Photocatalytic Generations of Secondary and Tertiary Silyl Radicals from Silylboranes Using an Alkoxide Cocatalyst

KOtBu-Catalyzed 1,2-Silaboration of N-Heteroarenes to Access 2-Silylheterocycles: A Cooperative Model for the Regioselectivity

(2022) Eunchan Jeong et al.   ACS Catalysis

Organic Photoredox-Catalyzed Silyl Radical Generation from Silylboronate

(2022) Naho Takemura et al.   ACS Catalysis

Synthesis of β-Silyl α-Amino Acids via Visible-Light-Mediated Hydrosilylation

(2021) Yi Wan et al.   ORGANIC LETTERS

Visible-Light Decatungstate/Disulfide Dual Catalysis for the Hydro-Functionalization of Styrenes

(2021) Alexis Prieto et al.   ORGANIC LETTERS

Illuminating Stannylation

(2021) Kyoka Sakamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper‐Photocatalyzed Hydrosilylation of Alkynes and Alkenes under Continuous Flow

(2021) Mingbing Zhong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photo-Induced ortho-C–H Borylation of Arenes through In Situ Generation of Rhodium(II) Ate Complexes

(2021) Jin Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters

(2021) Martin Oestreich et al.   SYNTHESIS-STUTTGART

Visible-Light Mediated Hydrosilylative and Hydrophosphorylative Cyclizations of Enynes and Dienes

(2020) Hong Hou et al.   ORGANIC LETTERS

Sila- and Germacarboxylic Acids: Precursors for the Corresponding Silyl and Germyl Radicals

(2020) Ning-Xin Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General Synthesis of Trialkyl- and Dialkylarylsilylboranes: Versatile Silicon Nucleophiles in Organic Synthesis

(2020) Ryosuke Shishido et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oligosilanes as Silyl Radical Precursors through Oxidative Si−Si Bond Cleavage using Redox Catalysis

(2020) Xiaoye Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In Situ Generation of Silyl Anion Species through Si−B Bond Activation for the Concerted Nucleophilic Aromatic Substitution of Fluoroarenes

(2019) Kumiko Kojima et al.   ChemPlusChem

Conjugated Polymers Inspired by Crystalline Silicon

(2019) Eric A. Marro et al.   CHEMISTRY OF MATERIALS

Pyridine‐Based Organocatalysts for Regioselective syn ‐1,2‐Silaboration of Terminal Alkynes and Allenes

(2019) Yohei Morimasa et al.   Asian Journal of Organic Chemistry

Dehydrogenative Silylation of Alkenes for the Synthesis of Substituted Allylsilanes by Photoredox, Hydrogen-Atom Transfer, and Cobalt Catalysis

(2019) Wan-Lei Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quadruple Borylation of Terminal Alkynes

(2019) Daiki Yukimori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective Synthesis of Polysubstituted Piperidines via Visible Light‐Driven Silylative Cyclization of Aza‐1,6‐Dienes: Experimental and DFT Studies

(2019) Shaozhong Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Mediated Regioselective Allylation, Benzylation, and Silylation of Methylene-Malononitriles via Photoredox-Induced Radical Cation Fragmentation

(2019) Rongfang Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Arylsilylation of Electron-Deficient Alkenes via Cooperative Photoredox and Nickel Catalysis

(2019) Zhikun Zhang et al.   ACS Catalysis

In Situ Generation of Silylzinc by Si−B Bond Activation Enabling Silylzincation and Silaboration of Terminal Alkynes

(2018) Yuki Nagashima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes

(2018) Chip Le et al.   SCIENCE

Visible-Light-Mediated Metal-Free Difunctionalization of Alkenes with CO2 and Silanes or C(sp3 )−H Alkanes

(2018) Jing Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Mediated Defluorosilylation of C(sp2 )−F and C(sp3 )−F Bonds

(2018) Xiang-Wie Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light-Driven Radical trans-Hydrosilylation of Electron-Neutral and -Rich Alkenes with Tertiary and Secondary Hydrosilanes

(2018) Jing Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

A Mild and Direct Site-Selective sp2 C–H Silylation of (Poly)Azines

(2018) Yiting Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quest for Novel Chemical Entities through Incorporation of Silicon in Drug Scaffolds

(2017) Remya Ramesh et al.   JOURNAL OF MEDICINAL CHEMISTRY

Visible Light Activation of Boronic Esters Enables Efficient Photoredox C(sp2)-C(sp3) Cross-Couplings in Flow

(2016) Fabio Lima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silicon-Containing Amino Acids: Synthetic Aspects, Conformational Studies, and Applications to Bioactive Peptides

(2016) Emmanuelle Rémond et al.   CHEMICAL REVIEWS

The chemistry of organo silanetriols

(2016) Rudolf Pietschnig et al.   COORDINATION CHEMISTRY REVIEWS

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling

(2016) Patricia Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Transition-Metal-Catalyzed Synthetic Transformations of Organosilicon Reagents

(2016) Takeshi Komiyama et al.   ACS Catalysis

Decatungstate-Photocatalyzed Si−H/C−H Activation in Silyl Hydrides: Hydrosilylation of Electron-Poor Alkenes

(2015) Hisham Qrareya et al.   ChemCatChem

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates

(2015) Scott E. Denmark et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry

(2015) David Nicewicz et al.   SYNLETT

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Visible-light radical reaction designed by Ru- and Ir-based photoredox catalysis

(2014) Takashi Koike et al.   Inorganic Chemistry Frontiers

Visible Light-Induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis

(2012) Yusuke Yasu et al.   ADVANCED SYNTHESIS & CATALYSIS

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

(2012) Hajime Ito et al.   CHEMICAL COMMUNICATIONS

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Di-tert-butylisobutylsilyl, Another Useful Protecting Group

(2011) Huan Liang et al.   ORGANIC LETTERS

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Hydrosilylation of C−C Multiple Bonds Using (Me3Si)3SiH in Water. Comparative Study of the Radical Initiation Step

(2009) Al Postigo et al.   ORGANOMETALLICS

Tris(trimethylsilyl)silyl versus tris(trimethylsilyl)germyl: Radical reactivity and oxidation ability

(2008) Jacques Lalevée et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes

(2008) Timothy A. Boebel et al.   ORGANOMETALLICS