Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical

What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

(2015) Sai V. C. Vummaleti et al.   Chemical Science

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

C4Cumulene and the Corresponding Air-Stable Radical Cation and Dication

(2014) Yan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evidence for Extensive Single-Electron-Transfer Chemistry in Boryl Anions: Isolation and Reactivity of a Neutral Borole Radical

(2014) Rüdiger Bertermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of a Neutral Boron-Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene

(2014) Philipp Bissinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron as a Powerful Reductant: Synthesis of a Stable Boron-Centered Radical-Anion Radical-Cation Pair

(2014) Philipp Bissinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron Radical Cations from the Facile Oxidation of Electron-Rich Diborenes

(2014) Philipp Bissinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes

(2014) Fatme Dahcheh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Two-Coordinate Fe0and Co0Complexes Supported by Cyclic (alkyl)(amino)carbenes

(2014) Gaël Ung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Characterization of a Triphenyl-Substituted Radical and an Unprecedented Formation of a Carbene-Functionalized Quinodimethane

(2014) Kartik Chandra Mondal et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Catalyst with Two-Coordinate Nickel: Theoretical and Catalytic Studies

(2014) Kartik Chandra Mondal et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes

(2014) David S. Weinberger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stabilization of a Cobalt–Cobalt Bond by Two Cyclic Alkyl Amino Carbenes

(2014) Kartik Chandra Mondal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Singlet carbenes as mimics for transition metals: synthesis of an air stable organic mixed valence compound [M2(C2)+˙; M = cyclic(alkyl)(amino)carbene]

(2014) Liqun Jin et al.   Organic Chemistry Frontiers

Formation of Trichlorosilyl-Substituted Carbon-Centered Stable Radicals through the Use of π-Accepting Carbenes

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of Neutral Mono- and Dinuclear Gold Complexes of Cyclic (Alkyl)(amino)carbenes

(2013) David S. Weinberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature

(2013) Prinson P. Samuel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions

(2013) Moritz F. Kuehnel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphaalkene vs. phosphinidene: the nature of the P–C bond in carbonyl-decorated carbene → PPh adducts

(2013) Roberta R. Rodrigues et al.   CHEMICAL COMMUNICATIONS

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Oxidative Addition Versus Substitution Reactions of Group 14 Dialkylamino Metalylenes with Pentafluoropyridine

(2013) Prinson P. Samuel et al.   INORGANIC CHEMISTRY

A Singlet Biradicaloid Zinc Compound and Its Nonradical Counterpart

(2013) Amit Pratap Singh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

(2013) Janell K. Mahoney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of Carbene-Stabilized Diarsenic: Diarsene Dications and Diarsenic Radical Cations

(2013) Mariham Y. Abraham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77Se NMR Chemical Shifts of Their Selenium Adducts

(2013) Annika Liske et al.   ORGANOMETALLICS

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

Conversion of a Singlet Silylene to a stable Biradical

(2012) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel fluoro complexes as intermediates in catalytic cross-coupling reactions

(2012) David Breyer et al.   JOURNAL OF FLUORINE CHEMISTRY

Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)(iPr2PCH2CH2OCH3)2]: C–F Bond Formation and Catalytic C–F Bond Activation Reactions

(2012) David Breyer et al.   ORGANOMETALLICS

Bond Activation with an Apparently Benign Ethynyl Dithiocarbamate ArCCSC(S)NR2

(2011) Gaël Ung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Brief Survey of Our Contribution to Stable Carbene Chemistry

(2011) David Martin et al.   ORGANOMETALLICS

Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines

(2011) R. Kinjo et al.   SCIENCE

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon

(2010) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Crystalline Phosphinyl Radical Cation

(2010) Olivier Back et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications

(2010) Olivier Back et al.   Nature Chemistry

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Carbenes Introduction

(2009) Anthony J. Arduengo et al.   CHEMICAL REVIEWS

Aromatic C–F activation by complexes containing the {Pt2S2} core via nucleophilic substitution: a combined experimental and theoretical study

(2009) Ainara Nova et al.   DALTON TRANSACTIONS

Synthesis and Reactivity of Ru(NHC)(dppp)(CO)H2and Ru(NHC)(dppp)(CO)HF Complexes: C-H and C-F Activation

(2009) Steven P. Reade et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION