Molecular iron complexes as catalysts for selective C–H bond oxygenation reactions

Olefincis-Dihydroxylation and Aliphatic CH Bond Oxygenation by a Dioxygen-Derived Electrophilic Iron-Oxygen Oxidant

(2015) Sayanti Chatterjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural diversity of late transition metal complexes with flexible tetra-NHC ligands

(2015) Daniel T. Weiss et al.   DALTON TRANSACTIONS

Synthesis and Characterization of an Iron Complex Bearing a Cyclic Tetra-N-heterocyclic Carbene Ligand: An Artifical Heme Analogue?

(2015) Markus R. Anneser et al.   INORGANIC CHEMISTRY

Iron-catalyzed oxidation of unreactive C H bonds: Utilizing bio-inspired axial ligand modification to increase catalyst stability

(2015) Stefan Haslinger et al.   JOURNAL OF CATALYSIS

Iron Complexes of a Macrocyclic N-Heterocyclic Carbene/Pyridine Hybrid Ligand

(2015) Iris Klawitter et al.   ORGANOMETALLICS

Catalytic behaviour of a novel Fe(iii) Schiff base complex in the mild oxidation of cyclohexane

(2015) Dmytro S. Nesterov et al.   Catalysis Science & Technology

Synthesis, characterization, electrochemical properties and catalytic reactivity of N-heterocyclic carbene-containing diiron complexes

(2015) Yanhong Wang et al.   RSC Advances

The Iron(II) Complex [Fe(CF3SO3)2(mcp)] as a Convenient, Readily Available Catalyst for the Selective Oxidation of Methylenic Sites in Alkanes

(2014) Mercè Canta et al.   ADVANCED SYNTHESIS & CATALYSIS

Efficient hydroxylation of aromatic compounds catalyzed by an iron(II) complex with H2O2

(2014) Xiao Wang et al.   APPLIED ORGANOMETALLIC CHEMISTRY

Epoxidation of Olefins Catalyzed by a Molecular IronN-Heterocyclic Carbene Complex: Influence of Reaction Parameters on the Catalytic Activity

(2014) Jens W. Kück et al.   ChemCatChem

Catalytic hydroxylation of benzene and toluene by an iron complex bearing a chelating di-pyridyl-di-NHC ligand

(2014) Andreas Raba et al.   CHEMICAL COMMUNICATIONS

Chemistry of Iron N-Heterocyclic Carbene Complexes: Syntheses, Structures, Reactivities, and Catalytic Applications

(2014) Korbinian Riener et al.   CHEMICAL REVIEWS

Active sites and mechanisms of bioinspired oxidation with H2O2, catalyzed by non-heme Fe and related Mn complexes

(2014) Konstantin P. Bryliakov et al.   COORDINATION CHEMISTRY REVIEWS

Unraveling the origins of catalyst degradation in non-heme iron-based alkane oxidation

(2014) Michaela Grau et al.   DALTON TRANSACTIONS

Iron(iii) complexes of multidentate pyridinyl ligands: synthesis, characterization and catalysis of the direct hydroxylation of benzene

(2014) Beibei Xu et al.   DALTON TRANSACTIONS

Oxyfunctionalization of polystyrene by hydrogen peroxide using non-heme iron catalysts

(2014) Shelley McArthur et al.   EUROPEAN POLYMER JOURNAL

Making Oxidation Potentials Predictable: Coordination of Additives Applied to the Electronic Fine Tuning of an Iron(II) Complex

(2014) Stefan Haslinger et al.   INORGANIC CHEMISTRY

Making Fe(BPBP)-catalyzed C–H and CC oxidations more affordable

(2014) Vital A. Yazerski et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions

(2014) Mekhman S. Yusubov et al.   TETRAHEDRON LETTERS

Synthesis, Characterization, and Catalytic Activity of Iron(II) and Nickel(II) Complexes Containing the Rigid Pentadentate Ligand PY5Me2

(2014) Jing Xiang et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Hydrocarbon oxidation catalyzed by a cheap nonheme imine-based iron(ii) complex

(2014) Giorgio Olivo et al.   Catalysis Science & Technology

Iron-catalyzed/mediated oxidative transformation of C–H bonds

(2014) Fan Jia et al.   Organic Chemistry Frontiers

Nonheme Iron Mediated Oxidation of Light Alkanes with Oxone: Characterization of Reactive Oxoiron(IV) Ligand Cation Radical Intermediates by Spectroscopic Studies and DFT Calculations

