Olefincis-Dihydroxylation and Aliphatic CH Bond Oxygenation by a Dioxygen-Derived Electrophilic Iron-Oxygen Oxidant

Spectroscopic Identification of an FeIII Center, not FeIV, in the Crystalline Sc–O–Fe Adduct Derived from [FeIV(O)(TMC)]2+

(2015) Jai Prakash et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modeling TauD-J: A High-Spin Nonheme Oxoiron(IV) Complex with High Reactivity toward C–H Bonds

(2015) Achintesh N. Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemical study of a nonheme Fe(ii) complex in the presence of dioxygen. Insights into the reductive activation of O2 at Fe(ii) centers

(2015) Nathalie Ségaud et al.   Chemical Science

Demonstration of the Heterolytic OO Bond Cleavage of Putative Nonheme Iron(II)OOH(R) Complexes for Fenton and Enzymatic Reactions

(2014) Suhee Bang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity of an Iron–Oxygen Oxidant Generated upon Oxidative Decarboxylation of Biomimetic Iron(II) α-Hydroxy Acid Complexes

(2014) Sayantan Paria et al.   INORGANIC CHEMISTRY

Autocatalytic Formation of an Iron(IV)–Oxo Complex via Scandium Ion-Promoted Radical Chain Autoxidation of an Iron(II) Complex with Dioxygen and Tetraphenylborate

(2014) Yusuke Nishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-inactive metal ions modulate the reactivity and oxygen release of mononuclear non-haem iron(III)–peroxo complexes

(2014) Suhee Bang et al.   Nature Chemistry

A Mononuclear Non-Heme Manganese(IV)–Oxo Complex Binding Redox-Inactive Metal Ions

(2013) Junying Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sc3+-Triggered Oxoiron(IV) Formation from O2 and its Non-Heme Iron(II) Precursor via a Sc3+–Peroxo–Fe3+ Intermediate

(2013) Feifei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A mononuclear nonheme iron(iii)–peroxo complex binding redox-inactive metal ions

(2013) Yong-Min Lee et al.   Chemical Science

Chemo- and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

(2012) Evgenii P. Talsi et al.   COORDINATION CHEMISTRY REVIEWS

Electron-transfer properties of high-valent metal-oxo complexes

(2012) Shunichi Fukuzumi   COORDINATION CHEMISTRY REVIEWS

Oxidative Decarboxylation of Benzilic Acid by a Biomimetic Iron(II) Complex: Evidence for an Iron(IV)-Oxo-Hydroxo Oxidant from O2

(2011) Sayantan Paria et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Biomimetic Iron Catalyst for the Epoxidation of Olefins with Molecular Oxygen at Room Temperature

(2011) Kristin Schröder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Theoretical Study of the Mechanism of Oxoiron(IV) Formation from H2O2and a Nonheme Iron(II) Complex: O–O Cleavage Involving Proton-Coupled Electron Transfer

(2011) Hajime Hirao et al.   INORGANIC CHEMISTRY

O2Activation by Bis(imino)pyridine Iron(II)−Thiolate Complexes

(2011) Yosra M. Badiei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Elusive iron(V) species identified

(2011) Aidan R. McDonald et al.   Nature Chemistry

Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

(2011) Irene Prat et al.   Nature Chemistry

Exploring the oxygen sensitivity of FeCl2 complexes with tris(2-pyridylmethyl)amine-type ligands: O2 coordination and a quest for superoxide

(2011) Dominique Mandon et al.   NEW JOURNAL OF CHEMISTRY

An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions

(2010) Florian Felix Pfaff et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Substrate activation by iron superoxo intermediates

(2010) Wilfred A van der Donk et al.   CURRENT OPINION IN STRUCTURAL BIOLOGY

Tuning the conversion of cyclohexane into cyclohexanol/one by molecular dioxygen, protons and reducing agents at a single non-porphyrinic iron centre and chemical versatility of the tris(2-pyridylmethyl)amine TPAFeIICl2complex in mild oxidation chemistry

(2010) Hassen Jaafar et al.   DALTON TRANSACTIONS

OlefinCis-Dihydroxylation with Bio-Inspired Iron Catalysts. Evidence for an FeII/FeIVCatalytic Cycle

(2010) Paul D. Oldenburg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dioxygen Activation by a Non-Heme Iron(II) Complex: Formation of an Iron(IV)−Oxo Complex via C−H Activation by a Putative Iron(III)−Superoxo Species

(2010) Yong-Min Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cytochrome P450 Compound I: Capture, Characterization, and C-H Bond Activation Kinetics

(2010) J. Rittle et al.   SCIENCE

Shape-Selective Interception by Hydrocarbons of the O2-Derived Oxidant of a Biomimetic Nonheme Iron Complex

(2009) Anusree Mukherjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of dioxygen by a mononuclear non-heme iron complex: characterization of a FeIII(OOH) intermediate

(2009) Marlène Martinho et al.   DALTON TRANSACTIONS

Dioxygen Activation by Mononuclear Nonheme Iron(II) Complexes Generates Iron−Oxygen Intermediates in the Presence of an NADH Analogue and Proton

(2009) Seungwoo Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton- and Reductant-Assisted Dioxygen Activation by a Nonheme Iron(II) Complex to Form an Oxoiron(IV) Intermediate

(2008) Aurore Thibon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biologically inspired oxidation catalysis

(2008) Lawrence Que et al.   NATURE

Versatility of biological non-heme Fe(II) centers in oxygen activation reactions

(2008) Elena G Kovaleva et al.   Nature Chemical Biology