Chemically Non-Innocent Cyclic (Alkyl)(Amino)Carbenes: Ligand Rearrangement, C−H and C−F Bond Activation

Cyclic Alkyl(amino) Carbene Stabilized Complexes with Low Coordinate Metals of Enduring Nature

(2016) Sudipta Roy et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Triatomic Silicon(0) Cluster Stabilized by a Cyclic Alkyl(amino) Carbene

(2016) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

25 years of N-heterocyclic carbenes: activation of both main-group element–element bonds and NHCs themselves

(2016) Sabrina Würtemberger-Pietsch et al.   DALTON TRANSACTIONS

Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir–η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion

(2016) Liu Liu et al.   Chemical Science

Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent Hydrodefluorination

(2015) Jiangtao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

“Decarbonization” of an imino-N-heterocyclic carbene ligand via triple benzyl migration from hafnium

(2015) Dipesh Prema et al.   CHEMICAL COMMUNICATIONS

Synthesis, Characterization, and Theoretical Investigation of Two-Coordinate Palladium(0) and Platinum(0) Complexes Utilizing π-Accepting Carbenes

(2015) Sudipta Roy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Crystalline Cyclic (Alkyl)(amino)carbene-tetrafluoropyridyl Radical

(2015) Steffen Styra et al.   CHEMISTRY-A EUROPEAN JOURNAL

Group 1 and 2 cyclic (alkyl)(amino)carbene complexes

(2015) Zoë R. Turner et al.   DALTON TRANSACTIONS

Air-Persistent Monomeric (Amino)(carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

(2015) Janell K. Mahoney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbene Supported Dimer of Heavier Ketenimine Analogue with P and Si Atoms

(2015) Sudipta Roy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bonding Analysis of TM(cAAC)2 (TM = Cu, Ag, and Au) and the Importance of Reference State

(2015) Clark R. Landis et al.   ORGANOMETALLICS

Activation of N-Heterocyclic Carbenes by {BeH2} and {Be(H)(Me)} Fragments

(2015) Merle Arrowsmith et al.   ORGANOMETALLICS

Reactions of imidazol(in)-2-ylidenes with electron deficient fluoroolefins

(2015) Anthony J. Arduengo et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

Cr(i)Cl as well as Cr+ are stabilised between two cyclic alkyl amino carbenes

(2015) Prinson P. Samuel et al.   Chemical Science

Intramolecular C–H insertion vs. Friedel–Crafts coupling induced by silyl cation-promoted C–F activation

(2015) Oliver Allemann et al.   Organic Chemistry Frontiers

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

Coupling of an N-Heterocyclic Carbene on Iron with Alkynes to Form η5-Cyclopentadienyl-Diimine Ligands

(2014) Tsubasa Hatanaka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Reactivity of a CAAC-Aminoborylene Adduct: A Hetero-Allene or an Organoboron Isoelectronic with Singlet Carbenes

(2014) Fatme Dahcheh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Two-Coordinate Fe0and Co0Complexes Supported by Cyclic (alkyl)(amino)carbenes

(2014) Gaël Ung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reductive generation of stable, five-membered N,N′-diamidocarbenes

(2014) Jonathan P. Moerdyk et al.   CHEMICAL COMMUNICATIONS

Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

(2014) Theresia Ahrens et al.   CHEMICAL REVIEWS

Stabilization of a Two-Coordinate Mononuclear Cobalt(0) Compound

(2014) Kartik Chandra Mondal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene-9-BBN Ring Expansions as a Route to Intramolecular Frustrated Lewis Pairs for CO2Reduction

(2014) Tongen Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Catalyst with Two-Coordinate Nickel: Theoretical and Catalytic Studies

(2014) Kartik Chandra Mondal et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Coinage Metals Binding as Main Group Elements: Structure and Bonding of the Carbene Complexes [TM(cAAC)2] and [TM(cAAC)2]+ (TM = Cu, Ag, Au)

(2014) Paul Jerabek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of Neutral Mononuclear Copper Complexes Stabilized by Two Cyclic (Alkyl)(amino)carbenes

(2014) David S. Weinberger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbene-Dichlorosilylene Stabilized Phosphinidenes Exhibiting Strong Intramolecular Charge Transfer Transition

(2014) Sudipta Roy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–F activation and functionalization of perfluoro- and polyfluoroarenes

(2014) Jimmie Weaver et al.   TETRAHEDRON

Singlet carbenes as mimics for transition metals: synthesis of an air stable organic mixed valence compound [M2(C2)+˙; M = cyclic(alkyl)(amino)carbene]

