Direct silylation reactions of inert C-H bonds via transition metal catalysis

Iridium-Catalyzed Regioselective Silylation of Aromatic and Benzylic CH Bonds Directed by a Secondary Amine

(2014) Qian Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of the Rhodium-Catalyzed Silylation of Arene C–H Bonds

(2014) Chen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Postsynthetic Metalation of Bipyridyl-Containing Metal–Organic Frameworks for Highly Efficient Catalytic Organic Transformations

(2014) Kuntal Manna et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Regioselective Silylation of Secondary Alkyl C–H Bonds for the Synthesis of 1,3-Diols

(2014) Bijie Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of 1-alkenes into 1,4-diols through an auxiliary-mediated formal homoallylic C–H oxidation

(2014) Nugzar Ghavtadze et al.   Nature Chemistry

Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol

(2014) C. Cheng et al.   SCIENCE

Anthranilamide-masked o-Iodoarylboronic Acids as Coupling Modules for Iterative Synthesis of ortho-Linked Oligoarenes

(2013) Masashi Koyanagi et al.   CHEMISTRY LETTERS

Iridium- and Rhodium-Catalyzed Dehydrogenative Silylations of C(sp3)H Bonds Adjacent to a Nitrogen Atom Using Hydrosilanes

(2013) Tsuyoshi Mita et al.   Chemistry-An Asian Journal

Hemilabile N-Xylyl-N′-methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage

(2013) Gyeongshin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aromatic C–H silylation of arenes with 1-hydrosilatrane catalyzed by an iridium(i)/2,9-dimethylphenanthroline (dmphen) complex

(2013) Tatsuo Ishiyama et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Fused Heteroaromatic Dihydrosiloles: Synthesis and Double-Fold Modification

(2013) Alexey Kuznetsov et al.   ORGANIC LETTERS

Rhodium-Catalyzed Intramolecular Silylation of Unactivated C(sp3)–H Bonds

(2013) Yoichiro Kuninobu et al.   ORGANIC LETTERS

Manganese-Mediated C-C Bond Formation via C-H Activation: From Stoichiometry to Catalysis

(2013) Congyang Wang   SYNLETT

Palladium-catalyzed cleavage of the Me–Si bond in ortho-trimethylsilyl aryltriflates: synthesis of benzosilole derivatives from ortho-trimethylsilyl aryltriflates and alkynes

(2013) Tianhao Meng et al.   RSC Advances

Palladium-Catalyzed Intermolecular Coupling of 2-Silylaryl Bromides with Alkynes: Synthesis of Benzosiloles and Heteroarene-Fused Siloles by Catalytic Cleavage of the C(sp3)Si Bond

(2012) Yun Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives

(2012) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Easy Access toL-Mannosides andL-Galactosides by Using CH Activation of the Corresponding 6-Deoxysugars

(2012) Tobias Gylling Frihed et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-catalyzed Ortho-selective Aromatic C–H Silylation: Acceptorless Dehydrogenative Coupling of Hydrosilanes

(2012) Toru Sakurai et al.   CHEMISTRY LETTERS

Rhodium-Catalyzed Carbon–Silicon Bond Activation for Synthesis of Benzosilole Derivatives

(2012) Masahiro Onoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

(2012) Eric M. Simmons et al.   NATURE

Disila-analogues of the synthetic retinoids EC23 and TTNN: synthesis, structure and biological evaluation

(2012) Josef B. G. Gluyas et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Sequential Protocol for C(sp3)–H Carboxylation with CO2: Transition-Metal-Catalyzed Benzylic C–H Silylation and Fluoride-Mediated Carboxylation

(2012) Tsuyoshi Mita et al.   ORGANIC LETTERS

General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes

(2012) Alexey Kuznetsov et al.   ORGANIC LETTERS

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Scandium-Catalyzed Silylation of Aromatic CH Bonds

(2011) Juzo Oyamada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights

(2011) Alison E. Wendlandt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-catalyzed C–H Silylation of Methylboronic Acid Using a Removable α-Directing Modifier on the Boron Atom

(2011) Hideki Ihara et al.   CHEMISTRY LETTERS

Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism

(2011) Hendrik F. T. Klare et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Synthesis of Benzosilolo[2,3-b]indoles via Cleavage of a C(sp3)–Si Bond and Consequent Intramolecular C(sp2)–Si Coupling

(2011) Yun Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Allylic C−H Silylation

(2011) Johanna M. Larsson et al.   ORGANIC LETTERS

Cobalt-Catalyzed, Chelation-Assisted C-H Bond Functionalization

(2011) Naohiko Yoshikai   SYNLETT

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Iridium-Catalyzed (Z)-Trialkylsilylation of Terminal Olefins

(2010) Biao Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Low-Valent Iron-Catalyzed C−C Bond Formation−Addition, Substitution, and C−H Bond Activation

(2010) Eiichi Nakamura et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Synthesis of Silafluorene Derivatives via Cleavage of Silicon−Hydrogen and Carbon−Hydrogen Bonds

(2010) Tomonari Ureshino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed AreneOrtho-Silylation by Formal Hydroxyl-Directed C−H Activation

(2010) Eric M. Simmons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlled Iterative Cross-Coupling: On the Way to the Automation of Organic Synthesis

(2009) Congyang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Selective Dehydrogenative Silylation of Alkenes Catalyzed by Rhenium Complexes

(2009) Yanfeng Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Easily Attachable and Detachableortho-Directing Agent for Arylboronic Acids in Ruthenium-Catalyzed Aromatic C−H Silylation

(2009) Hideki Ihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Efficient Iridium-Catalyzed CH Functionalization/Silylation of Heteroarenes

(2008) Biao Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Silylation of Aromatic Carbon-Hydrogen Bonds in 2-Arylpyridines with Disilane

(2008) Mamoru Tobisu et al.   Chemistry-An Asian Journal

A New Design Strategy for Organic Optoelectronic Materials by Lateral Boryl Substitution

(2007) Mark Elbing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION