What Wanzlick Did Not Dare To Dream: Cyclic (Alkyl)(amino)carbenes (cAACs) as New Key Players in Transition-Metal Chemistry

An N-Heterocyclic Carbene-Nickel Half-Sandwich Complex as a Precatalyst for Suzuki–Miyaura Coupling of Aryl/Heteroaryl Halides with Aryl/Heteroarylboronic Acids

(2017) Shin Ando et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis and Reactivity of Cyclic (Alkyl)(Amino)Carbene Stabilized Nickel Carbonyl Complexes

(2017) Ursula S. D. Paul et al.   ORGANOMETALLICS

Nickel(II) Complexes of Highly σ-Donating Cyclic (Alkyl)(Amino)- and Malonate-Carbenes: Syntheses and Catalytic Studies

(2017) Mickaël Henrion et al.   ORGANOMETALLICS

Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature

(2016) Sudipta Roy et al.   ACCOUNTS OF CHEMICAL RESEARCH

Adduct Formation, B−H Activation and Ring Expansion at Room Temperature from Reactions of HBcat with NHCs

(2016) Sabrina Würtemberger-Pietsch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclic (Alkyl)(Amino)Carbene Complexes of Rhodium and Nickel and Their Steric and Electronic Parameters

(2016) Ursula S. D. Paul et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation

(2016) Zoë R. Turner   CHEMISTRY-A EUROPEAN JOURNAL

Generalization of the Copper to Late-Transition-Metal Transmetallation to Carbenes beyond N-Heterocyclic Carbenes

(2016) Yannick D. Bidal et al.   CHEMISTRY-A EUROPEAN JOURNAL

25 years of N-heterocyclic carbenes: activation of both main-group element–element bonds and NHCs themselves

(2016) Sabrina Würtemberger-Pietsch et al.   DALTON TRANSACTIONS

[CpArNi{Ga(nacnac)}]: An Open-Shell Nickel(I) Complex Supported by a Gallium(I) Carbenoid (CpAr = C5(C6H4-4-Et)5, nacnac = HC[C(Me)N-(C6H3)-2,6-iPr2]2)

(2016) Uttam Chakraborty et al.   INORGANIC CHEMISTRY

Pentaarylcyclopentadienyl Iron, Cobalt, and Nickel Halides

(2016) Uttam Chakraborty et al.   INORGANIC CHEMISTRY

NHC Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions of Aryl Boronate Esters with Perfluorobenzenes

(2016) Jing Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Preparing (Multi)Fluoroarenes as Building Blocks for Synthesis: Nickel-Catalyzed Borylation of Polyfluoroarenes via C–F Bond Cleavage

(2016) Jing Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Hemilabile Cyclic (Alkyl)(amino)carbenes (CAACs) and Applications in Organometallic Chemistry

(2016) Jiaxiang Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Neutral zero-valent s-block complexes with strong multiple bonding

(2016) Merle Arrowsmith et al.   Nature Chemistry

Accessing the CpArNi(I) Synthon: Reactions with N-Heterocyclic Carbenes, TEMPO, Sulfur, and Selenium

(2016) Uttam Chakraborty et al.   ORGANOMETALLICS

Synthesis and Thermal Properties of Novel NHC-Stabilized Cobalt Carbonyl Nitrosyl Complexes

(2016) Florian Hering et al.   ORGANOMETALLICS

Reaction of Phenyl Iso(thio)cyanate with N-Heterocyclic Carbene-Supported Nickel Complexes: Formation of Nickelacycles

(2016) Stefan Pelties et al.   ORGANOMETALLICS

Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals

(2015) Bin Rao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

(2015) Darrin M. Flanigan et al.   CHEMICAL REVIEWS

Synthesis, Characterization, and Theoretical Investigation of Two-Coordinate Palladium(0) and Platinum(0) Complexes Utilizing π-Accepting Carbenes