(2014) Liqun Jin et al.   Organic Chemistry Frontiers

Isolation of Neutral Mono- and Dinuclear Gold Complexes of Cyclic (Alkyl)(amino)carbenes

(2013) David S. Weinberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature

(2013) Prinson P. Samuel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC to aNHC rearrangement by an organotin sulphide cation

(2013) Michael Wagner et al.   CHEMICAL COMMUNICATIONS

Metal free and selective activation of one C–F bond in a bound CF3 group

(2013) Ramachandran Azhakar et al.   CHEMICAL COMMUNICATIONS

N,N′-Diamidocarbenes Facilitate Selective CH Insertions and Transfer Hydrogenations

(2013) Jonathan P. Moerdyk et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Addition Versus Substitution Reactions of Group 14 Dialkylamino Metalylenes with Pentafluoropyridine

(2013) Prinson P. Samuel et al.   INORGANIC CHEMISTRY

A Singlet Biradicaloid Zinc Compound and Its Nonradical Counterpart

(2013) Amit Pratap Singh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bottleable (Amino)(Carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes

(2013) Janell K. Mahoney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Normal-to-Abnormal Rearrangement and NHC Activation in Three-Coordinate Iron(II) Carbene Complexes

(2013) Benjamin M. Day et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acyclic Germylones: Congeners of Allenes with a Central Germanium Atom

(2013) Yan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

Main-Group Lewis Acids for C–F Bond Activation

(2013) Timo Stahl et al.   ACS Catalysis

CN Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes using Hydrosilanes

(2012) David Schmidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beryllium-Induced CN Bond Activation and Ring Opening of an N-Heterocyclic Carbene

(2012) Merle Arrowsmith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of a Singlet Silylene to a stable Biradical

(2012) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents

(2012) Jonathan P. Moerdyk et al.   Nature Chemistry

Intramolecular C(sp3)–H Bond Activation Reactions of Low-Valent Cobalt Complexes with Coordination Unsaturation

(2012) Zhenbo Mo et al.   ORGANOMETALLICS

C−F and C−H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers: How Fluorine Tips the Scales

(2011) Eric Clot et al.   ACCOUNTS OF CHEMICAL RESEARCH

Pentafluoropyridine as a fluorinating reagent for preparing a hydrocarbon soluble β-diketiminatolead(ii) monofluoride

(2011) Anukul Jana et al.   CHEMICAL COMMUNICATIONS

Consecutive C-F Bond Activation of Hexafluorobenzene and Decafluorobiphenyl

(2011) Thomas Schaub et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Carbon–Silicon and Carbon–Carbon Bond Formation by Elimination Reactions at Metal N-Heterocyclic Carbene Complexes

(2011) Polly L. Arnold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Alkyl C–F Bonds by B(C6F5)3: Stoichiometric and Catalytic Transformations

(2011) Christopher B. Caputo et al.   ORGANOMETALLICS

Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines

(2011) R. Kinjo et al.   SCIENCE

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N,N′-Diamidoketenimines via Coupling of Isocyanides to an N-Heterocyclic Carbene

(2010) Todd W. Hudnall et al.   JOURNAL OF ORGANIC CHEMISTRY

Addition-Elimination Reactions across the M−C Bond of Metal N-Heterocyclic Carbenes

(2010) Zoë R. Turner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon

(2010) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Zirconium Benzyl Mediated C−N Bond Cleavage of an Amino-Linked N-Heterocyclic Carbene

(2010) Yu-Cheng Hu et al.   ORGANOMETALLICS

N-heterocyclic carbenes which readily add ammonia, carbon monoxide and other small molecules,

(2010) Ulrich Siemeling et al.   Chemical Science

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Catalytic CF Activation and Hydrodefluorination of Fluoroalkyl Groups

(2009) Gregor Meier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Ligand-Promoted Carbene Insertion into the Aryl Substituent of anN-Heterocyclic Carbene Ligand in Ruthenium-Based Metathesis Catalysts

(2009) Brandon R. Galan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Magnesium amido N-heterocyclic carbene complexes

(2008) Polly L. Arnold et al.   DALTON TRANSACTIONS

CHEMISTRY: Soluble Allotropes of Main-Group Elements

(2008) C. A. Dyker et al.   SCIENCE

Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts

(2008) C. Douvris et al.   SCIENCE

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS