Carbene-stabilized main group radicals and radical ions

Isolation of a Neutral P8Cluster by [2+2] Cycloaddition of a Diphosphene Facilitated by Carbene Activation of White Phosphorus

(2013) Christopher L. Dorsey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si

(2013) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploring the reactivity of white phosphorus with electrophilic carbenes: synthesis of a P4 cage and P8 clusters

(2013) Caleb D. Martin et al.   CHEMICAL COMMUNICATIONS

Rational Synthesis and Mutual Conversion of Bis-N-heterocyclic Diphosphanes and Secondary N-Heterocyclic Phosphanes

(2013) Oliver Puntigam et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Easy Access to Silicon(0) and Silicon(II) Compounds

(2013) Kartik Chandra Mondal et al.   INORGANIC CHEMISTRY

Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations

(2013) Xiaobo Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable Tetraaryldiphosphine Radical Cation and Dication

(2013) Xiaobo Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of Carbene-Stabilized Diarsenic: Diarsene Dications and Diarsenic Radical Cations

(2013) Mariham Y. Abraham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene Boranes Accelerate Type I Radical Photopolymerizations and Overcome Oxygen Inhibition

(2012) Jacques Lalevée et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Diaminocarbene with a Pyramidalized Nitrogen Atom: A Stable N-Heterocyclic Carbene with Enhanced Electrophilicity

(2012) David Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Isolable Radical Anion Based on the Borole Framework

(2012) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Conversion of a Singlet Silylene to a stable Biradical

(2012) Kartik Chandra Mondal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and characterisation of BODIPY radical anions

(2012) Victoria J. Richards et al.   CHEMICAL COMMUNICATIONS

An N-heterocyclic carbene adduct of diatomic tin, :SnSn:

(2012) Cameron Jones et al.   CHEMICAL COMMUNICATIONS

Borylene Complexes (BH)L2 and Nitrogen Cation Complexes (N+)L2: Isoelectronic Homologues of Carbones CL2

(2012) Mehmet Ali Celik et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Insight into the Reversible Dissociation and Chemical Reactivity of a Sterically Encumbered Diphosphane

(2012) Daniela Förster et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Preparation of a Diphosphine with Persistent Phosphinyl Radical Character in Solution: Characterization, Reactivity with O2, S8, Se, Te, and P4, and Electronic Structure Calculations

(2012) Nick A. Giffin et al.   INORGANIC CHEMISTRY

Exploring the nucleophilicity ofN,N′-diamidocarbenes: Heteroallenes and related compounds as coupling reagents

(2012) Young-Gi Lee et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Alkyne and Reversible Nitrile Activation: N,N′-Diamidocarbene-Facilitated Synthesis of Cyclopropenes, Cyclopropenones, and Azirines

(2012) Jonathan P. Moerdyk et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Isolable NHC-Stabilized Silylene Radical Cation: Synthesis and Structural Characterization

(2012) Hiroaki Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polarity Reversal Catalysis in Radical Reductions of Halides by N-Heterocyclic Carbene Boranes

(2012) Xiangcheng Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of B-Heterocyclic π-Radical and Its Reactivity as a Boryl Radical

(2012) Yoshitaka Aramaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Soft Photopolymerizations Initiated by Dye-Sensitized Formation of NHC-Boryl Radicals under Visible Light

(2012) Sofia Telitel et al.   MACROMOLECULES

Diamidocarbenes as versatile and reversible [2 + 1] cycloaddition reagents

(2012) Jonathan P. Moerdyk et al.   Nature Chemistry

Elucidating the Mechanism of Reversible Oxiranations via Magnetization Transfer Spectroscopy

(2012) Daniel T. Chase et al.   ORGANIC LETTERS

Dual Reactivity of a Stable Zwitterionic N-Heterocyclic Silylene and Its Carbene Complex Probed with Muonium

(2012) Paul W. Percival et al.   ORGANOMETALLICS

Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond

(2012) H. Braunschweig et al.   SCIENCE

A Boron-Boron Triple Bond

(2012) G. Frenking et al.   SCIENCE

Retracted Article: Homonuclear bond activation using a stable N,N′-diamidocarbene

(2012) Kelly M. Wiggins et al.   Chemical Science

Synthesis and Reactions of N-Heterocyclic Carbene Boranes

(2011) Dennis P. Curran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Domino Reactions

(2011) André Grossmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbene-stabilized main group diatomic allotropes

(2011) Yuzhong Wang et al.   DALTON TRANSACTIONS

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Comproportionation of Cationic and Anionic Tungsten Complexes Having anN-Heterocyclic Carbene Ligand To Give the Isolable 17-Electron Tungsten Radical CpW(CO)2(IMes)•

(2011) John A. S. Roberts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron Paramagnetic Resonance and Computational Studies of Radicals Derived from Boron-Substituted N-Heterocyclic Carbene Boranes

(2011) John C. Walton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Stable Dialkylphosphinyl Radical

(2011) Shintaro Ishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical reductions of alkyl halides bearing electron withdrawing groups with N-heterocyclic carbene boranes

(2011) Shau-Hua Ueng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Brief Survey of Our Contribution to Stable Carbene Chemistry

