What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

Facile synthesis of [(NHC)MX(cod)] and [(NHC)MCl(CO)2] (M = Rh, Ir; X = Cl, I) complexes

(2015) R. Savka et al.   DALTON TRANSACTIONS

Group 1 and 2 and Early Transition Metal Complexes Bearing N-Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications

(2014) Stéphane Bellemin-Laponnaz et al.   CHEMICAL REVIEWS

When the Tolman Electronic Parameter Fails: A Comparative DFT and Charge Displacement Study of [(L)Ni(CO)3]0/– and [(L)Au(CO)]0/+

(2014) Gianluca Ciancaleoni et al.   INORGANIC CHEMISTRY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Exploring the Coordination of Cyclic Selenoureas to Gold(I)

(2014) David J. Nelson et al.   ORGANOMETALLICS

Methoxy-Functionalized N-Heterocyclic Carbenes

(2014) David J. Nelson et al.   ORGANOMETALLICS

The Chemical Bond in Gold(I) Complexes with N-Heterocyclic Carbenes

(2014) Demian Marchione et al.   ORGANOMETALLICS

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Straightforward synthesis of [Au(NHC)X] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

(2013) Alba Collado et al.   CHEMICAL COMMUNICATIONS

A general synthetic route to [Cu(X)(NHC)] (NHC = N-heterocyclic carbene, X = Cl, Br, I) complexes

(2013) Orlando Santoro et al.   CHEMICAL COMMUNICATIONS

Quantifying and understanding the electronic properties of N-heterocyclic carbenes

(2013) David J. Nelson et al.   CHEMICAL SOCIETY REVIEWS

Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77Se NMR Chemical Shifts of Their Selenium Adducts

(2013) Annika Liske et al.   ORGANOMETALLICS

End-On and Side-On π-Acid Ligand Adducts of Gold(I): Carbonyl, Cyanide, Isocyanide, and Cyclooctyne Gold(I) Complexes Supported by N-Heterocyclic Carbenes and Phosphines

(2012) Mehmet Ali Celik et al.   INORGANIC CHEMISTRY

Proton Transfer Reactions of Triazol-3-ylidenes: Kinetic Acidities and Carbon Acid pKa Values for Twenty Triazolium Salts in Aqueous Solution

(2012) Richard S. Massey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolable, gold carbonyl complexes supported by N-heterocyclic carbenes

(2011) Chandrakanta Dash et al.   CHEMICAL COMMUNICATIONS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

pKas of the conjugate acids of N-heterocyclic carbenes in water

(2010) Eleanor M. Higgins et al.   CHEMICAL COMMUNICATIONS

Flexibility of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis and Their Impact in the First Coordination Sphere of the Metal

(2010) Francesco Ragone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

SambVca: A Web Application for the Calculation of the Buried Volume of N-Heterocyclic Carbene Ligands

(2009) Albert Poater et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Understanding the M(NHC) (NHC=N-heterocyclic carbene) bond

(2008) Heiko Jacobsen et al.   COORDINATION CHEMISTRY REVIEWS

Analyzing NMR shielding tensors calculated with two-component relativistic methods using spin-free localized molecular orbitals

(2008) Jochen Autschbach   JOURNAL OF CHEMICAL PHYSICS

Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands

(2008) Stefanie Wolf et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System

(2007) Roy A. Kelly III et al.   ORGANOMETALLICS