Biomimetic Iron-Catalyzed Asymmetric Epoxidations: Fundamental Concepts, Challenges and Opportunities
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Title
Biomimetic Iron-Catalyzed Asymmetric Epoxidations: Fundamental Concepts, Challenges and Opportunities
Authors
Keywords
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Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 356, Issue 2-3, Pages 261-299
Publisher
Wiley
Online
2014-01-28
DOI
10.1002/adsc.201300716
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Note: Only part of the references are listed.- Kinetic Mechanism of Phenylalanine Hydroxylase: Intrinsic Binding and Rate Constants from Single-Turnover Experiments
- (2013) Kenneth M. Roberts et al. BIOCHEMISTRY
- Intermediate P* from Soluble Methane Monooxygenase Contains a Diferrous Cluster
- (2013) Rahul Banerjee et al. BIOCHEMISTRY
- Chiral Iron Catalysts for Asymmetric Synthesis
- (2013) Kovuru Gopalaiah CHEMICAL REVIEWS
- Metal-catalyzed asymmetric sulfoxidation, epoxidation and hydroxylation by hydrogen peroxide
- (2013) Hassan Srour et al. COORDINATION CHEMISTRY REVIEWS
- The FeIII(H2O2) Complex as a Highly Efficient Oxidant in Sulfoxidation Reactions: Revival of an Underrated Oxidant in Cytochrome P450
- (2013) Binju Wang et al. Journal of Chemical Theory and Computation
- Peroxidase activity of a myoglobin mutant with three distal histidines forming a metal-binding site: Implications for the cross-reactivity of cytochrome c oxidase
- (2013) Ying-Wu Lin et al. JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC
- Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-heme Iron Catalysts
- (2013) Olaf Cussó et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Comparison of High-Spin and Low-Spin Nonheme FeIII–OOH Complexes in O–O Bond Homolysis and H-Atom Abstraction Reactivities
- (2013) Lei V. Liu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Rate-Determining Water-Assisted O–O Bond Cleavage of an FeIII-OOH Intermediate in a Bio-inspired Nonheme Iron-Catalyzed Oxidation
- (2013) Williamson N. Oloo et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Mechanistic studies of an unprecedented enzyme-catalysed 1,2-phosphono-migration reaction
- (2013) Wei-chen Chang et al. NATURE
- Nonheme Iron Oxidant Formed in the Presence of H2O2 and Acetic Acid Is the Cyclic Ferric Peracetate Complex, Not a Perferryloxo Complex
- (2013) Yong Wang et al. ACS Catalysis
- Molecularly enlarged S,S-BnTsDPEN ligands for iron-catalyzed asymmetric olefin epoxidation reactions using hydrogen peroxide
- (2013) Vital A. Yazerski et al. Catalysis Science & Technology
- Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant
- (2012) Zhuangzhi Shi et al. CHEMICAL SOCIETY REVIEWS
- Highly Enantioselective Epoxidation of Multisubstituted Enones Catalyzed by Non-Heme Iron Catalysts
- (2012) Bin Wang et al. CHEMISTRY-A EUROPEAN JOURNAL
- High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy
- (2012) Aidan R. McDonald et al. COORDINATION CHEMISTRY REVIEWS
- [FeIV═O(TBC)(CH3CN)]2+: Comparative Reactivity of Iron(IV)-Oxo Species with Constrained Equatorial Cyclam Ligation
- (2012) Samuel A. Wilson et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- A Non-Heme Iron(III) Complex with Porphyrin-like Properties That Catalyzes Asymmetric Epoxidation
- (2012) Takashi Niwa et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Evidence for an Alternative to the Oxygen Rebound Mechanism in C–H Bond Activation by Non-Heme FeIVO Complexes
- (2012) Kyung-Bin Cho et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Reversible O–O Bond Scission of Peroxodiiron(III) to High-Spin Oxodiiron(IV) in Dioxygen Activation of a Diiron Center with a Bis-tpa Dinucleating Ligand as a Soluble Methane Monooxygenase Model
- (2012) Masahito Kodera et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Enantioselective water-soluble iron–porphyrin-catalyzed epoxidation with aqueous hydrogen peroxide and hydroxylation with iodobenzene diacetate
- (2012) Paul Le Maux et al. TETRAHEDRON
- Asymmetric vanadium- and iron-catalyzed oxidations: new mild (R)-modafinil synthesis and formation of epoxides using aqueous H2O2 as a terminal oxidant
- (2012) Kerstin A. Stingl et al. TETRAHEDRON
- Asymmetric Epoxidations with H2O2 on Fe and Mn Aminopyridine Catalysts: Probing the Nature of Active Species by Combined Electron Paramagnetic Resonance and Enantioselectivity Study
- (2012) Oleg Y. Lyakin et al. ACS Catalysis
- Dioxygen Activation in Soluble Methane Monooxygenase
- (2011) Christine E. Tinberg et al. ACCOUNTS OF CHEMICAL RESEARCH
- Chiral Bioinspired Non-Heme Iron Complexes for Enantioselective Epoxidation of α,β-Unsaturated Ketones
- (2011) Mei Wu et al. ADVANCED SYNTHESIS & CATALYSIS
- Mechanistic Studies of Reactions of Peroxodiiron(III) Intermediates in T201 Variants of Toluene/o-Xylene Monooxygenase Hydroxylase
- (2011) Woon Ju Song et al. BIOCHEMISTRY
- A new efficient ironcatalyst for olefinepoxidation with hydrogen peroxide