(2011) David Martin et al.   ORGANOMETALLICS

Building a Lewis Base with Boron

(2011) Y. Wang et al.   SCIENCE

Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines

(2011) R. Kinjo et al.   SCIENCE

N-Heterocyclic carbenes versus transition metals for stabilizing phosphinyl radicals

(2011) Olivier Back et al.   Chemical Science

A Water-Compatible NHC-Borane: Photopolymerizations in Water and Rate Constants for Elementary Radical Reactions

(2011) Mohamad-Ali Tehfe et al.   ACS Macro Letters

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Steering the Surprisingly Modular π-Acceptor Properties of N-Heterocyclic Carbenes: Implications for Gold Catalysis

(2010) Manuel Alcarazo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation of a Carbene-Stabilized Phosphorus Mononitride and Its Radical Cation (PN+.)

(2010) Rei Kinjo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ammonia N–H activation by a N,N′-diamidocarbene

(2010) Todd W. Hudnall et al.   CHEMICAL COMMUNICATIONS

EPR Studies of the Generation, Structure, and Reactivity of N-Heterocyclic Carbene Borane Radicals

(2010) John C. Walton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Crystalline Phosphinyl Radical Cation

(2010) Olivier Back et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbenes−Borane Complexes: A New Class of Initiators for Radical Photopolymerization

(2010) Mohamad-Ali Tehfe et al.   MACROMOLECULES

Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications

(2010) Olivier Back et al.   Nature Chemistry

Estimated Rate Constants for Hydrogen Abstraction from N-Heterocyclic Carbene−Borane Complexes by an Alkyl Radical†

(2010) Andrey Solovyev et al.   ORGANIC LETTERS

N-Heterocyclic carbene-borane radicals as efficient initiating species of photopolymerization reactions under air

(2010) Mohamad-Ali Tehfe et al.   Polymer Chemistry

Different electronic structure of phosphonyl radical adducts of N-heterocyclic carbenes, silylenes and germylenes: EPR spectroscopic study and DFT calculations

(2010) Dennis Sheberla et al.   Chemical Science

N-heterocyclic carbenes which readily add ammonia, carbon monoxide and other small molecules,

(2010) Ulrich Siemeling et al.   Chemical Science

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonmetal-Mediated Fragmentation of P4: Isolation of P1and P2Bis(carbene) Adducts

(2009) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Complexed Triphosphaallyl Radical, Cation, and Anion Family

(2009) Manfred Scheer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spirocyclic boronium ions: precursors to persistent neutral radicals

(2009) Thomas K. Wood et al.   CHEMICAL COMMUNICATIONS

Stable Noncyclic Singlet Carbenes

(2009) Joan Vignolle et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts†

(2009) Georgios C. Vougioukalakis et al.   CHEMICAL REVIEWS

Structural and Reactivity Studies of “Pincer” Pyridine Dicarbene Complexes of Fe0: Experimental and Computational Comparison of the Phosphine and NHC Donors

(2009) Andreas A. Danopoulos et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy

(2009) Mariham Y. Abraham et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and structure of early transition metal NHC complexes

(2009) Christian Lorber et al.   DALTON TRANSACTIONS

Synthesis and Reactions of Mono- and Dinuclear Ni(I) Thiolate Complexes

(2009) Mikinao Ito et al.   INORGANIC CHEMISTRY

N-Heterocyclic Carbene Boryl Radicals: A New Class of Boron-Centered Radical

(2009) Shau-Hua Ueng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of a Simplified Version of Stable Bulky and Rigid Cyclic (Alkyl)(amino)carbenes, and Catalytic Activity of the Ensuing Gold(I) Complex in the Three-Component Preparation of 1,2-Dihydroquinoline Derivatives

(2009) Xiaoming Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Isolable NHC-Supported Silanone

(2009) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AnN,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

(2009) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Borenium Cation Stabilized by an N-Heterocyclic Carbene Ligand

(2009) Takeshi Matsumoto et al.   ORGANOMETALLICS

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Understanding the M(NHC) (NHC=N-heterocyclic carbene) bond

(2008) Heiko Jacobsen et al.   COORDINATION CHEMISTRY REVIEWS

Structural variations in nickel, palladium, and platinum complexes containing pyrimidyl N-heterocyclic carbene ligand

(2008) Chao Chen et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Planar, Twisted, and Trans-Bent:  Conformational Flexibility of Neutral Diborenes

(2008) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbene-Stabilized Diphosphorus

(2008) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Routes to New N-Heterocyclic Carbene Titanium(IV) Imido Complexes

(2008) Christian Lorber et al.   ORGANOMETALLICS

CHEMISTRY: Soluble Allotropes of Main-Group Elements

(2008) C. A. Dyker et al.   SCIENCE

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE

Making Stable Radicals of Heavy Elements of Groups 14 and 13: The Might of Silyl Substitution

(2007) Vladimir Ya. Lee et al.   CHEMISTRY LETTERS

(Me3Si)3SiH: Twenty Years After Its Discovery as a Radical-Based Reducing Agent

(2007) Chryssostomos Chatgilialoglu   CHEMISTRY-A EUROPEAN JOURNAL