(2015) Sudipta Roy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical

(2015) Steffen Styra et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organometallic Probe for the Electronics of Base-Stabilized Group 11 Metal Cations

(2015) Holger Braunschweig et al.   CHEMISTRY-A EUROPEAN JOURNAL

Correlations and Contrasts in Homo- and Heteroleptic Cyclic (Alkyl)(amino)carbene-Containing Pt0Complexes

(2015) Nicole Arnold et al.   CHEMISTRY-A EUROPEAN JOURNAL

General and Mild Ni0-Catalyzed α-Arylation of Ketones Using Aryl Chlorides

(2015) José A. Fernández-Salas et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, Structures and Properties of Half-Sandwich Nickel(II) Complexes with Backbone-Modified NHC Ligands

(2015) Łukasz Banach et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Determining the Ligand Properties of N-Heterocyclic Carbenes from77Se NMR Parameters

(2015) Kathrin Verlinden et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cr(i)Cl as well as Cr+ are stabilised between two cyclic alkyl amino carbenes

(2015) Prinson P. Samuel et al.   Chemical Science

What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

(2015) Sai V. C. Vummaleti et al.   Chemical Science

Isolation of bis(copper) key intermediates in Cu-catalyzed azide-alkyne "click reaction"

(2015) L. Jin et al.   Science Advances

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

Trinuclear Gold Clusters Supported by Cyclic (alkyl)(amino)carbene Ligands: Mimics for Gold Heterogeneous Catalysts

(2014) Liqun Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C4Cumulene and the Corresponding Air-Stable Radical Cation and Dication

(2014) Yan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Complexes as Remarkably Active Catalysts for Ethenolysis

(2014) Vanessa M. Marx et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene

(2014) Philipp Bissinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes

(2014) Fatme Dahcheh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Two-Coordinate Fe0and Co0Complexes Supported by Cyclic (alkyl)(amino)carbenes

(2014) Gaël Ung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From acetone metalation to the catalytic α-arylation of acyclic ketones with NHC–nickel(ii) complexes

(2014) Mickaël Henrion et al.   CHEMICAL COMMUNICATIONS

Selective P4 activation by an organometallic nickel(i) radical: formation of a dinuclear nickel(ii) tetraphosphide and related di- and trichalcogenides

(2014) Stefan Pelties et al.   CHEMICAL COMMUNICATIONS

Stabilization of a Two-Coordinate Mononuclear Cobalt(0) Compound

(2014) Kartik Chandra Mondal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel(I) Monomers and Dimers with Cyclopentadienyl and Indenyl Ligands

(2014) Jianguo Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Catalyst with Two-Coordinate Nickel: Theoretical and Catalytic Studies

(2014) Kartik Chandra Mondal et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Efficient C-N and C-S Bond Formation Using the Highly Active [Ni(allyl)Cl(IPr*OMe)] Precatalyst

(2014) Anthony R. Martin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Electronic Structure and Slow Magnetic Relaxation of Low-Coordinate Cyclic Alkyl(amino) Carbene Stabilized Iron(I) Complexes

(2014) Prinson P. Samuel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coinage Metals Binding as Main Group Elements: Structure and Bonding of the Carbene Complexes [TM(cAAC)2] and [TM(cAAC)2]+ (TM = Cu, Ag, Au)

(2014) Paul Jerabek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes

(2014) David S. Weinberger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stabilization of a Cobalt–Cobalt Bond by Two Cyclic Alkyl Amino Carbenes

(2014) Kartik Chandra Mondal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploring the Coordination of Cyclic Selenoureas to Gold(I)

(2014) David J. Nelson et al.   ORGANOMETALLICS

Methoxy-Functionalized N-Heterocyclic Carbenes

(2014) David J. Nelson et al.   ORGANOMETALLICS

Two- and three-coordinate formal iron(i) compounds featuring monodentate aminocarbene ligands

(2014) Zhenbo Mo et al.   Organic Chemistry Frontiers

Singlet carbenes as mimics for transition metals: synthesis of an air stable organic mixed valence compound [M2(C2)+˙; M = cyclic(alkyl)(amino)carbene]

(2014) Liqun Jin et al.   Organic Chemistry Frontiers

Isolation of Neutral Mono- and Dinuclear Gold Complexes of Cyclic (Alkyl)(amino)carbenes

(2013) David S. Weinberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature

(2013) Prinson P. Samuel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

β- and α-Hydride Abstraction in Gold(I) Alkyl Complexes

(2013) Gaël Ung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-catalyzed olefin metathesis accelerated by the steric effect of the backbone substituent in cyclic (alkyl)(amino) carbenes

(2013) Jun Zhang et al.   CHEMICAL COMMUNICATIONS

Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters

(2013) Caleb D. Martin et al.   CHEMICAL COMMUNICATIONS

Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

(2013) Roberta R. Rodrigues et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic carbenes (NHCs) as organocatalysts and structural components in metal-free polymer synthesis

(2013) Maréva Fèvre et al.   CHEMICAL SOCIETY REVIEWS

Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts

(2013) Fu-She Han   CHEMICAL SOCIETY REVIEWS

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Are β-H-Eliminations or Alkene Insertions Feasible Elementary Steps in Catalytic Cycles Involving Gold(I) Alkyl Species or Gold(I) Hydrides?

(2013) Günter Klatt et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Heterocyclic carbenes

(2013) Catherine S. J. Cazin   DALTON TRANSACTIONS

A Singlet Biradicaloid Zinc Compound and Its Nonradical Counterpart

(2013) Amit Pratap Singh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

(2013) Janell K. Mahoney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Properties, and Reactivity of Palladium and Nickel NHC Complexes Supported by Combinations of Allyl, Cyclopentadienyl, and Indenyl Ligands

(2013) Elizabeth A. Bielinski et al.   ORGANOMETALLICS

Enhanced Activity of [Ni(NHC)CpCl] Complexes in Arylamination Catalysis

(2013) Anthony R. Martin et al.   ORGANOMETALLICS

Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77Se NMR Chemical Shifts of Their Selenium Adducts

(2013) Annika Liske et al.   ORGANOMETALLICS

Stable Carbenes: From ‘Laboratory Curiosities' to Catalysis Mainstays

(2013) Tomislav Rovis et al.   SYNLETT

Iron(II), Cobalt(II), and Nickel(II) Complexes of a Cyclic (Alkyl)(amino)carbene

(2013) Stefan Pelties et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

Hydrosilylation of Aldehydes and Ketones Catalyzed by an N-Heterocyclic Carbene-Nickel Hydride Complex under Mild Conditions

(2012) Linus P. Bheeter et al.   ADVANCED SYNTHESIS & CATALYSIS

Conversion of a Singlet Silylene to a stable Biradical

(2012) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolated Silver Intermediate of Gold Precatalyst Activation

(2012) Simone G. Weber et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Kumada–Tamao–Corriu Coupling of Heteroaromatic Chlorides and Aryl Ethers Catalyzed by (IPr)Ni(allyl)Cl

(2012) María José Iglesias et al.   ORGANIC LETTERS

Synthesis and Catalytic Activity in Suzuki Coupling of Nickel Complexes Bearing n-Butyl- and Triethoxysilylpropyl-Substituted NHC Ligands: Toward the Heterogenization of Molecular Catalysts

(2012) Anna Magdalena Oertel et al.   ORGANOMETALLICS

Decisive Steps of the Hydrodefluorination of Fluoroaromatics using [Ni(NHC)2]

(2012) Peter Fischer et al.   ORGANOMETALLICS

Gold-Catalyzed Hydroamination of Alkynes and Allenes with Parent Hydrazine

(2011) Rei Kinjo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Consecutive C-F Bond Activation of Hexafluorobenzene and Decafluorobiphenyl

(2011) Thomas Schaub et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Stoichiometric and catalytic C–Cl activation of Aryl Chlorides using an NHC-stabilized nickel(0) complex