(2013) Chun-Wai Tse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxygenation of saturated and aromatic hydrocarbons with H2O2 catalysed by the carbonyl thiophenolate iron complex (OC)3Fe(PhS)2Fe(CO)3

(2013) Eduard E. Karslyan et al.   CATALYSIS TODAY

Catalytic oxidation of alkanes by iron bispidine complexes and dioxygen: oxygen activation versus autoxidation

(2013) Peter Comba et al.   CHEMICAL COMMUNICATIONS

Phthalocyanine Metal Complexes in Catalysis

(2013) Alexander B. Sorokin   CHEMICAL REVIEWS

Electronic Tuning of Iron-Oxo-Mediated CH Activation: Effect of Electron-Donating Ligand on Selectivity

(2013) Yutaka Hitomi et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Mechanism of Stereospecific CH Oxidation by Fe(Pytacn) Complexes: Bioinspired Non-Heme Iron Catalysts Containingcis-Labile Exchangeable Sites

(2013) Irene Prat et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-catalyzed asymmetric sulfoxidation, epoxidation and hydroxylation by hydrogen peroxide

(2013) Hassan Srour et al.   COORDINATION CHEMISTRY REVIEWS

Hexanuclear and undecanuclear iron(iii) carboxylates as catalyst precursors for cyclohexane oxidation

(2013) Miljan N. M. Milunovic et al.   DALTON TRANSACTIONS

Assessing the Impact of Electronic and Steric Tuning of the Ligand in the Spin State and Catalytic Oxidation Ability of the FeII(Pytacn) Family of Complexes

(2013) Irene Prat et al.   INORGANIC CHEMISTRY

C–H Oxidation by H2O2 and O2 Catalyzed by a Non-Heme Iron Complex with a Sterically Encumbered Tetradentate N-Donor Ligand

(2013) Qiao Zhang et al.   INORGANIC CHEMISTRY

Iron Coordination Chemistry with New Ligands Containing Triazole and Pyridine Moieties. Comparison of the Coordination Ability of the N-Donors

(2013) Nathalie Ségaud et al.   INORGANIC CHEMISTRY

Hydrocarbon oxidation catalyzed by manganese and iron complexes with the hexadentate ligand N,N'-di(ethylacetate)-N,N′-bis(2-pyridylmethyl)-1,2-ethanediamine

(2013) Qiao Zhang et al.   INORGANICA CHIMICA ACTA

Ionic liquids as reaction media in catalytic oxidations with manganese and iron pyridyl triazacyclononane complexes

(2013) Sara Lentini et al.   INORGANICA CHIMICA ACTA

Polydentate pyridyl ligands and the catalytic activity of their iron(II) complexes in oxidation reactions utilizing peroxides as the oxidants

(2013) Matthew Lenze et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

8-Quinolinolato iron(III)-catalyzed oxygenation of cyclohexane with hydrogen peroxide under heating or visible light irradiation

(2013) Yongjun Wang et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Regioselective Oxidation of Nonactivated Alkyl C–H Groups Using Highly Structured Non-Heme Iron Catalysts

(2013) Laura Gómez et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalyst-Controlled Aliphatic C–H Oxidations with a Predictive Model for Site-Selectivity

(2013) Paul E. Gormisky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective activation of secondary C–H bonds by an iron catalyst: insights into possibilities created by the use of a carboxyl-containing bipyridine ligand

(2013) Shi Cheng et al.   NEW JOURNAL OF CHEMISTRY

A strong-field pentadentate ligand in iron-based alkane oxidation catalysis and implications for iron(iv) oxo intermediates

(2013) Emma Wong et al.   Catalysis Science & Technology

An Iron(III)-Monoamidate Complex Catalyst for Selective Hydroxylation of Alkane CH Bonds with Hydrogen Peroxide

(2012) Yutaka Hitomi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic, Mild, and Selective Oxyfunctionalization of Linear Alkanes: Current Challenges

(2012) Mélanie Bordeaux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic hydrocarbon oxidation by iron complex of 5,10,15-tris(difluorophenyl)corrole via activation of hydroperoxides

(2012) Anand Pariyar et al.   CATALYSIS COMMUNICATIONS

Oxidation of cyclohexane by transition-metal complexes with biomimetic ligands

(2012) Ana Rosa Silva et al.   CATALYSIS TODAY

Observation of a ferric hydroperoxide complex during the non-heme iron catalysed oxidation of alkenes and alkanes by O2

(2012) Yu He et al.   CHEMICAL COMMUNICATIONS

Hydroxylation of Aromatics with the Help of a Non-Haem FeOOH: A Mechanistic Study under Single-Turnover and Catalytic Conditions

(2012) Aurore Thibon et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed CH Hydroxylation and Olefincis-Dihydroxylation Using a Single-Electron Oxidant and Water as the Oxygen-Atom Source

(2012) Isaac Garcia-Bosch et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Iron Catalyst for Oxidation of Alkyl CH Bonds Showing Enhanced Selectivity for Methylenic Sites

(2012) Irene Prat et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemo- and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

(2012) Evgenii P. Talsi et al.   COORDINATION CHEMISTRY REVIEWS

High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy

(2012) Aidan R. McDonald et al.   COORDINATION CHEMISTRY REVIEWS

Aquasoluble iron(III)-arylhydrazone-β-diketone complexes: Structure and catalytic activity for the peroxidative oxidation of C5–C8 cycloalkanes

(2012) Maximilian N. Kopylovich et al.   JOURNAL OF INORGANIC BIOCHEMISTRY

Synthesis and Characterization of Novel Iron(II) Complexes with Tetradentate Bis(N-heterocyclic carbene)–Bis(pyridine) (NCCN) Ligands

(2012) Andreas Raba et al.   ORGANOMETALLICS

Structure and oxygenase activity of the iron(ii) complex with pyridylcarboxamide ligand

(2012) E. A. Turitsyna et al.   RUSSIAN CHEMICAL BULLETIN

Structure and catalytic activity of a new iron(II) complex with a tetradentate carboxamide ligand: The effect of the outer-sphere donor on the chemoselectivity of the metal complex catalyst

(2012) A. A. Shteinman   RUSSIAN JOURNAL OF INORGANIC CHEMISTRY

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

l-Proline derived mimics of the non-haem iron active site catalyse allylic oxidation in acetonitrile solutions

(2012) Victoria J. Dungan et al.   TETRAHEDRON LETTERS

Use of iron and manganese porphyrins in solution and immobilized on silica obtained by the sol–gel process as catalyst in the oxidation of organic substrates

(2011) Geani Maria Ucoski et al.   APPLIED CATALYSIS A-GENERAL

Mild alkane C–H and O–H oxidations catalysed by mixed-N,S copper, iron and vanadium systems

(2011) Ricardo R. Fernandes et al.   APPLIED CATALYSIS A-GENERAL

Selective C–H oxidation catalyzed by metalloporphyrins

(2011) Miquel Costas   COORDINATION CHEMISTRY REVIEWS

Efficient catalytic cycloalkane oxidation employing a “helmet” phthalocyaninato iron(iii) complex

(2011) Elizabeth S. Brown et al.   DALTON TRANSACTIONS

New iron(ii) α-iminopyridine complexes and their catalytic activity in the oxidation of activated methylene groups and secondary alcohols to ketones

(2011) Pushkar Shejwalkar et al.   DALTON TRANSACTIONS

Mechanistic investigation of cyclohexane oxidation by a non-heme iron complex: evidence of product inhibition by UV/vis stopped-flow studies

(2011) Lauren C. Gregor et al.   DALTON TRANSACTIONS

Steric Modifications Tune the Regioselectivity of the Alkane Oxidation Catalyzed by Non-Heme Iron Complexes

(2011) Yu He et al.   INORGANIC CHEMISTRY

Mono- and Dinuclear Iron Complexes of Bis(1-methylimidazol-2-yl)ketone (bik): Structure, Magnetic Properties, and Catalytic Oxidation Studies

(2011) Pieter C. A. Bruijnincx et al.   INORGANIC CHEMISTRY

The mechanistic aspects of iron(III) porphyrin catalyzed oxidation reactions in mixed solvents

(2011) Amit Singh et al.   INORGANICA CHIMICA ACTA

Bis- and tris-pyridyl amino and imino thioether Cu and Fe complexes. Thermal and microwave-assisted peroxidative oxidations of 1-phenylethanol and cyclohexane in the presence of various N-based additives

(2011) Ricardo R. Fernandes et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Synthesis and structural characterization of iron complexes with 2,2,2-tris(1-pyrazolyl)ethanol ligands: Application in the peroxidative oxidation of cyclohexane under mild conditions

(2011) Telma F.S. Silva et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Axial Ligand Effect On The Rate Constant of Aromatic Hydroxylation By Iron(IV)–Oxo Complexes Mimicking Cytochrome P450 Enzymes

(2011) Devesh Kumar et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Properties of (μ-Oxo)di-iron complexes and catalytic activity toward cyclohexane oxidation

(2011) Gabrieli L. Parrilha et al.   JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY

Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

(2011) Irene Prat et al.   Nature Chemistry

Iron oligopyridine complexes as efficient catalysts for practical oxidation of arenes, alkanes, tertiary amines and N-acyl cyclic amines with Oxone

(2011) Peng Liu et al.   Chemical Science

Mild oxidation of hydrocarbons catalyzed by iron corrole with tert-butylhydroperoxide

(2010) Achintesh Narayan Biswas et al.   CATALYSIS COMMUNICATIONS

Hydrocarbon oxidation by homogeneous and heterogeneous non-heme iron (III) catalysts with H2O2

(2010) G. Bilis et al.   CATALYSIS TODAY

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Selective Iron-Catalyzed Oxidation of Phenols and Arenes with Hydrogen Peroxide: Synthesis of Vitamin E Intermediates and Vitamin K3

(2010) Konstanze Möller et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aromatic Hydroxylation at a Non-Heme Iron Center: Observed Intermediates and Insights into the Nature of the Active Species

(2010) Olga V. Makhlynets et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tuning the conversion of cyclohexane into cyclohexanol/one by molecular dioxygen, protons and reducing agents at a single non-porphyrinic iron centre and chemical versatility of the tris(2-pyridylmethyl)amine TPAFeIICl2complex in mild oxidation chemistry

(2010) Hassen Jaafar et al.   DALTON TRANSACTIONS

Iron complexes of new hydrophobic derivatives oftris(2-pyridylmethyl)amine: synthesis, characterization, and catalysis of alkane oxygenation by H2O2

(2010) Gregorio Guisado-Barrios et al.   JOURNAL OF COORDINATION CHEMISTRY

Selective hydroxylation of alkanes catalyzed by iron(IV)corrole

(2010) Achintesh Narayan Biswas et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

A monocarboxylate-bridged diiron(iii) μ-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

(2010) Martin Jarenmark et al.   NEW JOURNAL OF CHEMISTRY

Coordination compounds from the planar tridentate Schiff-base ligand 2-methoxy-6-((quinolin-8-ylimino)methyl)phenol (mqmpH) with several transition metal ions: Use of [FeIII(mqmp)(CH3OH)Cl2] in the catalytic oxidation of alkanes and alkenes

(2010) Sanjit Nayak et al.   POLYHEDRON

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE

Binuclear iron(III) phthalocyanine(μ-oxodimer)/tetrabutylammonium oxone: a powerful catalytic system for oxidation of hydrocarbons in organic solution

(2010) Heather M. Neu et al.   TETRAHEDRON LETTERS

Hydrocarbon Oxidation with H2O2, Catalyzed by Iron Complexes with a Polydentate Pyridine-Based Ligand

(2010) Stefania Tanase et al.   TOPICS IN CATALYSIS

Binuclear Iron(III) Phthalocyanine(μ-Oxodimer)-Catalyzed Oxygenation of Aromatic Hydrocarbons with Iodosylbenzene Sulfate and Iodosylbenzene as the Oxidants

(2009) Heather M. Neu et al.   ADVANCED SYNTHESIS & CATALYSIS

Stereospecific CH Oxidation with H2O2Catalyzed by a Chemically Robust Site-Isolated Iron Catalyst

(2009) Laura Gómez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes

(2009) Paul R. Ortiz de Montellano   CHEMICAL REVIEWS

Towards robust alkane oxidation catalysts: electronic variations in non-heme iron(ii) complexes and their effect in catalytic alkane oxidation

(2009) Jason England et al.   DALTON TRANSACTIONS

Mononuclear iron complexes relevant to nonheme iron oxygenases. Synthesis, characterizations and reactivity of Fe-Oxo and Fe-Peroxo intermediates

(2009) Aurore Thibon et al.   DALTON TRANSACTIONS

Chemoselective and biomimetic hydroxylation of hydrocarbons by non-heme μ-oxo-bridged diiron(iii) catalysts using m-CPBA as oxidant

(2009) Ramasamy Mayilmurugan et al.   DALTON TRANSACTIONS

Oxidation of Cyclohexane by High-Valent Iron Bispidine Complexes: Tetradentate versus Pentadentate Ligands

(2009) Peter Comba et al.   INORGANIC CHEMISTRY

Oxidation of activated methylene groups to ketones catalyzed by new iron phosphinooxazoline complexes and by iron(II) triflate

(2009) Matthew Lenze et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

EPR Spectroscopic Trapping of the Active Species of Nonheme Iron-Catalyzed Oxidation

(2009) Oleg Y. Lyakin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron oxygenases: structure, mechanism and modelling

(2009) Al'bert A Shteinman   RUSSIAN CHEMICAL REVIEWS

Catalyst Stability Determines the Catalytic Activity of Non-Heme Iron Catalysts in the Oxidation of Alkanes

(2008) Jason England et al.   ADVANCED SYNTHESIS & CATALYSIS

Half-Sandwich Scorpionate Vanadium, Iron and Copper Complexes: Synthesis and Application in the Catalytic Peroxidative Oxidation of Cyclohexane under Mild Conditions

(2008) Telma F. S. Silva et al.   ADVANCED SYNTHESIS & CATALYSIS

Selective Oxidation of Aliphatic CH Bonds in the Synthesis of Complex Molecules

(2008) Mathias Christmann   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Oxidation of Organic Substrates by Molecular Oxygen and Hydrogen Peroxide by Multistep Electron Transfer—A Biomimetic Approach

(2008) Julio Piera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidations of cycloalkanes and benzene by hydrogen peroxide catalyzed by an {FeIIIN2S2} centre

(2008) Ricardo R. Fernandes et al.   APPLIED CATALYSIS A-GENERAL

Chiral iron(III)-salen-catalyzed oxidation of hydrocarbons

(2008) A BISWAS et al.   CATALYSIS COMMUNICATIONS

Oxidation of polycyclic aromatic hydrocarbons with hydrogen peroxide catalyzed by Iron(III)porphyrins

(2008) N GIRI et al.   CATALYSIS COMMUNICATIONS

Influence of microwave irradiation in the cyclohexane oxidation catalyzed by Fe(III) complexes

(2008) Nakédia M.F. Carvalho et al.   CATALYSIS TODAY

Bio-inspired oxidation of methane in water catalyzed by N-bridged diiron phthalocyanine complex

(2008) Alexander B. Sorokin et al.   CHEMICAL COMMUNICATIONS

Direct evidence for an iron(iv)-oxo porphyrin π-cation radical as an active oxidant in catalytic oxygenation reactions

(2008) Ah-Rim Han et al.   CHEMICAL COMMUNICATIONS

A Novel Platform for Modeling Oxidative Catalysis in Non‐Heme Iron Oxygenases with Unprecedented Efficiency

(2008) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic implications of the active species involved in the oxidation of hydrocarbons by iron complexes of pyrazine-2-carboxylic acid

(2008) Stefania Tanase et al.   DALTON TRANSACTIONS

The system iron(II)/mpzbpy mediates the H2O2 oxidation of cyclohexane and cyclooctene and the aerobic oxidative cleavage of ascorbic acid to oxalate

(2008) Graham de Ruiter et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Unexpected high oxidation of cyclohexane by Fe salts and dihydrogen peroxide in acetonitrile

(2008) Brandon Retcher et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Alkane hydroxylation catalyzed by a series of mononuclear nonheme iron complexes containing 4-nitropyridine ligands

(2008) Yutaka Hitomi et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Non-heme iron polyazadentate complexes as catalysts for aromatic hydroxylation by H2O2: Particular efficiency of tetrakis(2-pyridylmethyl)ethylenediamine–iron(II) complexes

(2008) Aurore Thibon et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Oxidation of Cyclohexane by a High-Valent Iron Bispidine Complex: A Combined Experimental and Computational Mechanistic Study†

(2008) Peter Comba et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Biologically inspired oxidation catalysis

(2008) Lawrence Que et al.   NATURE

The Fe(PDP)-catalyzed aliphatic C–H oxidation: a slow addition protocol

(2008) Nicolaas A. Vermeulen et al.   TETRAHEDRON