Rhenium-Catalyzed Annulation Reactions

Rhenium(I)-Catalyzed Generation of α,β-Unsaturated Carbene Complex Intermediates from Propargyl Ethers for the Preparation of Cycloheptadiene Derivatives

(2016) Hideyuki Sogo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclobutenones and Benzocyclobutenones: Versatile Synthons in Organic Synthesis

(2016) Peng-hao Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh(III)-Catalyzed Redox-Neutral Annulation of Primary Benzamides with Diazo Compounds: Approach to Isoquinolinones

(2016) Youzhi Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

Potential of Metal-Catalyzed C–C Single Bond Cleavage for Organic Synthesis

(2016) Masahiro Murakami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of isoquinolines via Rh-catalyzed C–H activation/C–N cyclization with diazodiesters or diazoketoesters as a C2 source

(2016) Jie Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhenium-Catalyzed Synthesis of 1,3-Diiminoisoindolines via Insertion of Carbodiimides into a C–H Bond of Aromatic and Heteroaromatic Imidates

(2016) Zijia Wang et al.   ORGANIC LETTERS

Rhenium and base co-catalyzed [3 + 2] annulations of N–H ketimines and alkynes to access unprotected tertiary indenamines through C–H bond activation

(2016) Xiqing Jin et al.   Organic Chemistry Frontiers

Transition-Metal-Catalyzed Direct Addition of Unactivated C–H Bonds to Polar Unsaturated Bonds

(2015) Lei Yang et al.   CHEMICAL REVIEWS

Formal [4+1] Annulation Reactions in the Synthesis of Carbocyclic and Heterocyclic Systems

(2015) Jia-Rong Chen et al.   CHEMICAL REVIEWS

Recent Progress in Re-Catalyzed Dehydroxylation Reactions

(2015) Guoliang Mao et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Quinolinones with Palladium-Catalyzed Oxidative Annulation between Acrylamides and Arynes

(2015) Weiguo Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Pyridine N-Oxide vs Pyridine Substrates for Rh(III)-Catalyzed Oxidative C–H Bond Functionalization

(2015) Sharon R. Neufeldt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhenium-catalyzed C–H aminocarbonylation of azobenzenes with isocyanates

(2015) Xiaoyu Geng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhenium-catalyzed dehydrogenative olefination of C(sp3)–H bonds with hypervalent iodine(iii) reagents

(2015) Haidong Gu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhenium-Catalyzed [4 + 1] Annulation of Azobenzenes and Aldehydes via Isolable Cyclic Rhenium(I) Complexes

(2015) Xiaoyu Geng et al.   ORGANIC LETTERS

Direct silylation reactions of inert C-H bonds via transition metal catalysis

(2015) Yunhui Yang et al.   Science China-Chemistry

CO-enabled rhenium hydride catalyst for directed C(sp2)–H bond alkylation with olefins

(2015) Hongming Jin et al.   Organic Chemistry Frontiers

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

(2014) Ke Gao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Manganese-Catalyzed Dehydrogenative [4+2] Annulation of NH Imines and Alkynes by CH/NH Activation

(2014) Ruoyu He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed 1,2-Acyloxy Migration/Intramolecular [3+2] 1,3-Dipolar Cycloaddtion Cascade Reaction: An Efficient Strategy for Syntheses of Medium-Sized-Ring Ethers and Amines

(2014) Changgui Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Transition-Metal-Catalyzed Functionalization of Unstrained Carbon–Carbon Bonds

(2014) Feng Chen et al.   CHEMICAL REVIEWS

Meeting the Challenge of Intermolecular Gold(I)-Catalyzed Cycloadditions of Alkynes and Allenes

(2014) Michael E. Muratore et al.   Chemistry-An Asian Journal

Strain-Promoted Oxidative Annulation of Arynes and Cyclooctynes with Benzamides: Palladium-Catalyzed C–H/N–H Activation for the Synthesis of N-Heterocycles

(2014) Xianglong Peng et al.   ORGANIC LETTERS

Sequential Addition and Cyclization Processes of α,β-Ynones and α,β-Ynoates Containing Proximate Nucleophiles

(2014) Antonio Arcadi et al.   SYNTHESIS-STUTTGART

Isoquinoline skeleton synthesis via chelation-assisted C−H activation

(2014) Ruoyu He et al.   TETRAHEDRON LETTERS

Transition metal-catalyzed direct nucleophilic addition of C–H bonds to carbon–heteroatom double bonds

(2014) Xi-Sha Zhang et al.   Chemical Science

Direct activation of relatively unstrained carbon–carbon bonds in homogeneous systems

