Determining the Ligand Properties of N-Heterocyclic Carbenes from77Se NMR Parameters

What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

(2015) Sai V. C. Vummaleti et al.   Chemical Science

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Exploring the Coordination of Cyclic Selenoureas to Gold(I)

(2014) David J. Nelson et al.   ORGANOMETALLICS

Methoxy-Functionalized N-Heterocyclic Carbenes

(2014) David J. Nelson et al.   ORGANOMETALLICS

1JCH couplings in Group 14/IVA tetramethyls from the gas-phase NMR and DFT structural study: a search for the best computational protocol

(2014) Ryszard B. Nazarski et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Relativistic effects on the 125Te and 33S NMR chemical shifts of various tellurium and sulfur species, together with 77Se of selenium congeners, in the framework of a zeroth-order regular approximation: applicability to tellurium compounds

(2014) Satoko Hayashi et al.   RSC Advances

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tuning the electronic properties of an N-heterocyclic carbene by charge and mesomeric effects

(2013) Hannes Buhl et al.   CHEMICAL COMMUNICATIONS

Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

(2013) Roberta R. Rodrigues et al.   CHEMICAL COMMUNICATIONS

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Inhibition of Lactoperoxidase-Catalyzed Oxidation by Imidazole-Based Thiones and Selones: A Mechanistic Study

(2013) Gouriprasanna Roy et al.   Chemistry-An Asian Journal

Converting a perimidine derivative to a cationic N-heterocyclic carbene

(2013) Kathrin Verlinden et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Gold and Palladium Hetero-Bis-NHC Complexes: Characterizations, Correlations, and Ligand Redistributions

(2013) Shuai Guo et al.   ORGANOMETALLICS

Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77Se NMR Chemical Shifts of Their Selenium Adducts

(2013) Annika Liske et al.   ORGANOMETALLICS

Synthesis and Application of Water-Soluble NHC Transition-Metal Complexes

(2012) Lars-Arne Schaper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Diaminocarbene with a Pyramidalized Nitrogen Atom: A Stable N-Heterocyclic Carbene with Enhanced Electrophilicity

(2012) David Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-PEPPSI-IPentCl: A Highly Effective Catalyst for the Selective Cross-Coupling of Secondary Organozinc Reagents

(2012) Matthew Pompeo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding the Chemistry of CationicN-Heterocyclic Carbenes: Alternative Synthesis, Reactivity, and Coordination Chemistry

(2012) Björn Hildebrandt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents

(2012) Jonathan P. Moerdyk et al.   Nature Chemistry

Tuning the Electronic Properties of Carbenes: A Systematic Comparison of Neighboring Amino versus Amido Groups

(2012) Garrett A. Blake et al.   ORGANOMETALLICS

Diamino- and Mixed Amino–Amido-N-Heterocyclic Carbenes Based on Triazine Backbones

(2012) Abdelaziz Makhloufi et al.   ORGANOMETALLICS

Reactivity of an Oxalamide-Based N-Heterocyclic Carbene

(2012) Markus Braun et al.   ORGANOMETALLICS

Converting Caffeine to Electronically Different N-Heterocyclic Carbenes with a Hypoxanthine Backbone

(2012) Abdelaziz Makhloufi et al.   ORGANOMETALLICS

Synthetic Routes to N-Heterocyclic Carbene Precursors

(2011) Laure Benhamou et al.   CHEMICAL REVIEWS

A Family of Thiazolium Salt Derived N-Heterocyclic Carbenes (NHCs) for Organocatalysis: Synthesis, Investigation and Application in Cross-Benzoin Condensation

(2011) Isabel Piel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Cationic N-Heterocyclic Carbene with an Organometallic Backbone: Synthesis and Reactivity

(2011) Björn Hildebrandt et al.   ORGANOMETALLICS

A Brief Survey of Our Contribution to Stable Carbene Chemistry

(2011) David Martin et al.   ORGANOMETALLICS

Is the1JPSeCoupling Constant a Reliable Probe for the Basicity of Phosphines? A31P NMR Study

(2011) Udo Beckmann et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

Cationic rhodium(I) and iridium(I) α-diimine complexes

(2011) Duncan A.J. Harding et al.   POLYHEDRON

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Steering the Surprisingly Modular π-Acceptor Properties of N-Heterocyclic Carbenes: Implications for Gold Catalysis

(2010) Manuel Alcarazo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The influence of electron delocalization upon the stability and structure of potential N-heterocyclic carbene precursors with 1,3-diaryl-imidazolidine-4,5-dione skeletons

(2010) Matthew G. Hobbs et al.   NEW JOURNAL OF CHEMISTRY

Facile Derivatization of a “Chemo-active” NHC Incorporating an Enolate Backbone and Relevant Tuning of Its Electronic Properties

(2010) Laure Benhamou et al.   ORGANOMETALLICS

An N-Heterocyclic Carbene Ligand with an Oxalamide Backbone

(2010) Markus Braun et al.   ORGANOMETALLICS

N-heterocyclic carbenes which readily add ammonia, carbon monoxide and other small molecules,

(2010) Ulrich Siemeling et al.   Chemical Science

Imidazol-2-ylidene-4-olate: an anionic N-heterocyclic carbene pre-programmed for further derivatization

(2009) Laure Benhamou et al.   CHEMICAL COMMUNICATIONS

Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

(2009) Macarena Poyatos et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Theoretical Analysis of Bonding in N-Heterocyclic Carbene−Rhodium Complexes

(2009) Monika Srebro et al.   INORGANIC CHEMISTRY

AnN,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

(2009) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electronic and Steric Parameters of 76 N-Heterocyclic Carbenes in Ni(CO)3(NHC)

(2009) Dmitry G. Gusev   ORGANOMETALLICS

13C NMR Spectroscopic Determination of Ligand Donor Strengths Using N-Heterocyclic Carbene Complexes of Palladium(II)

(2009) Han Vinh Huynh et al.   ORGANOMETALLICS

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Understanding the M(NHC) (NHC=N-heterocyclic carbene) bond

(2008) Heiko Jacobsen et al.   COORDINATION CHEMISTRY REVIEWS

N-Heterocyclic Carbenes with Inorganic Backbones:  Electronic Structures and Ligand Properties

(2008) Anna Kausamo et al.   INORGANIC CHEMISTRY

Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands

(2008) Stefanie Wolf et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Novel Expanded Ring N-Heterocyclic Carbenes: Free Carbenes, Silver Complexes, And Structures

(2008) Manuel Iglesias et al.   ORGANOMETALLICS

Rapid phosphorus(iii) ligand evaluation utilising potassium selenocyanate

(2007) Alfred Muller et al.   DALTON TRANSACTIONS

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System

(2007) Roy A. Kelly III et al.   ORGANOMETALLICS