(2011) Thomas Zell et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Probing the Origin of Degenerate Metathesis Selectivity via Characterization and Dynamics of Ruthenacyclobutanes Containing Variable NHCs

(2011) Benjamin K. Keitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Development and Catalytic Uses of N-Heterocyclic Carbene Gold Complexes

(2010) Steven P. Nolan   ACCOUNTS OF CHEMICAL RESEARCH

Well-Defined Allylnickel Chloride/N-Heterocyclic Carbene [(NHC)Ni(allyl)Cl] Complexes as Highly Active Precatalysts for CN and CS Cross-Coupling Reactions

(2010) María José Iglesias et al.   ADVANCED SYNTHESIS & CATALYSIS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Serendipitous Discovery of the Catalytic Hydroammoniumation and Methylamination of Alkynes

(2010) Xiaoming Zeng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homogeneous Gold Catalysis Beyond Assumptions and Proposals-Characterized Intermediates

(2010) A. Stephen K. Hashmi   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of a Carbene-Stabilized Phosphorus Mononitride and Its Radical Cation (PN+.)

(2010) Rei Kinjo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Organometallic Reactions of Ammonia

(2010) Jessica L. Klinkenberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

Cross coupling reactions of polyfluoroarenes via C–F activation

(2010) Alex D. Sun et al.   DALTON TRANSACTIONS

A Crystalline Phosphinyl Radical Cation

(2010) Olivier Back et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications

(2010) Olivier Back et al.   Nature Chemistry

Nonmetal-Mediated Fragmentation of P4: Isolation of P1and P2Bis(carbene) Adducts

(2009) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

(2009) Macarena Poyatos et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

A Cationic Gold(I) Complex as a General Catalyst for the Intermolecular Hydroamination of Alkynes: Application to the One-Pot Synthesis of Allenes from Two Alkynes and a Sacrificial Amine

(2009) Xiaoming Zeng et al.   CHEMISTRY-A EUROPEAN JOURNAL

SambVca: A Web Application for the Calculation of the Buried Volume of N-Heterocyclic Carbene Ligands

(2009) Albert Poater et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives

(2009) Xiaoming Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Intermolecular Markovnikov Hydroamination of Allenes with Secondary Amines

(2009) Xiaoming Zeng et al.   ORGANIC LETTERS

13C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II)

(2009) Han Vinh Huynh et al.   ORGANOMETALLICS

Homogeneous Catalytic Hydroamination of Alkynes and Allenes with Ammonia

(2008) Vincent Lavallo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand Effects in Homogeneous Au Catalysis

(2008) David J. Gorin et al.   CHEMICAL REVIEWS

N-Heterocyclic carbenes in gold catalysis

(2008) Nicolas Marion et al.   CHEMICAL SOCIETY REVIEWS

Carbenes: Synthesis, properties, and organometallic chemistry

(2008) Pierre de Frémont et al.   COORDINATION CHEMISTRY REVIEWS

Square-Planar (Pentafluorophenyl)nickel(II) Complexes by Derivatization of a C–F Activation Product

(2008) Thomas Schaub et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cyclic (alkyl)(amino)carbene gold(I) complexes: A synthetic and structural investigation

(2008) Guido D. Frey et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands

(2008) Stefanie Wolf et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations

(2008) Thomas Schaub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Selectivity of Olefin Metathesis Catalysts Bearing Cyclic (Alkyl)(Amino)Carbenes

(2008) Donde R. Anderson et al.   ORGANOMETALLICS

Gold-catalyzed hydrofunctionalization of allenes with nitrogen and oxygen nucleophiles and its mechanistic insight

(2008) Naoko Nishina et al.   TETRAHEDRON

Recent developments in gold catalysis

(2008) Fabien Gagosz   TETRAHEDRON

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System

(2007) Roy A. Kelly III et al.   ORGANOMETALLICS