide as Oxidant

(2008) Bianca Bitterlich et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Epoxidation of Cyclic Enones

(2008) Xingwang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Big data: The next Google

(2008)   NATURE

Versatility of biological non-heme Fe(II) centers in oxygen activation reactions

(2008) Elena G Kovaleva et al.   Nature Chemical Biology

Iron(II) Complexes with Bio-Inspired N,N,O Ligands as Oxidation Catalysts: Olefin Epoxidation andcis-Dihydroxylation

(2007) Pieter C. A. Bruijnincx et al.   CHEMISTRY-A EUROPEAN JOURNAL

Epoxidation and 1,2-Dihydroxylation of Alkenes by a Nonheme Iron Model System − DFT Supports the Mechanism Proposed by Experiment

(2007) Peter Comba et al.   INORGANIC CHEMISTRY