- (2011) Elena A. Mikhalyova et al. CHEMICAL COMMUNICATIONS
- Application of Designed Enzymes in Organic Synthesis
- (2011) Gernot A. Strohmeier et al. CHEMICAL REVIEWS
- Enantioenriched Compounds via Enzyme-Catalyzed Redox Reactions
- (2011) Mélanie Hall et al. CHEMICAL REVIEWS
- A combined experimental and computational study on the sulfoxidation by high-valent iron bispidine complexes
- (2011) Madhavan Jaccob et al. DALTON TRANSACTIONS
- Iron Coordination Chemistry of N2Py2 Ligands Substituted by Carboxylic Moieties and Their Impact on Alkene Oxidation Catalysis
- (2011) Frédéric Oddon et al. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
- Scandium Ion-Enhanced Oxidative Dimerization andN-Demethylation ofN,N-Dimethylanilines by a Non-Heme Iron(IV)-Oxo Complex
- (2011) Jiyun Park et al. INORGANIC CHEMISTRY
- Biocatalysis as an alternative for the production of chiral epoxides: A comparative review
- (2011) Hui Lin et al. JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC
- Iron-Catalyzed Asymmetric Epoxidation of β,β-Disubstituted Enones
- (2011) Yasuhiro Nishikawa et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Ligand Topology Effect on the Reactivity of a Mononuclear Nonheme Iron(IV)-Oxo Complex in Oxygenation Reactions
- (2011) Seungwoo Hong et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Metal Ion Effect on the Switch of Mechanism from Direct Oxygen Transfer to Metal Ion-Coupled Electron Transfer in the Sulfoxidation of Thioanisoles by a Non-Heme Iron(IV)−Oxo Complex
- (2011) Jiyun Park et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Asymmetric catalysis using iron complexes – ‘Ruthenium Lite’?
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- Metal Ion-Coupled Electron Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc3+
- (2010) Yuma Morimoto et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Million-fold activation of the [Fe2(µ-O)2] diamond core for C–H bond cleavage
- (2010) Genqiang Xue et al. Nature Chemistry
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- (2010) L. V. Liu et al. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
- Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics
- (2010) J. Rittle et al. SCIENCE
- Sustainability in Catalysis - Concept or Contradiction?
- (2010) Bernd Plietker SYNLETT
- Water as an Oxygen Source in the Generation of Mononuclear Nonheme Iron(IV) Oxo Complexes
- (2009) Yong-Min Lee et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A Two-State Reactivity Model Explains Unusual Kinetic Isotope Effect Patterns in CH Bond Cleavage by Nonheme Oxoiron(IV) Complexes
- (2009) Eric J. Klinker et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Measurement of Intrinsic Rate Constants in the Tyrosine Hydroxylase Reaction
- (2009) Bekir E. Eser et al. BIOCHEMISTRY
- Reductive elimination of superoxide: Structure and mechanism of superoxide reductases
- (2009) Ana Filipa Pinto et al. BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS
- P450 Enzymes: Their Structure, Reactivity, and Selectivity—Modeled by QM/MM Calculations
- (2009) Sason Shaik et al. CHEMICAL REVIEWS
- Contrasting Effects of Axial Ligands on Electron-Transfer Versus Proton-Coupled Electron-Transfer Reactions of Nonheme Oxoiron(IV) Complexes
- (2009) Shunichi Fukuzumi et al. CHEMISTRY-A EUROPEAN JOURNAL
- Asymmetric Epoxidation of Terminal Olefins with Binaphthyl Strapped Porphyrin Catalysts: (-( Stacking Interaction and Steric Effects on the Enantioselectivities
- (2009) Qizhi REN et al. CHINESE JOURNAL OF CHEMISTRY
- Contrastingcis andtrans Effects on the Reactivity of Nonheme Oxoiron(IV) Complexes
- (2008) Yuming Zhou et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Iron-Catalyzed Asymmetric Olefincis-Dihydroxylation with 97 % Enantiomeric Excess
- (2008) Ken Suzuki et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- A chiral iron-sexipyridine complex as a catalyst for alkene epoxidation with hydrogen peroxide
- (2008) Ho-Lun Yeung et al. CHEMICAL COMMUNICATIONS
- Organocatalytic Oxidation. Asymmetric Epoxidation of Olefins Catalyzed by Chiral Ketones and Iminium Salts
- (2008) O. Andrea Wong et al. CHEMICAL REVIEWS
- Iron-catalysed carbon–heteroatom and heteroatom–heteroatom bond forming processes
- (2008) Arkaitz Correa et al. CHEMICAL SOCIETY REVIEWS
- Biomimetic Iron-Catalyzed Asymmetric Epoxidation of Aromatic Alkenes by Using Hydrogen Peroxide
- (2008) Feyissa Gadissa Gelalcha et al. CHEMISTRY-A EUROPEAN JOURNAL
- Iron-Catalyzed Hydrogenation, Hydride Transfer, and Hydrosilylation: An Alternative to Precious-Metal Complexes?
- (2008) Sylvain Gaillard et al. ChemSusChem
- Asymmetric Epoxidation of Electron-Deficient Olefins
- (2008) David Diez et al. CURRENT ORGANIC SYNTHESIS
- Biologically inspired oxidation catalysis
- (2008) Lawrence Que et al. NATURE
- Further insights into the mechanism of the reaction of activated bleomycin with DNA
- (2008) M. S. Chow et al. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA
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