(2014) Alpay Dermenci et al.   Organic Chemistry Frontiers

Iron-catalyzed/mediated oxidative transformation of C–H bonds

(2014) Fan Jia et al.   Organic Chemistry Frontiers

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Roles of Bases in Transition-Metal Catalyzed Organic Reactions

(2013) Kunbing Ouyang et al.   ACTA CHIMICA SINICA

Nitrones as Trapping Reagents of α,β-Unsaturated Carbene Intermediates - [1,2]Oxazino[5,4-b]indoles by a Platinum- Catalyzed Intermolecular [3+3] Cycloaddition

(2013) Weibo Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium- and Platinum-Catalyzed [4+3] Cycloaddition with Concomitant Indole Annulation: Synthesis of Cyclohepta[b]indoles

(2013) Dongxu Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhenium-Catalyzed Synthesis of 3-Imino-1-isoindolinones by CH Bond Activation: Application to the Synthesis of Polyimide Derivatives

(2013) Shunsuke Sueki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold(I)-Catalysed Alkene Cycloaddition Reactions of Propargyl Acetals

(2013) Naseem Iqbal et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Indole Derivatives from 2-Alkynylanilines by Means of Gold Catalysis

(2013) Giorgio Abbiati et al.   ISRAEL JOURNAL OF CHEMISTRY

Performance of Density Functionals for Activation Energies of Re-Catalyzed Organic Reactions

(2013) Yihua Sun et al.   Journal of Chemical Theory and Computation

Re/Mg Bimetallic Tandem Catalysis for [4+2] Annulation of Benzamides and Alkynes via C-H/N-H Functionalization

(2013) Qiuzheng Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkene Oxyalkylation Enabled by Merging Rhenium Catalysis with Hypervalent Iodine(III) Reagents via Decarboxylation

(2013) Yin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[4+2] vs [3+2] Annulations in the Nickel- and Cobalt-Catalyzed Reaction ofortho-Haloimines with Alkynes: Differential Reactivity towards the Synthesis of Isoquinolines and Aminoindenes

(2013) Subramaniyan Mannathan et al.   JOURNAL OF THE CHINESE CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Manganese-Mediated C-C Bond Formation via C-H Activation: From Stoichiometry to Catalysis

(2013) Congyang Wang   SYNLETT

Rhenium-Catalyzed Acceptorless Dehydrogenative Coupling via Dual Activation of Alcohols and Carbonyl Compounds

(2013) Hongming Jin et al.   ACS Catalysis

Reductive Cleavage of the C sp 2C sp 3 Bond of Secondary Benzyl Alcohols: Rhodium Catalysis Directed by N-Containing Groups

(2012) Kang Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed CH Activation and Intermolecular Annulation with Allenes

(2012) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-catalysed synthesis of isoquinolinones and analogues via C–H and N–H bonds double activation

(2012) Hongban Zhong et al.   CHEMICAL COMMUNICATIONS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Gold(I)-Catalyzed Divergence in the Preparation of Bicyclic Enol Esters: From Exclusively [3C+2C]-Cycloaddition Reactions to Exclusive Formation of Vinylcyclopropanes

(2012) Ryan C. Conyers et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh-Catalyzed CC Cleavage of Benzyl/Allylic Alcohols to Produce Benzyl/Allylic Amines or other Alcohols by Nucleophilic Addition of Intermediate Rhodacycles to Aldehydes and Imines

(2012) Xi-Sha Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhenium-Catalyzed Regio- and Stereoselective Addition of Imines to Terminal Alkynes Leading to N-Alkylideneallylamines

(2012) Yoshiya Fukumoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

(2012) Bin Li et al.   ORGANIC LETTERS

Rhenium-Catalyzed Regioselective Synthesis of Multisubstituted Pyridines from β-Enamino Ketones and Alkynes via C–C Bond Cleavage

(2012) Shun-ichi Yamamoto et al.   ORGANIC LETTERS

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Strategies for Spiroketal Synthesis Based on Transition-Metal Catalysis

(2012) Aaron Aponick et al.   SYNTHESIS-STUTTGART

Recent Developments in Palladium-Catalyzed Formation of Five- and Six-Membered Fused Heterocycles

(2012) K. Majumdar et al.   SYNTHESIS-STUTTGART

Ruthenium-Catalyzed Oxidative Annulation by Cleavage of CH/NH Bonds

(2011) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-Catalyzed Isoquinolone Synthesis through CH Activation Using an Oxidizing Directing Group

(2011) Bin Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photochemical Preparation of Pyrimidin-2(1H)-ones by Rhenium(I) Complexes with Visible Light

(2011) Qiang Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Computational Elucidation of the Internal Oxidant-Controlled Reaction Pathways in Rh(III)-Catalyzed Aromatic C–H Functionalization

(2011) Liang Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Gold-Catalyzed Formal [3 + 3] and [4 + 2] Cycloaddition Reactions of Nitrosobenzenes with Alkenylgold Carbenoids

(2011) Vinayak Vishnu Pagar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridinyl Directed Alkenylation with Olefins via Rh(III)-Catalyzed C–C Bond Cleavage of Secondary Arylmethanols

(2011) Hu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhenium-Catalyzed Regiodivergent Addition of Indoles to Terminal Alkynes

(2011) Dexin Xia et al.   ORGANIC LETTERS

Oxidation and Amination of Benzylic sp3 C–H Bond Catalyzed by Rhenium(V) Complexes

(2011) Hao Peng et al.   ACS Catalysis

Gold-Catalyzed Cyclopenta- and Cycloheptannulation Cascades: A Stereocontrolled Approach to the Scaffold of Frondosins A and B

(2010) David Garayalde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Organic Reactions Catalyzed by Rhenium Carbonyl Complexes

(2010) Yoichiro Kuninobu et al.   CHEMICAL REVIEWS

Rhenium-catalyzed Regioselective Synthesis of Phenol Derivatives from 1,3-Diesters and Terminal Alkynes

(2010) Yoichiro Kuninobu et al.   CHEMISTRY LETTERS

Rhenium(I)-Catalyzed Cyclization of Silyl Enol Ethers Containing a Propargyl Carboxylate Moiety: Versatile Access to Highly Substituted Phenols

(2010) Kodai Saito et al.   CHEMISTRY-A EUROPEAN JOURNAL

Low-Valent Iron-Catalyzed C−C Bond Formation−Addition, Substitution, and C−H Bond Activation

(2010) Eiichi Nakamura et al.   JOURNAL OF ORGANIC CHEMISTRY

Pt-Catalyzed Tandem 1,2-Acyloxy Migration/Intramolecular [3 + 2] Cycloaddition of Enynyl Esters

(2010) Huaiji Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhenium-Catalyzed Synthesis of Indenones by Novel Dehydrative Trimerization of Aryl Aldehydes via C−H Bond Activation

(2010) Yoichiro Kuninobu et al.   ORGANIC LETTERS

Synthesis of β- and γ-Carbolinones via Pd-Catalyzed Direct Dehydrogenative Annulation (DDA) of Indole-carboxamides with Alkynes Using Air as the Oxidant

(2010) Zhuangzhi Shi et al.   ORGANIC LETTERS

Rhenium-Catalyzed Diastereoselective Synthesis of Aminoindanes via the Insertion of Allenes into a C−H Bond

(2010) Yoichiro Kuninobu et al.   ORGANIC LETTERS

Palladium- and Copper-Catalyzed Arylation of Carbon−Hydrogen Bonds

(2009) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed [3+3]-Annulation of Azomethine Imines with Propargyl Esters

(2009) Nathan D. Shapiro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Prenylation of Aromatic and α,β-Unsaturated Carboxamides via Iridium-Catalyzed C−H Oxidative Addition−Allene Insertion

(2009) Yong Jian Zhang et al.   ORGANIC LETTERS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Rhenium-Catalyzed Synthesis of Stereodefined Cyclopentenes from β-Ketoesters and Aliphatic Allenes

(2008) Salprima Yudha S. et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhenium- and manganese-catalyzed insertion of acetylenes into β-keto esters: synthesis of 2-pyranones

(2008) Yoichiro Kuninobu et al.   CHEMICAL COMMUNICATIONS

Synthesis of Cp−Re Complexes via Olefinic C−H Activation and Successive Formation of Cyclopentadienes

(2008) Yoichiro Kuninobu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Azepines by a Gold-Catalyzed Intermolecular [4 + 3]-Annulation

(2008) Nathan D. Shapiro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective synthesis of 4-aryl-3,4-dihydro-1,3,5-triazino[2,1-a]isoindol-2-ones

(2008) Angelina V. Biitseva et al.   MONATSHEFTE FUR CHEMIE

Rhenium-Catalyzed Synthesis of Multisubstituted Aromatic Compounds via C−C Single-Bond Cleavage

(2008) Yoichiro Kuninobu et al.   ORGANIC LETTERS

Nickel-catalyzed carbocyanation of alkynes

(2008) Yoshiaki Nakao et al.   PURE AND APPLIED CHEMISTRY

Catalytic reactions involving the cleavage of carbon–cyano and carbon–carbon triple bonds

(2007) Mamoru Tobisu et al.   CHEMICAL SOCIETY REVIEWS