Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes

Highly Enantioselective Iron-Catalyzed cis -Dihydroxylation of Alkenes with Hydrogen Peroxide Oxidant via an FeIII -OOH Reactive Intermediate

(2016) Chao Zang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes

(2016) Xenia Engelmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exceedingly Fast Oxygen Atom Transfer to Olefins via a Catalytically Competent Nonheme Iron Species

(2016) Joan Serrano-Plana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Readily Accessible Bulky Iron Catalysts exhibiting Site Selectivity in the Oxidation of Steroidal Substrates

(2016) David Font et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From DNA to catalysis: a thymine-acetate ligated non-heme iron(iii) catalyst for oxidative activation of aliphatic C–H bonds

(2016) Afnan Al-hunaiti et al.   CHEMICAL COMMUNICATIONS

Iron Catalyzed Highly Enantioselective Epoxidation of Cyclic Aliphatic Enones with Aqueous H2O2

(2016) Olaf Cussó et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative diversification of amino acids and peptides by small-molecule iron catalysis

(2016) Thomas J. Osberger et al.   NATURE

Dramatic Effect of Carboxylic Acid on the Electronic Structure of the Active Species in Fe(PDP)-Catalyzed Asymmetric Epoxidation

(2016) Alexandra M. Zima et al.   ACS Catalysis

Bioinspired Nonheme Iron Catalysts for C–H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants

(2015) Williamson N. Oloo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Scalable Synthesis of Piperazines Enabled by Visible-Light Irradiation and Aluminum Organometallics

(2015) Samuel Suárez-Pantiga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Photooxygenation of Alkyl Benzenes Catalyzed by Riboflavin Tetraacetate and a Non-Heme Iron Catalyst

(2015) Bernd Mühldorf et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Interplay of a Non-Heme Iron Catalyst and Amino Acid Coligands in H2O2Activation for Asymmetric Epoxidation of α-Alkyl-Substituted Styrenes

(2015) Olaf Cussó et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular iron complexes as catalysts for selective C–H bond oxygenation reactions

(2015) A. C. Lindhorst et al.   CHEMICAL COMMUNICATIONS

Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives

(2015) Olaf Cussó et al.   CHEMICAL COMMUNICATIONS

Asymmetric Epoxidation Using Hydrogen Peroxide as Oxidant

(2015) Chuan Wang et al.   Chemistry-An Asian Journal

Fighting Fenton Chemistry: A Highly Active Iron(III) Tetracarbene Complex in Epoxidation Catalysis

(2015) Jens W. Kück et al.   ChemSusChem

Non-heme iron catalysts for epoxidation and aziridination reactions of challenging terminal alkenes: towards sustainability

(2015) Anja Fingerhut et al.   GREEN CHEMISTRY

C–H Bond Oxidation Catalyzed by an Imine-Based Iron Complex: A Mechanistic Insight

(2015) Giorgio Olivo et al.   INORGANIC CHEMISTRY

Enhanced Reactivity in Hydrogen Atom Transfer from Tertiary Sites of Cyclohexanes and Decalins via Strain Release: Equatorial C–H Activation vs Axial C–H Deactivation

(2015) Michela Salamone et al.   JOURNAL OF ORGANIC CHEMISTRY

Green and Efficient: Iron-Catalyzed Selective Oxidation of Olefins to Carbonyls with O2

(2015) Angela Gonzalez-de-Castro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C—H Bonds with Stereoretention

(2015) Joan Serrano-Plana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

EPR Spectroscopic Detection of the Elusive FeV═O Intermediates in Selective Catalytic Oxofunctionalizations of Hydrocarbons Mediated by Biomimetic Ferric Complexes

(2015) Oleg Y. Lyakin et al.   ACS Catalysis

Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes

(2014) Wonwoo Nam et al.   ACCOUNTS OF CHEMICAL RESEARCH

Biomimetic Iron-Catalyzed Asymmetric Epoxidations: Fundamental Concepts, Challenges and Opportunities

(2014) Feyissa Gadissa Gelalcha   ADVANCED SYNTHESIS & CATALYSIS

The Iron(II) Complex [Fe(CF3SO3)2(mcp)] as a Convenient, Readily Available Catalyst for the Selective Oxidation of Methylenic Sites in Alkanes

(2014) Mercè Canta et al.   ADVANCED SYNTHESIS & CATALYSIS

Practical Iron-Catalyzed Hydrogen Peroxide Epoxidation of Aromatic Olefins using a Combination of Two Kinds of Simple Picolinate Ligands under Halide-Free Reaction Conditions

(2014) Takefumi Chishiro et al.   ADVANCED SYNTHESIS & CATALYSIS

Dehydrogenative α-Oxygenation of Ethers with an Iron Catalyst

(2014) Angela Gonzalez-de-Castro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Making Fe(BPBP)-catalyzed C–H and CC oxidations more affordable

(2014) Vital A. Yazerski et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Hydrocarbon oxidation catalyzed by a cheap nonheme imine-based iron(ii) complex

(2014) Giorgio Olivo et al.   Catalysis Science & Technology

Fe(PyTACN)-Catalyzedcis-Dihydroxylation of Olefins with Hydrogen Peroxide

(2013) Irene Prat et al.   ADVANCED SYNTHESIS & CATALYSIS

Bioinspired Manganese and Iron Complexes with Tetradentate N Ligands for the Asymmetric Epoxidation of Olefins

(2013) Xiaoe Wang et al.   ChemCatChem

Efficient epoxidation of olefins by H2O2 catalyzed by iron “helmet” phthalocyanines

(2013) Igor Y. Skobelev et al.   CHEMICAL COMMUNICATIONS

Electronic Tuning of Iron-Oxo-Mediated CH Activation: Effect of Electron-Donating Ligand on Selectivity

(2013) Yutaka Hitomi et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Mechanism of Stereospecific CH Oxidation by Fe(Pytacn) Complexes: Bioinspired Non-Heme Iron Catalysts Containingcis-Labile Exchangeable Sites

(2013) Irene Prat et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fe-Catalyzed One-Pot Oxidative Cleavage of Unsaturated Fatty Acids into Aldehydes with Hydrogen Peroxide and Sodium Periodate

(2013) Peter Spannring et al.   CHEMISTRY-A EUROPEAN JOURNAL

Substituent Effects on the Catalytic Activity of Bipyrrolidine-Based Iron Complexes

(2013) Giorgio Olivo et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselective Oxidation of Nonactivated Alkyl C–H Groups Using Highly Structured Non-Heme Iron Catalysts

(2013) Laura Gómez et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-heme Iron Catalysts

(2013) Olaf Cussó et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rate-Determining Water-Assisted O–O Bond Cleavage of an FeIII-OOH Intermediate in a Bio-inspired Nonheme Iron-Catalyzed Oxidation

(2013) Williamson N. Oloo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled Aliphatic C–H Oxidations with a Predictive Model for Site-Selectivity

(2013) Paul E. Gormisky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Catalytic Diversity of Rieske Non-Heme Iron-Dependent Oxygenases

(2013) Sarah M. Barry et al.   ACS Catalysis

Nonheme Iron Oxidant Formed in the Presence of H2O2 and Acetic Acid Is the Cyclic Ferric Peracetate Complex, Not a Perferryloxo Complex

(2013) Yong Wang et al.   ACS Catalysis

An Iron(III)-Monoamidate Complex Catalyst for Selective Hydroxylation of Alkane CH Bonds with Hydrogen Peroxide

(2012) Yutaka Hitomi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Epoxidation of Multisubstituted Enones Catalyzed by Non-Heme Iron Catalysts

(2012) Bin Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Iron Catalyst for Oxidation of Alkyl CH Bonds Showing Enhanced Selectivity for Methylenic Sites

(2012) Irene Prat et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemo- and stereoselective CH oxidations and epoxidations/cis-dihydroxylations with H2O2, catalyzed by non-heme iron and manganese complexes

(2012) Evgenii P. Talsi et al.   COORDINATION CHEMISTRY REVIEWS

Directed Metal (Oxo) Aliphatic C–H Hydroxylations: Overriding Substrate Bias

(2012) Marinus A. Bigi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of unsaturated steroid ketones with hydrogen peroxide catalyzed by Fe(bpmen)(OTf)2. New methodology to access biologically active steroids by chemo-, and stereoselective processes

(2012) David Clemente-Tejeda et al.   TETRAHEDRON

Chiral Bioinspired Non-Heme Iron Complexes for Enantioselective Epoxidation of α,β-Unsaturated Ketones

(2011) Mei Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

A Biomimetic Iron Catalyst for the Epoxidation of Olefins with Molecular Oxygen at Room Temperature

(2011) Kristin Schröder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A new efficient ironcatalyst for olefinepoxidation with hydrogen peroxide

(2011) Elena A. Mikhalyova et al.   CHEMICAL COMMUNICATIONS

Steric Modifications Tune the Regioselectivity of the Alkane Oxidation Catalyzed by Non-Heme Iron Complexes

(2011) Yu He et al.   INORGANIC CHEMISTRY

Diverting non-haem iron catalysed aliphatic C–H hydroxylations towards desaturations

(2011) Marinus A. Bigi et al.   Nature Chemistry

Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

(2011) Irene Prat et al.   Nature Chemistry

Iron-Catalyzed Epoxidation of Aromatic Olefins and 1,3-Dienes

(2010) Kristin Schröder et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent advances in catalytic asymmetric epoxidation using the environmentally benign oxidant hydrogen peroxide and its derivatives

(2010) Giorgio De Faveri et al.   CHEMICAL SOCIETY REVIEWS

OlefinCis-Dihydroxylation with Bio-Inspired Iron Catalysts. Evidence for an FeII/FeIVCatalytic Cycle

(2010) Paul D. Oldenburg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

(2010) M. S. Chen et al.   SCIENCE

Shape-Selective Interception by Hydrocarbons of the O2-Derived Oxidant of a Biomimetic Nonheme Iron Complex

(2009) Anusree Mukherjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific CH Oxidation with H2O2Catalyzed by a Chemically Robust Site-Isolated Iron Catalyst

(2009) Laura Gómez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes

(2009) Paul R. Ortiz de Montellano   CHEMICAL REVIEWS

Olefin-Dependent Discrimination between Two Nonheme HOFeVO Tautomeric Species in Catalytic H2O2Epoxidations

(2009) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidation of Cyclohexane by High-Valent Iron Bispidine Complexes: Tetradentate versus Pentadentate Ligands

(2009) Peter Comba et al.   INORGANIC CHEMISTRY

Catalyst Stability Determines the Catalytic Activity of Non-Heme Iron Catalysts in the Oxidation of Alkanes

(2008) Jason England et al.   ADVANCED SYNTHESIS & CATALYSIS

Iron-Catalyzed Asymmetric Olefincis-Dihydroxylation with 97 % Enantiomeric Excess

(2008) Ken Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Oxidation. Asymmetric Epoxidation of Olefins Catalyzed by Chiral Ketones and Iminium Salts

(2008) O. Andrea Wong et al.   CHEMICAL REVIEWS

Biomimetic Iron-Catalyzed Asymmetric Epoxidation of Aromatic Alkenes by Using Hydrogen Peroxide

(2008) Feyissa Gadissa Gelalcha et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Novel Platform for Modeling Oxidative Catalysis in Non‐Heme Iron Oxygenases with Unprecedented Efficiency

(2008) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

High-valent iron-mediated cis-hydroxyacetoxylation of olefins

(2008) Ruben Mas-Balleste et al.   DALTON TRANSACTIONS

Epoxidation and 1,2-Dihydroxylation of Alkenes by a Nonheme Iron Model System − DFT Supports the Mechanism Proposed by Experiment

(2007) Peter Comba et al.   INORGANIC CHEMISTRY