Nickel-catalyzed direct alkynylation of C(sp2)–H bonds of amides: an “inverse Sonogashira strategy” to ortho-alkynylbenzoic acids

Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

(2015) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

A sustainable and simple catalytic system for direct alkynylation of C(sp2)–H bonds with low nickel loadings

(2015) Yue-Jin Liu et al.   CHEMICAL COMMUNICATIONS

Nickel Catalysts/N,N′-Bidentate Directing Groups: An Excellent Partnership in Directed C–H Activation Reactions

(2015) Luis C. Misal Castro et al.   CHEMISTRY LETTERS

Direct ortho-Thiolation of Arenes and Alkenes by Nickel Catalysis

(2015) Cong Lin et al.   ORGANIC LETTERS

Reusable directing groups [8-aminoquinoline, picolinamide, sulfoximine] in C(sp3)–H bond activation: present and future

(2015) Raja K. Rit et al.   TETRAHEDRON

Palladium-Catalyzed Direct Alkynylation ofN-Vinylacetamides

(2014) Yun-He Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed CH Alkynylation of Arenes at Room Temperature

(2014) Chao Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed CH Alkylations: Direct Secondary Alkylations and Trifluoroethylations of Arenes

(2014) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of conjugated 1,3-enynes by Rh(iii)-catalysed alkynylation of alkenes via C–H activation

(2014) Karl D. Collins et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed olefinic C–H alkynylation of enamides at room temperature

(2014) Chao Feng et al.   CHEMICAL COMMUNICATIONS

Copper/Silver-Mediated Directortho-Ethynylation of Unactivated (Hetero)aryl CH Bonds with Terminal Alkyne

(2014) Yue-Jin Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Site-Selective Amidation of Unactivated C(sp3)H Bonds

(2014) Xuesong Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Aryl C–H Olefination with Unactivated, Aliphatic Alkenes

(2014) Arghya Deb et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(II)-Mediated Ortho C–H Alkynylation of (Hetero)Arenes with Terminal Alkynes

(2014) Ming Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)- and Ir(III)-Catalyzed C–H Alkynylation of Arenes under Chelation Assistance

(2014) Fang Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Rhodium(III)-Catalyzed Olefinic C–H Alkynylation of Acrylamides Using Tosyl-Imide as Directing Group

(2014) Chao Feng et al.   ORGANIC LETTERS

8-Aminoquinoline: A Powerful Directing Group in Metal-Catalyzed Direct Functionalization of CH Bonds

(2013) Matthieu Corbet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Cross-Coupling between Heterocycles and Terminal Alkynes with Low Catalyst Loading

(2013) Xiaoming Jie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(0)-Catalyzed Alkynylation of C(sp3)–H Bonds

(2013) Jian He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Direct Alkylation of C–H Bonds in Benzamides and Acrylamides with Functionalized Alkyl Halides via Bidentate-Chelation Assistance

(2013) Yoshinori Aihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Direct Arylation of C(sp3)–H Bonds in Aliphatic Amides via Bidentate-Chelation Assistance

(2013) Yoshinori Aihara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed direct oxidative annulation of N-iminopyridinium ylides with terminal alkynes using O2as oxidant

(2012) Shengtao Ding et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Regioselective Ortho-Arylation and Alkenylation of N-Alkyl Benzamides with Boronic Acids via Ruthenium-Catalyzed C–H Bond Activation: An Easy Route to Fluorenones Synthesis

(2012) Ravi Kiran Chinnagolla et al.   ORGANIC LETTERS

Palladium-catalyzed oxidative alkynylation of arene C–H bond using the chelation-assisted strategy

(2012) Seok Hwan Kim et al.   TETRAHEDRON

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

C–H Functionalization in organic synthesis

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in Sonogashira reactions

(2011) Rafael Chinchilla et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Direct Ethynylation of C(sp3)–H Bonds in Aliphatic Carboxylic Acid Derivatives

(2011) Yusuke Ano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Alkynylation of Heterocycles with Terminal Alkynes under Air Conditions

(2011) Seok Hwan Kim et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct ortho-Alkynylation of Aromatic Carboxylic Acid Derivatives

(2011) Yusuke Ano et al.   ORGANIC LETTERS

Cobalt-Catalyzed, Chelation-Assisted C-H Bond Functionalization

(2011) Naohiko Yoshikai   SYNLETT

Formal Inverse Sonogashira Reaction: Direct Alkynylation of Arenes and Heterocycles with Alkynyl Halides

(2010) Alexander S. Dudnik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed direct oxidative Heck–Cassar–Sonogashira type alkynylation of indoles with alkynes under oxygen

(2010) Luo Yang et al.   CHEMICAL COMMUNICATIONS

Rotational Isomerism Involving Acetylene Carbon

(2010) Shinji Toyota   CHEMICAL REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed Direct C-H Alkenylation, Alkynylation, Benzylation, and Alkylation of (Hetero)arenes

(2010) Samir Messaoudi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Gold-Catalyzed Ethynylation of Arenes

(2010) Teresa de Haro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Direct Alkynylation of Electron-Deficient Polyfluoroarenes with Terminal Alkynes Using O2as an Oxidant

(2010) Ye Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient and Versatile Pd-Catalyzed Direct Alkynylation of Both Azoles and Azolines

(2010) Seok Hwan Kim et al.   ORGANIC LETTERS

Direct Alkynylation of Indole and Pyrrole Heterocycles

(2009) Jonathan P. Brand et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper as a Powerful Catalyst in the Direct Alkynylation of Azoles

(2009) François Besselièvre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Direct Alkynylation of Azoles with Alkynyl Bromides

(2009) Naoto Matsuyama et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct Alkynylation of C−H Bonds in Benzenes

(2009) Mamoru Tobisu et al.   ORGANIC LETTERS

Palladium-catalysed direct alkenylation of sydnones

(2009) Arantxa Rodriguez et al.   TETRAHEDRON LETTERS

Catalysts for the Sonogashira Coupling-The Crownless Again Shall Be King

(2008) Herbert Plenio   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct palladium-catalyzed C-3 alkynylation of indoles

(2008) Yonghong Gu et al.   TETRAHEDRON LETTERS