Iron-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling Using an Alkoxide Base

A Perspective on Late-Stage Aromatic C–H Bond Functionalization

(2022) Li Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross-Coupling Enabled by Well-Defined Precatalysts with L,X-Type Ligands

(2022) L. Reginald Mills et al.   ACS Catalysis

Potassium Trimethylsilanolate-Promoted, Anhydrous Suzuki–Miyaura Cross-Coupling Reaction Proceeds via the “Boronate Mechanism”: Evidence for the Alternative Fork in the Trail

(2022) Connor P. Delaney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Catalysis: A New Horizon Towards Organoboron‐mediated C−C Cross‐coupling

(2022) Suparna Mondal et al.   Chemistry-An Asian Journal

Cobalt-Catalyzed Coupling of Aryl Chlorides with Aryl Boron Esters Activated by Alkoxides

(2021) Sanita B. Tailor et al.   ACS Catalysis

A Process Chemistry Benchmark for sp2–sp3 Cross Couplings

(2021) Gregory L. Beutner et al.   JOURNAL OF ORGANIC CHEMISTRY

Advancing Base-Metal Catalysis: Development of a Screening Method for Nickel-Catalyzed Suzuki–Miyaura Reactions of Pharmaceutically Relevant Heterocycles

(2021) Matthew J. Goldfogel et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Air-Stable Iron-Based Precatalysts for Suzuki–Miyaura Cross-Coupling Reactions between Alkyl Halides and Aryl Boronic Esters

(2021) Alexander S. Wong et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Rational Design of an Iron-Based Catalyst for Suzuki-Miyaura Cross-Couplings Involving Heteroaromatic Boronic Esters and Tertiary Alkyl Electrophiles

(2020) Michael P. Crockett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding the Medicinal Chemist Toolbox: Comparing Seven C(sp2)–C(sp3) Cross-Coupling Methods by Library Synthesis

(2020) Amanda W. Dombrowski et al.   ACS Medicinal Chemistry Letters

Cobalt-Catalyzed C(sp2)–C(sp3) Suzuki–Miyaura Cross Coupling

(2020) Jacob R. Ludwig et al.   ORGANIC LETTERS

Synthesis, Structure, and Hydrogenolysis of Pyridine Dicarbene Iron Dialkyl Complexes

(2019) Stephan M. Rummelt et al.   ORGANOMETALLICS

Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki−Miyaura Cross-Coupling of Boronic Esters

(2019) Connor P. Delaney et al.   ACS Catalysis

Iron-Catalyzed Cross-Couplings in the Synthesis of Pharmaceuticals: In Pursuit of Sustainability

(2018) Aleksandra Piontek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Interrogation of Co/Ni-Dual Catalyzed Hydroarylation

(2018) Sophia L. Shevick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermediates and Mechanism in Iron-Catalyzed Cross-Coupling

(2018) Jeffrey D. Sears et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions between Alkyl Halides and Unactivated Arylboronic Esters

(2018) Michael P. Crockett et al.   ORGANIC LETTERS

Development and Evolution of Mechanistic Understanding in Iron-Catalyzed Cross-Coupling

(2018) Michael L. Neidig et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future

(2018) Louis-Charles Campeau et al.   ORGANOMETALLICS

A Pharmaceutical Industry Perspective on Sustainable Metal Catalysis

(2018) John D. Hayler et al.   ORGANOMETALLICS

Cobalt-Catalyzed Cross-Coupling Reactions of Arylboronic Esters and Aryl Halides

(2017) Hung A. Duong et al.   ORGANOMETALLICS

Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

(2017) Gregory C. Fu   ACS Central Science

Nickel-Catalyzed Cross-Coupling of Redox-Active Esters with Boronic Acids

(2016) Jie Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in iron-catalysed cross coupling reactions and their mechanistic underpinning

(2016) T. L. Mako et al.   Inorganic Chemistry Frontiers

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

Development of GSK's acid and base selection guides

(2015) Richard K. Henderson et al.   GREEN CHEMISTRY

Analysis of Past and Present Synthetic Methodologies on Medicinal Chemistry: Where Have All the New Reactions Gone?

(2015) Dean G. Brown et al.   JOURNAL OF MEDICINAL CHEMISTRY

Expedient Iron-Catalyzed Coupling of Alkyl, Benzyl and Allyl Halides with Arylboronic Esters

(2014) Robin B. Bedford et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanism and Selectivity in Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Halides with Alkyl Halides

(2013) Soumik Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Escape from Flatland 2: complexity and promiscuity

(2012) Frank Lovering   MedChemComm

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Stereospecific Cross-Coupling between Alkenylboronates and Alkyl Halides Catalyzed by Iron–Bisphosphine Complexes

(2011) Toru Hashimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Suzuki Cross-Couplings of Activated Secondary Alkyl Electrophiles: Arylations of Racemic α-Chloroamides

(2010) Pamela M. Lundin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Suzuki−Miyaura Coupling of Alkyl Halides

(2010) Takuji Hatakeyama et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Escape from Flatland: Increasing Saturation as an Approach to Improving Clinical Success

(2009) Frank Lovering et al.   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH